Infrared Spectra of Trimethylamine-Carbon Monoxide-Borane and its Deuterated Derivatives

1974 ◽  
Vol 28 (5) ◽  
pp. 427-430 ◽  
Author(s):  
James C. Carter ◽  
George W. Luther ◽  
Alfred L. Moyé
Keyword(s):  
Carbon Monoxide ◽  
Low Temperature ◽  
Spectral Data ◽  
Infrared Spectra ◽  
Nmr Data ◽  
Infrared Spectral

Low temperature infrared spectral data are given for the adducts H3BC(O)N(CH3)3, D3BC(O)N(CH3)3, H3BC(O)N(CD)3)3)D3BC(O)N(CD3)3 over the range 3000 to 300 cm−1. Boron-11 NMR data are given for H3BCO and H3BC(O)N(CH3)3. The spectra allow the assignment of the structure of the adducts as [Formula: see text]

Metal Halide Ammines. III. Thermal Analyses and Calorimetry of Fluorosilicate Ammines and Hydrates of Bivalent Metals. Infrared Spectra of the Ammines

1975 ◽  
Vol 53 (16) ◽  
pp. 2426-2429 ◽  
Author(s):  
Kashinath C. Patil ◽  
Etalo A. Secco
Keyword(s):  
Spectral Data ◽  
Infrared Spectra ◽  
Thermal Analyses ◽  
Calorimetric Data ◽  
Ammonia Loss ◽  
Bivalent Metal ◽  
Decomposition Reactions ◽  
Infrared Spectral ◽  
Bivalent Metals ◽  
And Calorimetry

Bivalent metal fluorosilicate ammines have been prepared. The thermal analyses of the dodecammines reveal the decomposition to occur via the pentammine and/or tetrammine. The final ammonia loss is concomitant with fluorosilicate decomposition. Calorimetric data are given for the decomposition reactions. Some fluorosilicate hydrates are included for comparison purposes.The infrared spectral data of the ammines are presented with their assignments.

Metal Halide Ammines. II. Thermal Analyses, Calorimetry and Infrared Spectra of Fluoride Ammines and Hydrates of Bivalent Metals

1972 ◽  
Vol 50 (4) ◽  
pp. 567-573 ◽  
Author(s):  
K. C. Patil ◽  
E. A. Secco
Keyword(s):  
Spectral Data ◽  
Infrared Spectra ◽  
Thermal Analyses ◽  
Metal Halide ◽  
Metal Fluoride ◽  
Bivalent Metal ◽  
Calorimetric Measurements ◽  
Infrared Spectral ◽  
Bivalent Metals ◽  
Experimental Values

Thermal analyses of bivalent metal fluoride ammines reveal that decomposition occurs in two or more steps. Calorimetric measurements along with related enthalpic values of the various decomposition steps are given.The infrared spectral data of the ammines and hydrates are compared with theoretical and some experimental values already in the literature.

scholarly journals Vibrational Mode Coupling to Reverse Electron Transfer in (CN)5FeCNRu(NH3)5− in Solution

1999 ◽  
Vol 19 (1-4) ◽  
pp. 385-387
Author(s):  
Chengfei Wang ◽  
Boris Akhremitchev ◽  
Gilbert C. Walker
Keyword(s):  
Electron Transfer ◽  
Charge Transfer ◽  
Spectral Data ◽  
Infrared Spectra ◽  
High Frequency ◽  
Mode Coupling ◽  
Vibrational Mode ◽  
Time Resolved ◽  
Reverse Electron Transfer ◽  
Infrared Spectral

We present charge transfer absorption, resonance Raman and time-resolved infrared spectral data for (CN)5FeCNRu(NH3)5− in various solvents. The transient infrared spectra and anisotropies reveal both non-equilibrium vibrational populations of high frequency modes and local solvent heating.

Structure of donor-acceptor complexes. X. Complexes of cyanoacetamide with Lewis acids

1969 ◽  
Vol 22 (7) ◽  
pp. 1381 ◽  
Author(s):  
RC Paul ◽  
SL Chadha
Keyword(s):  
Oxygen Atom ◽  
Spectral Data ◽  
Infrared Spectra ◽  
Lewis Acids ◽  
Far Infrared ◽  
Carbonyl Oxygen ◽  
Aluminium Chloride ◽  
Infrared Spectral ◽  
Donor Acceptor ◽  
Ionic Nature

Complexes of cyanoacetamide with aluminium chloride and bromide, anti- mony(V) chloride, boron(III) bromide, tin(IV) chloride and bromide, titanium(IV) chloride and bromide, and zirconium(IV) chloride have been prepared. The molar conductances of the complexes in nitrobenzene indicate their non-ionic nature. The infrared spectra indicate bonding of the metal halides to the carbonyl oxygen atom of the ligand. Metal- to-oxygen bonding also gets support from the far-infrared spectral data.

Metal Halide Ammines. 1. Thermal Analyses, Calorimetry, and Infrared Spectra of Cadmium Halide (Cl, Br, I) Derivatives

1971 ◽  
Vol 49 (23) ◽  
pp. 3831-3835 ◽  
Author(s):  
K. C. Patil ◽  
E. A. Secco
Keyword(s):  
Spectral Data ◽  
Infrared Spectra ◽  
Thermal Analyses ◽  
Decomposition Reaction ◽  
Metal Halide ◽  
Calorimetric Measurements ◽  
Infrared Spectral

The thermal analyses of cadmium halide hexammines reveal that decomposition occurs by loss of ammonia via the diammine and the monoammine. Calorimetric measurements along with related enthalpic values for the intermediate stable stages of the decomposition reaction are given.The infrared spectral data of the diammines and monoammines are presented with their assignments.

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