Infrared Spectra of 1:10 Phenanthroline and its Addition Compounds with Antimony Trichloride and Antimony Pentachloride

1969 ◽  
Vol 24 (12) ◽  
pp. 2015-2016 ◽  
Author(s):  
S. S. Singh
2015 ◽  
Vol 4 ◽  
pp. 45-48
Author(s):  
Ram Nath Prasad Yadav

Lewis acidity of antimony(III) halides and their organo substituted derivatives is well known. The molecules SbX3 are good acceptor and a wide range of neutral complexes have been prepared but it seems antimony trichloride is a weak acceptor as compared to antimony pentachloride. The halide complexes are more interesting because of the part played by the lone pair in determining the stereochemistry where 1:1 complexes have trigonal bipyramidal and 1:2 complexes have square pyramidal configurations. Complexes of antimony trichloride with aromatic hydrocarbon are also known but the presence of organic group in a molecule reduces its capacity to form complexes.DOI: http://dx.doi.org/10.3126/av.v4i0.12357Academic Voices Vol.4 2014: 45-48


1981 ◽  
Vol 78 ◽  
pp. 927-932 ◽  
Author(s):  
F.J.C.M. Toolenaar ◽  
G.J. van der Poort ◽  
F. Stoop ◽  
V. Ponec

Author(s):  
Daniel Tabor ◽  
Timothy Zwier ◽  
Joseph Korn ◽  
Daniel Hewett ◽  
Edwin Sibert
Keyword(s):  

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