The Microwave Spectra of m-Xylene and m-Xylene-d10. Determination of the Low Methyl Internal Rotation Barrier
2001 ◽
Vol 56
(9-10)
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pp. 635-640
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Keyword(s):
Abstract The rotational spectra of m-xylene, (CH3)2C6H4 and of m-xylene-d10, (CD3)2C6D4 have been recorded between 6 and 26.5 GHz using pulsed beam Fourier transform microwave spectroscopy. The clue for the assignment of the internal rotation multiplets was the inertial defect derived from the A1A1 species transitions. The rotational constants for m-xylene and m-xylene-d10 are A = 3572.1117(1) MHz / 2896.1195(17) MHz, B = 1761.8621(1) MHz / 1446.0236(15) MHz, C =1197.3943(2) MHz / 988.2357(7) MHz, the barrier to internal rotation of the two methyl groups are V3 = 53.7(16) J/mol / 39.8(5) J/mol, their moments of inertia were assumed to be I∞= 3.14 uÅ2 / 6.28 uÅ2.
1993 ◽
Vol 48
(11)
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pp. 1093-1101
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1985 ◽
Vol 40
(3)
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pp. 271-273
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Keyword(s):
1999 ◽
Vol 248
(2-3)
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pp. 247-261
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1994 ◽
Vol 35
(4)
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pp. 542-544
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2000 ◽
Vol 55
(5)
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pp. 481-485
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Keyword(s):
1992 ◽
Vol 47
(6)
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pp. 761-764
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Mikrowellenspektrum, Hinderungspotential der internen Rotation und Dipolmoment des para-Fluortoluols
1965 ◽
Vol 20
(12)
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pp. 1682-1686
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1998 ◽
Vol 120
(8)
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pp. 1934-1935
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1996 ◽
Vol 51
(10-11)
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pp. 1099-1106
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1975 ◽
Vol 35
(4)
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pp. 475-478
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Keyword(s):