Determination of a High Potential Barrier Hindering Internal Rotation in 2-Methylcyclopentanone and α-Methyl-γ-Butyrolactone by Microwave Fourier Transform Spectroscopy
1992 ◽
Vol 47
(6)
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pp. 761-764
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Keyword(s):
AbstractThe microwave spectra of α-methyl-γ-butyrolactone and 2-methylcyclopentanone have been reinvestigated using microwave Fourier transform spectroscopy. A-E splittings due to internal rotation of the methyl group have been observed in the ground and several vibrationally excited states for both molecules. From an internal-axis-method analysis of these splittings, values of the methyl group internal rotation barrier of 2.61 kcal mol-1 for α-methyl-γ-butyrolactone and 2.41 kcal mol-1 for 2-methylcyclopentanone have been obtained.
2000 ◽
Vol 55
(5)
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pp. 481-485
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Keyword(s):
2001 ◽
Vol 56
(9-10)
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pp. 635-640
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1982 ◽
Vol 37
(9)
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pp. 1035-1037
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1994 ◽
Vol 35
(4)
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pp. 542-544
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Determination of a High Potential Barrier Hindering Internal Rotation from the Ground State Spectrum
1983 ◽
Vol 38
(9)
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pp. 1010-1014
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Keyword(s):
1985 ◽
Vol 40
(3)
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pp. 271-273
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Keyword(s):
1985 ◽
Vol 40
(6)
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pp. 575-587
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1973 ◽
Vol 95
(17)
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pp. 5759-5761
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Keyword(s):