Neue Methoden zur spektrophotometrischen pK-Wertbestimmung, III Dreistufige Titrationssysteme / New Methods for Spectrophotometric Determination of pK-Values, III Titration of Trivalent Protolytes
1975 ◽
Vol 30
(5-6)
◽
pp. 358-372
◽
Keyword(s):
The spectrophotometric titration of three-step sequential dissociation equilibria is analyzed by means of two dimensional absorbance diagrams. The evaluation of pK1 and pK3 as well as of the absorbance coefficients of both ampholytes is made by the uniform segments at the beginning and end of the titration. New methods of evaluating the value of pK2 precisely and without difficulty even at small pK-differences are described. By means of several independent criteria the pK-values and the absorbance coefficients of the ampholytes can be examined. The titration of (1,2,4)-benzenetricarboxylic acid illustrates the new method.
1974 ◽
Vol 29
(7-8)
◽
pp. 500-513
◽
1984 ◽
Vol 32
(6)
◽
pp. 2468-2470
◽
2016 ◽
Vol 21
(6)
◽
pp. 486-494
2016 ◽
Vol 408
(28)
◽
pp. 8079-8088
◽
1959 ◽
Vol 23
(12)
◽
pp. 698-701
2001 ◽
Vol 40
(Part 1, No. 1)
◽
pp. 388-392
Keyword(s):