Untersuchung des M2/M3-Phasenübergangs in V1-xFexO2 mit x = 0,024.
1976 ◽
Vol 31
(10)
◽
pp. 1367-1371
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Keyword(s):
The Mössbauer investigations of V1-xFexO2 with x = 0.024 indicate that Fe enters two cation positions of M2 and M3. At the phase transition the two quadrupole splittings show a discontinuous behavior whereas the isomer shift changes continuously with a crossingover at the M2, M3 transition (Tt′ = 275 K). Generally a first order phase transition is accompanied by a change of the cell volume V and a change of the isomer shift. The observed continuous behavior of the isomer shift points to a first order transition with δV ≠ 0.
1999 ◽
Vol 10
(07)
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pp. 1261-1269
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Keyword(s):
Keyword(s):
1990 ◽
Vol 167
(3-4)
◽
pp. 388-394
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1989 ◽
Vol 71
(1)
◽
pp. 45-48
◽
1982 ◽
Vol 67
(3)
◽
pp. 787-803
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