Heterogene Hydrierung ungesättigter Verbindungen mit dem P-2-Ni Katalysator bei Umsatzzahlen UZ bis 90000 / Heterogeneous Hydrogenation of Unsaturated Compounds with Catalyst P-2-Ni with Turnover Numbers up to 90,000

1977 ◽  
Vol 32 (12) ◽  
pp. 1461-1466 ◽  
Author(s):  
Walter Strohmeier ◽  
Magdalena Pföhler ◽  
Hannelore Steigerwald

Unsaturated compounds are very rapidly hydrogenated with nickel-boride catalyst P-2-Ni without solvent under mild conditions (70-85 °C and 10 bar). Turnover numbers UZ up to 90,000 and space-time-yields of 7440 mmol product per 1 and 1 mgA Nickel in one hour with a mean catalyst activity ā = 124 were observed. This hydrogenation catalyst has a power, which is in the same magnitude of very active noble metal catalysts.

2021 ◽  
Author(s):  
Zhengang Ke ◽  
Yanfei Zhao ◽  
Ruipeng Li ◽  
Huan Wang ◽  
Wei Zeng ◽  
...  

N-methylation of amines with CO2/H2 to N-methylamines over non-noble metal catalysts is very interesting but remains challenging. Herein, we present an alcohol (e.g., ethanol) promoted strategy for N-methylation of anilines...


2020 ◽  
Vol 22 (1) ◽  
pp. 39-43 ◽  
Author(s):  
Kaiyue Yao ◽  
Ziliang Yuan ◽  
Shiwei Jin ◽  
Quan Chi ◽  
Bing Liu ◽  
...  

Nitrogen–doped carbon-supported cobalt–molybdenum bimetallic catalysts are active for the hydrodeoxygenation of sulfoxides to sulfides under mild conditions, which is the first case of use of heterogeneous non-noble metal catalysts for the reaction.


2021 ◽  
pp. 2150013
Author(s):  
Lei Wei ◽  
Xiaomeng Wang ◽  
Ya-Na Yu ◽  
Hongyan Liu ◽  
Yepei Li ◽  
...  

For practical application of sodium borohydride (NaBH[Formula: see text] hydrolysis to generate hydrogen, metallic catalysts with low cost but excellent activity are highly desired. However, it remains a big challenge to further improve the activity of non-noble metal catalysts. In this work, photocatalysis technology was successfully introduced to enhance the catalyst activity for NaBH4 hydrolysis. By means of conventional impregnation-reduction method, CoB nanocatalyst was evenly deposited on graphitic carbon nitride surface, resulting in a Schottky-type photocatalyst (CoB/CN). As expected, hydrogen generation rate was greatly boosted owing to light irradiation. According to the results of capture experiments, photoexcited electron from g-C3N4 could enrich the electron density of CoB surface, which leads to the improvement of catalyst activity. Additionally, the light irradiation facilitates the remarkable decrease of apparent activation energy. Compared with some reported noble metal catalysts, the CoB/CN presents higher activity, especially under light irradiation.


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