Alkylammonium-chloroantimonate(III) Struktur und Schwingungsspektren/Alkylammoniumchloroantimonates(III). Structure and Vibrational Spectra

1983 ◽  
Vol 38 (2) ◽  
pp. 149-154 ◽  
Author(s):  
U. Ensinger ◽  
W. Schwarz ◽  
A. Schmidt
Keyword(s):  
Hydrogen Bonds ◽  
Vibrational Spectra ◽  
Molecular Structures ◽  
X Ray ◽  
Pyramidal Structure ◽  
Crystal And Molecular Structures ◽  
Tetragonal Pyramidal ◽  
Cl Atoms

Abstract The crystal and molecular structures of triethylammonium tetrachloroantimonate(III) (1) and tris[methylammonium] hexachloroantimonate(III) (2) were determined by X-ray analysis. In compound 1, SbCl3 molecules are bridged by Cl ions to form chains. The coordination of Sb by Cl atoms yields a distorted tetragonal-pyramidal structure. In compound 2 there are chains of SbCL4- ions, again through bridging by Cl ions. One Cl ion has no contacts to Sb. The cations of 1 and 2 form hydrogen bonds with the anionic components.

Tetraalky lammonium - tetr achlor oantimonate (III). Struktur und Schwingungsspektren / Tetraalky lammonium Tetrachloroantimonates(III). Structure and Vibrational Spectra

1982 ◽  
Vol 37 (12) ◽  
pp. 1584-1589 ◽  
Author(s):  
U. Ensinger ◽  
W. Schwarz ◽  
A. Schmidt
Keyword(s):  
Vibrational Spectra ◽  
Molecular Structures ◽  
X Ray ◽  
Bond Lengths ◽  
Crystal And Molecular Structures

The crystal and molecular structures of tetraethyl- (1), tetra-η-propyl- (2) and tetra-nbutylammonium tetrachloroantimonate(III) (3) were determined by X-ray analysis. There are discrete Sb4Cl164- (1) and Sb2Cl82- (2 and 3) anions. The Sb-Cl bond lengths vary in the range between 234 and 326 pm, and are explained as in a three centre-four electron situation. The vibrational spectra of the anions are briefly discussed

Monitoring structural transformations in crystals. 12. Course of an intramolecular [4 + 4] photocycloaddition in a crystal

2008 ◽  
Vol 64 (3) ◽  
pp. 375-382 ◽  
Author(s):  
Elżbieta Trzop ◽  
Ilona Turowska-Tyrk
Keyword(s):  
Hydrogen Bonds ◽  
Cell Volume ◽  
Molecular Shape ◽  
Structural Transformations ◽  
Photochemical Reactions ◽  
Molecular Structures ◽  
X Ray Diffraction ◽  
X Ray ◽  
Crystal And Molecular Structures ◽  
Orientation Of Molecules

Variations in crystal and molecular structures, brought about by the intramolecular [4 + 4] photocycloaddition of bi(anthracene-9,10-dimethylene), were monitored using X-ray diffraction. The cell volume increased by 0.8% until the reaction was ca 40% complete, and afterwards decreased by 1.6% during the remainder of the photoreaction. The changes of the a and b lattice parameters were correlated with the changes of the molecular shape and packing. The distance between the directly reacting C atoms varied in a manner not observed for other photochemical reactions in crystals. It was constant until ca 20% photoreaction progress, then decreased, and later stabilized from ca 40% photoreaction progress. This phenomenon was explained by interplay between stress resulting from the presence of product molecules and the rigidity of reactant molecules. Changes of the orientation of molecules during the photoreaction were smaller than in the case of other monitored photochemical reactions in crystals owing to similarities in the shape and packing of reactant and product molecules. Weak C—H...π hydrogen bonds exist among reactant molecules in the pure reactant and partly reacted crystals.

Newμ-Oxo Octanuclear Complexes of 3d Elements Stabilized by Dialkylcarbamato Ligands. Synthesis and X-ray Crystal and Molecular Structures†

2002 ◽  
Vol 41 (11) ◽  
pp. 2814-2816 ◽  
Author(s):  
Daniela Belli Dell'Amico ◽  
Consuelo Bradicich ◽  
Fausto Calderazzo ◽  
Alessandro Guarini ◽  
Luca Labella ◽  
...  
Keyword(s):  
Molecular Structures ◽  
X Ray ◽  
Crystal And Molecular Structures ◽  
3D Elements

Lewis-Base Adducts of Group 1B Metal(I) Compounds. XXI The Crystal and Molecular Structures of the Unsolvated Forms of Dibromotris(triphenylphosphine)dicopper(I) and 'step' Tetrabromotetrakis(triphenyl-phosphine)tetracopper(I)

1985 ◽  
Vol 38 (8) ◽  
pp. 1243 ◽  
Author(s):  
JC Dyason ◽  
LM Engelhardt ◽  
C Pakawatchai ◽  
PC Healy ◽  
AH White
Keyword(s):  
Single Crystal ◽  
Crystal Structures ◽  
Molecular Structures ◽  
Lewis Base ◽  
Crystal Data ◽  
X Ray Diffraction ◽  
Triphenyl Phosphine ◽  
X Ray ◽  
Crystal And Molecular Structures

The crystal structures of the title compounds have been determined by single-crystal X-ray diffraction methods at 295 K. Crystal data for (PPh3)2CuBr2Cu(PPh3) (1) show that the crystals are iso-morphous with the previously studied chloro analogue, being monoclinic, P21/c, a 19.390(8), b 9.912(5), c 26.979(9) Ǻ, β 112,33(3)°; R 0.043 for No 3444. Cu( trigonal )- P;Br respectively are 2.191(3); 2.409(2), 2.364(2) Ǻ. Cu(tetrahedral)- P;Br respectively are 2.241(3), 2.249(3); 2.550(2), 2.571(2) Ǻ. Crystals of 'step' [PPh3CuBr]4 (2) are isomorphous with the solvated bromo and unsolvated iodo analogues, being monoclinic, C2/c, a 25.687(10), b 16.084(7), c 17.815(9) Ǻ, β 110.92(3)°; R 0.072 for No 3055. Cu( trigonal )- P;Br respectively are 2.206(5); 2.371(3), 2.427(2) Ǻ. Cu(tetrahedral)- P;Br are 2.207(4); 2.446(2), 2.676(3), 2.515(3) Ǻ.

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