Darstellung, Charakterisierung und Röntgenstrukturanalyse von η5 -Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, Cp*Re(CO)(SMe)2 / Preparation, Characterization and X-Ray Structure Analysis of η5-Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, Cp*Re(CO)(SMe)2
1987 ◽
Vol 42
(6)
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pp. 739-745
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Keyword(s):
X Ray
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Abstract Reaction of the tetrahydrofuran-stabilized 16-electron complex fragment [Cp*Re(CO)2] with dimethyl disulfide, MeSSMe, leads to the diamagnetic title compound, Cp*Re(CO)(SMe)2 , which was characterized by mass, IR and NMR spectra and by an X-ray crystal structure analysis**. The two methylsulfido ligands are bent (angles Re-S-CH3 114.1(3)°) and turned away from the Cp* ring. The Re - S-bond distances are 227.0(2) pm.
1999 ◽
Vol 54
(7)
◽
pp. 858-862
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Keyword(s):
2005 ◽
Vol 2005
(4)
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pp. 238-239
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1979 ◽
Vol 34
(2)
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pp. 217-223
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Keyword(s):