3,3’’-Bis(saccharin-6-ylmethyl)-1,1’:3’,1’’-terphenyl – Precursor of A New Tetradendate Bis-bridging Ligand

2012 ◽  
Vol 67 (10) ◽  
pp. 1070-1080 ◽  
Author(s):  
Stefan Buck ◽  
Gerhard Maas
Keyword(s):  
Crystal Structure ◽  
Structure Analysis ◽  
Title Compound ◽  
Crystal Structure Analysis ◽  
X Ray ◽  
Bridging Ligand ◽  
Coordination Sites ◽  
Dinuclear Ruthenium

The title compound (H2tpsac) was synthesized from 6-bromosaccharin and 3,3’’-bis(bromomethyl)- m-terphenyl. The ability of tpsac to serve as a tetradentate bis-bridging ligand was demonstrated by the formation of the dinuclear ruthenium(I,I) complexes [Ru2(CO)5(μ,μ-tpsac)]2, [Ru2(CO)4(μ,μ-tpsac)]n, [Ru2(CO)4(PPh3)2(μ,μ-tpsac)], and [Ru2(CO)5(PPh3)(μ,μ-tpsac)]. An X-ray crystal structure analysis of [Ru2(CO)4(PPh3)2(μ,μ-tpsac)] showed the head-to-tail (or 1,1) arrangement of the two saccharinate coordination sites.

4-(Bromomethyl)benzophenone

2007 ◽  
Vol 63 (3) ◽  
pp. o1188-o1189 ◽  
Author(s):  
Wei-Jian Xu ◽  
Yang-Ling Zang ◽  
Guo-Liang Wu ◽  
Sheng-Pei Su ◽  
De-Yue Qiu
Keyword(s):  
Crystal Structure ◽  
Carbon Tetrachloride ◽  
Dihedral Angle ◽  
Structure Analysis ◽  
Title Compound ◽  
Crystal Packing ◽  
Crystal Structure Analysis ◽  
X Ray ◽  
Compound C ◽  
Phenyl Rings

The title compound, C14H11BrO, was synthesized by the reaction of 4-methylbenzophenone and bromine in carbon tetrachloride. X-ray crystal structure analysis reveals that the benzene and phenyl rings form a dihedral angle of 59.53 (6)°, and the crystal packing is stabilized by intermolecular C—H...π interactions.

(1aR,2aS,5aS,5bS)-Perhydro-4H-oxireno[3,4]cyclopenta[1,2-b]furan-4-one

2007 ◽  
Vol 63 (3) ◽  
pp. o1359-o1360
Author(s):  
Christian Peifer ◽  
Melanie Tschertsche ◽  
Dieter Schollmeyer ◽  
Stefan Laufer
Keyword(s):  
Crystal Structure ◽  
Structure Analysis ◽  
Title Compound ◽  
Crystal Structure Analysis ◽  
Epoxide Group ◽  
X Ray ◽  
Compound C ◽  
Lactone Group

The structure of the title compound, C7H8O3, was determined in the course of our studies of the synthesis of cyclopenta[1,2-b]furan-4-one derivatives. The molecule has four chiral C atoms. The X-ray crystal structure analysis shows the compound to possess an epoxide group with an endo orientation with respect to the lactone group.

Synthesis and X-ray Crystal Studies of 6-(2-chlorophenyl)-3-methyl[1,2,4] triazolo[4,5-b][1,3,4]thiadiazole

2005 ◽  
Vol 2005 (4) ◽  
pp. 238-239 ◽  
Author(s):  
Shivananju Nanjunda-Swamy ◽  
Basappa ◽  
Gangadharaiah Sarala ◽  
Basappa Prabhuswamy ◽  
Sridhar M. Anandalwar ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Structure Analysis ◽  
Title Compound ◽  
Molecular Hydrogen ◽  
Crystal Structure Analysis ◽  
Spectroscopic Techniques ◽  
Space Group ◽  
X Ray ◽  
Cell Parameters

The compound 6-(2-chlorophenyl)-3-methyl[1,2,4]triazolo[4,5-b][1,3,4]thiadiazole, was synthesised using different reagents and conditions, characterised by spectroscopic techniques and finally confirmed by X-ray crystal structure analysis. The title compound crystallises in monoclinic class under the space group P21/c with cell parameters, a=10.6710 (6)Å, b=7.3660 (4)Å, c=14.3900 (8)Å, β=110.403 (3)°, Z=2 and R1= 0.0396 for 2715 reflections [I>2ΣI]. The structure exhibits inter-molecular hydrogen bonding.

scholarly journals Thermally Unstable 5-(9-Anthrylmethyl)-10-methyl-5,10-dihydrophenazine

1999 ◽  
Vol 23 (2) ◽  
pp. 72-73
Author(s):  
Akira Sugimoto ◽  
Keisuke Matsumoto ◽  
Hideyuki Maruyama ◽  
Kazuhiko Mizuno ◽  
Kaku Uehara
Keyword(s):  
Crystal Structure ◽  
Aromatic Ring ◽  
Structure Analysis ◽  
Title Compound ◽  
Crystal Structure Analysis ◽  
Orbital Interaction ◽  
X Ray

The title compound in refluxing toluene decomposed to 9-anthrylmethyl derivatives and phenazine as major products upon cleavage of the N–CH2 bond; the orbital interaction of which with π-orbitals of the aromatic ring was suggested by the X-ray crystal structure analysis.

Darstellung, Charakterisierung und Röntgenstrukturanalyse von η5 -Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, Cp*Re(CO)(SMe)2 / Preparation, Characterization and X-Ray Structure Analysis of η5-Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, Cp*Re(CO)(SMe)2

1987 ◽  
Vol 42 (6) ◽  
pp. 739-745 ◽  
Author(s):  
Max Herberhold ◽  
Bertram Schmidkonz ◽  
Manfred L. Ziegler ◽  
Orhan Serhadle
Keyword(s):  
Crystal Structure ◽  
Structure Analysis ◽  
Title Compound ◽  
Nmr Spectra ◽  
Dimethyl Disulfide ◽  
Crystal Structure Analysis ◽  
Ir And Nmr Spectra ◽  
X Ray ◽  
Complex Fragment

Abstract Reaction of the tetrahydrofuran-stabilized 16-electron complex fragment [Cp*Re(CO)2] with dimethyl disulfide, MeSSMe, leads to the diamagnetic title compound, Cp*Re(CO)(SMe)2 , which was characterized by mass, IR and NMR spectra and by an X-ray crystal structure analysis**. The two methylsulfido ligands are bent (angles Re-S-CH3 114.1(3)°) and turned away from the Cp* ring. The Re - S-bond distances are 227.0(2) pm.

Tetraphenylarsonium diisothiocyanatodibromonickelate(II)

2006 ◽  
Vol 62 (5) ◽  
pp. m1014-m1015
Author(s):  
S. S. Singh ◽  
R. S. Prasad ◽  
Shailesh Upreti ◽  
N. K. Jha ◽  
A. Ramanan
Keyword(s):  
Crystal Structure ◽  
Structure Analysis ◽  
Title Compound ◽  
Crystal Structure Analysis ◽  
Mixed Ligand ◽  
Asymmetric Unit ◽  
X Ray ◽  
Twofold Axis ◽  
Compound C

Use of mixed-ligand (bromide and thiocyanate ions) coordination with nickel has led to the crystallization of the title compound, (C24H20As)2[Ni(NCS)2Br2]. X-ray crystal structure analysis reveals that the asymmetric unit contains one (C6H5)4As+ cation and one half [Ni(NCS)2Br2]2− anion, the latter lying on a crystallographic twofold axis.

scholarly journals Photochemical syntheses. XI. X-Ray analysis and molecular structure of 1,8-Diphenyl-1a,2,7,7a-tetrahydro-1,2,7-metheno-1H cyclopropa[b]naphthalene, a naphthalene-diphenylacetylene photoadduct

1976 ◽  
Vol 29 (8) ◽  
pp. 1851 ◽  
Author(s):  
C Kowala ◽  
BJ Poppleton ◽  
WHF Sasse
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Structure Analysis ◽  
Title Compound ◽  
Crystal Structure Analysis ◽  
X Ray

The structure of the title compound(1) has been confirmed by X-ray crystal structure analysis.

Synthese und Einkristall-Strukturanalyse des Oxidnitrits K5AgO2(NO2)2 / Synthesis and Single Crystal Structure Analysis of the Oxide Nitrite K5AgO2(NO2)2

1993 ◽  
Vol 48 (2) ◽  
pp. 230-232 ◽  
Author(s):  
Thomas Bremm ◽  
Martin Jansen
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Structure Analysis ◽  
Title Compound ◽  
Crystal Structure Analysis ◽  
Single Crystal Structure ◽  
Single Crystal Diffraction ◽  
X Ray ◽  
Perovskite Type ◽  
Single Crystal Structure Analysis

AbstractThe title compound has been characterized by X-ray powder and single crystal diffraction: Pbam. a = 715.8(1), b = 1393.1(2), c = 539.4(1) pm; Z = 2; 1088 diffractometer data; R = 0.087, Rw = 0.083. The crystal structure is a variant of the anti-perovskite type of structure. The NO2- anion is rotationally disordered.

scholarly journals Preparative-scale HPLC Resolution of Metallacyclic η3-Allyltricarbonyliron Complexes and Determination of the Absolute Configuration by X-Ray Crystal Structure Analysis

1999 ◽  
Vol 23 (9) ◽  
pp. 578-579
Author(s):  
Rainer Schobert ◽  
Hermann Pfab ◽  
Jutta Böhmer ◽  
Frank Hampel ◽  
Andreas Werner
Keyword(s):  
Crystal Structure ◽  
Silica Gel ◽  
Structure Analysis ◽  
Absolute Configuration ◽  
Crystal Structure Analysis ◽  
Preparative Scale ◽  
X Ray ◽  
The Absolute

Racemates of (η3-allyl)tricarbonyliron lactone complex Fe(CO)3{η1:η3-C(O)XCH2CHCMeCH2} 1a (X = O) and (η3-allyl)tricarbonyliron lactam complex 2a (X = NMe) are resolved on a preparative scale by HPLC on cellulose tris(3,5-dimethylphenyl)carbamate/silica gel RP-8 and the absolute configuration of (-)-2a is determined by X-ray crystal structure analysis.

Second-Generation Inhibitors for the Metalloprotease Neprilysin Based on Bicyclic Heteroaromatic Scaffolds: Synthesis, Biological Activity, and X-Ray Crystal-Structure Analysis

2005 ◽  
Vol 88 (4) ◽  
pp. 731-750 ◽  
Author(s):  
Stefan Sahli ◽  
Brian Frank ◽  
W. Bernd Schweizer ◽  
François Diederich ◽  
Denise Blum-Kaelin ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Biological Activity ◽  
Structure Analysis ◽  
Second Generation ◽  
Crystal Structure Analysis ◽  
X Ray
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