Notizen: The Auration of Dimethylsulfide

Dimethylsulfide reacts with (triphenylphosphine) gold(I) trifluoromethanesulfonate to give quantitative yields of the mixed ligand complex [(Ph3P)Au(SMe2)]+O3SCF3- (1). The structure of compound 1 has been determined by an X-ray crystal structure analysis. The lattice contains independent anions and (monomeric) cations, which have a linear P-Au-S axis. Attempts to produce a binuclear. dicationic complex through addition of a second equivalent of [(Ph3P)Au]+ failed and lead to decomposition products including [(Ph3P)2Au]+O3SCF3-.

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ChemInform Abstract: A NOVEL MIXED LIGAND COMPLEX FROM THE COCONDENSATION OF COBALT VAPOR WITH A MIXTURE OF THE MONODENTATE LIGAND (CH3)2NPF2 AND THE BIDENTATE LIGAND CH3N(PF2)2- THE X-RAY CRYSTAL STRUCTURE OF (CH3N(PF2)2)3CO2(PF2N(CH3)2)2

Chemischer Informationsdienst ◽

10.1002/chin.197840293 ◽

1978 ◽

Vol 9 (40) ◽

Author(s):

M. CHANG ◽

M. G. NEWTON ◽

R. B. KING ◽

T. J. LOTZ

Keyword(s):

Crystal Structure ◽

Mixed Ligand Complex ◽

Bidentate Ligand ◽

Mixed Ligand ◽

Monodentate Ligand ◽

Ligand Complex ◽

X Ray

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ChemInform Abstract: Chemical Oxidation of Binuclear Rhodium(I) Complexes with Silver Salts. Synthesis, X-Ray Crystal Structure, and Electrochemical Properties of the Rh4+ 2 Mixed-Ligand Complex Rh2(Form)2(O2CCF3)2(H2O)2·0.5 C6H6 (Form: N,N′-Di-p-tolylfor

ChemInform ◽

10.1002/chin.198721253 ◽

1987 ◽

Vol 18 (21) ◽

Author(s):

P. PIRAINO ◽

G. BRUNO ◽

G. TRESOLDI ◽

S. LO SCHIAVO ◽

P. ZANELLO

Keyword(s):

Crystal Structure ◽

Electrochemical Properties ◽

Mixed Ligand Complex ◽

Chemical Oxidation ◽

Mixed Ligand ◽

Ligand Complex ◽

X Ray ◽

Silver Salts

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Chemical oxidation of binuclear rhodium(I) complexes with silver salts. Synthesis, x-ray crystal structure, and electrochemical properties of the rhodium [Rh24+] mixed-ligand complex Rh2(Form)2(O2CCF3)2(H2O)2.0.5C6H6 (Form = N,N'-di-p-tolylformamidinate anion)

Inorganic Chemistry ◽

10.1021/ic00248a019 ◽

1987 ◽

Vol 26 (1) ◽

pp. 91-96 ◽

Cited By ~ 28

Author(s):

Pasquale Piraino ◽

Giuseppe Bruno ◽

Giuseppe Tresoldi ◽

Sandro Lo Schiavo ◽

Piero Zanello

Keyword(s):

Crystal Structure ◽

Electrochemical Properties ◽

Mixed Ligand Complex ◽

Chemical Oxidation ◽

Mixed Ligand ◽

Ligand Complex ◽

X Ray ◽

Silver Salts

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A novel mixed ligand complex from the cocondensation of cobalt vapor with a mixture of the monodentate ligand (CH3)2NPF2 and the bidentate ligand CH3N(PF2)2: The X-ray crystal structure of [CH3N(PF2)2]3Co2[PF2N(CH3)2]2

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)87387-9 ◽

1978 ◽

Vol 28 ◽

pp. L153-L154 ◽

Cited By ~ 10

Author(s):

M. Chang ◽

M.G. Newton ◽

R.B. King ◽

T.J. Lotz

Keyword(s):

Crystal Structure ◽

Mixed Ligand Complex ◽

Bidentate Ligand ◽

Mixed Ligand ◽

Monodentate Ligand ◽

Ligand Complex ◽

X Ray

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Tetraphenylarsonium diisothiocyanatodibromonickelate(II)

Acta Crystallographica Section E Structure Reports Online ◽

10.1107/s160053680601021x ◽

2006 ◽

Vol 62 (5) ◽

pp. m1014-m1015

Author(s):

S. S. Singh ◽

R. S. Prasad ◽

Shailesh Upreti ◽

N. K. Jha ◽

A. Ramanan

Keyword(s):

Crystal Structure ◽

Structure Analysis ◽

Title Compound ◽

Crystal Structure Analysis ◽

Mixed Ligand ◽

Asymmetric Unit ◽

X Ray ◽

Twofold Axis ◽

Compound C

Use of mixed-ligand (bromide and thiocyanate ions) coordination with nickel has led to the crystallization of the title compound, (C24H20As)2[Ni(NCS)2Br2]. X-ray crystal structure analysis reveals that the asymmetric unit contains one (C6H5)4As+ cation and one half [Ni(NCS)2Br2]2− anion, the latter lying on a crystallographic twofold axis.

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Preparative-scale HPLC Resolution of Metallacyclic η3-Allyltricarbonyliron Complexes and Determination of the Absolute Configuration by X-Ray Crystal Structure Analysis

Journal of Chemical Research ◽

10.1177/174751989902300930 ◽

1999 ◽

Vol 23 (9) ◽

pp. 578-579

Author(s):

Rainer Schobert ◽

Hermann Pfab ◽

Jutta Böhmer ◽

Frank Hampel ◽

Andreas Werner

Keyword(s):

Crystal Structure ◽

Silica Gel ◽

Structure Analysis ◽

Absolute Configuration ◽

Crystal Structure Analysis ◽

Preparative Scale ◽

X Ray ◽

The Absolute

Racemates of (η3-allyl)tricarbonyliron lactone complex Fe(CO)3{η1:η3-C(O)XCH2CHCMeCH2} 1a (X = O) and (η3-allyl)tricarbonyliron lactam complex 2a (X = NMe) are resolved on a preparative scale by HPLC on cellulose tris(3,5-dimethylphenyl)carbamate/silica gel RP-8 and the absolute configuration of (-)-2a is determined by X-ray crystal structure analysis.

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