Exchange Interaction in a Dinuclear Iron(III) Complex of a Heptadentate Schiff Base: Synthesis, Crystal Structure and Magnetic Properties

2005 ◽  
Vol 60 (7) ◽  
pp. 727-731 ◽  
Author(s):  
C. T. Zeyrek ◽  
A. Elmali ◽  
Y. Elerman
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Schiff Base ◽  
Exchange Interaction ◽  
Hamiltonian Operator ◽  
Antiferromagnetic Coupling ◽  
Iron Ions ◽  
Spin Hamiltonian ◽  
Dinuclear Iron

Synthesis, crystallographic characterization and magnetic properties of the new dinuclear iron(III) complex Fe2L(OCH3)Cl2 (L=1,3-bis[N-(3,5-dichloro-2-hydroxybenzylidene)-2-aminoethyl]-2-(3,5- dichlo ro-2-hydroxyphenyl)imidazolidine) are reported. The structure consists of dinuclear units. The two iron(III) atoms are asymmetrically bridged by a phenoxo and a methoxo group. The iron(III) centers are separated by 3.133(2) Å . The Magnetic susceptibility of the complex was measured over the range 5 - 298 K and the observed data were successfully simulated by the equation based on the spin-Hamiltonian operator H = −JS⃗1.S⃗2. Magnetic susceptibility measurements indicate very weak antiferromagnetic coupling between the iron ions with J = −10.8 cm−1 and g = 2.0.

Synthesis, Crystal Structure, and Spectroscopic and Magnetic Properties of a Dinuclear Iron(III) Complex Asymmetrically Bridged by a Phenoxo and a Methoxo Group

2005 ◽  
Vol 60 (9) ◽  
pp. 940-944 ◽  
Author(s):  
C. T. Zeyrek ◽  
A. Elmali ◽  
Y. Elerman
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Structural Parameters ◽  
Hamiltonian Operator ◽  
Antiferromagnetic Coupling ◽  
Iron Ions ◽  
Spin Hamiltonian ◽  
Dinuclear Iron ◽  
Super Exchange Interaction

A new dinuclear iron(III) derivative Fe2L(OCH3)Cl2 (L = 1,3-bis[N-(5-chloro-2-hydroxybenzylidene)- 2-aminoethyl]-2-(5-chloro-2-hydroxyphenyl)imidazolidine) has been synthesized, it crystal structure determined and magnetically characterized. The two iron(III) ions are asymmetrically bridged by a phenoxo and a methoxo group and separated by 3.150(2)Å . The magnetic susceptibility of the complex was measured over the range 5 - 349.3 K and the observed data were successfully simulated by the equation based on the spin-Hamiltonian operator , indicating very weak antiferromagnetic coupling between the iron ions with J = −11.3 cm−1. The magnetic and structural parameters of the compound and the nature of the magnetic super-exchange interaction are discussed and compared with data of similar dinuclear iron(III) complexes.

Crystal Structure and Magnetic Properties of a Dinuclear Iron(III) Doubly Oxygen Bridged Schiff Base Complex

2003 ◽  
Vol 58 (5) ◽  
pp. 433-437 ◽  
Author(s):  
A. Elmali ◽  
Y. Elerman ◽  
C. T. Zeyrek ◽  
I. Svoboda
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Schiff Base ◽  
Schiff Base Complex ◽  
Inversion Center ◽  
Temperature Dependent ◽  
Triclinic Space Group ◽  
Dinuclear Iron ◽  
Binuclear Unit

[Fe(L)Cl]2 (L = N-(4-methylphenyl)-3-methoxy-salicylaldimimine) was synthesized and its crystal structure determined. [C30H26Cl2Fe2N2O6], triclinic, space group P 1̄ , a = 9.278(2), b = 9.4050(10), c = 10.489(2) Å , α = 64.43(2), β = 74.540(10), γ = 62.40(2)° , V = 729.1(2) Å 3, Z = 1. Two identical [Fe(L)Cl] fragments, related by an inversion center, are connected by two bridging O atoms to form a binuclear unit. The iron(III) centers are separated by 3.196(2) Å and weakly antiferromagnetically coupled (J = -10.1(1) cm-1), as derived from temperature-dependent magnetic susceptibility measurements in the range 5.1-283.5 K.

X-Ray Structure and Magnetic Properties of the Tetracupferronato-bis(μ-methoxy)-diiron(III) Complex

1995 ◽  
Vol 50 (11) ◽  
pp. 1587-1590 ◽  
Author(s):  
Yalcin Elerman ◽  
Mehmet Kabak ◽  
Ingrid Svoboda ◽  
Hartmut Fuess ◽  
Klaus Griesar ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Exchange Interaction ◽  
Monoclinic Space Group ◽  
Antiferromagnetic Exchange ◽  
Temperature Dependent ◽  
Space Group ◽  
X Ray ◽  
Antiferromagnetic Exchange Interaction

The tetracupferronato-bis(μ-methoxy)-diiron(III) complex has been synthesized in acetonitrile and its crystal structure determined. C26H26N8O10Fe2, monoclinic, space group C2/c, a =18.425(3), b = 12.999(2), c = 15.046(3) Å, β = 124.66(2)°,V = 2964(1) Å3, Z = 4, wR(2) = 0.097 from 1491 reflections (F2). Two iron(III) atoms are at special positions in six-fold coordination, bridged by O with a Fe-O-Fe angle of 102.4(1)° and a distance between two iron(III) centers of 3.075(1) Å. Temperature-dependent magnetic susceptibility measurements reveal a antiferromagnetic exchange interaction (J = -14 cm-1) between the iron(III) centers.

scholarly journals Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

Metals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 849 ◽  
Author(s):  
Ivan Nemec ◽  
Ingrid Svoboda ◽  
Radovan Herchel
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Schiff Base ◽  
Spin Crossover ◽  
Theoretical Calculations ◽  
Magnetic Behavior ◽  
Schiff Base Complexes ◽  
Mononuclear Iron ◽  
Mononuclear Complexes

The synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA2− is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations.

Crystal Structure and Magnetic Properties of a (μ-Hydroxo)(μ-acetato) Dicopper(II) Complex

2000 ◽  
Vol 55 (7) ◽  
pp. 561-566 ◽  
Author(s):  
E. Kavlakoglu ◽  
A. Elmali ◽  
Y. Elerman ◽  
H. Fuess
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Antiferromagnetic Coupling ◽  
Monoclinic Space Group ◽  
Helium Temperature ◽  
Temperature Dependent ◽  
Bridging Ligands ◽  
Square Planar ◽  
Super Exchange Interaction

[Cu2(L)(O2CMe)] · H2O (L = 1,3-Bis(2-Hydroxy-1-napthylideneamino)propan-2-ol) was synthesized and its crystal structure determined. (C27H23N2O5Cu2).H2O , monoclinic, space group P21/c, a = 11.795(3), b = 17.988(5), c = 12.005(6) Å, β = 109.99(3)°, V = 2393(2) Å3, Z = 4. Two copper(II) ions in a square-planar coordination are bridged by alkoxide and acetate oxygen atoms to form a dinuclear unit. The metal coordination sphere is four-coordinate, planar with an NO3 donor set. The dihedral angle between the two coordination planes is 6.34(9)°. The copper(II) centers are separated by 3.492(2) Å and weakly antiferromagnetically coupled (-2J = 163.6 cm-1 ), which follows from temperature-dependent magnetic susceptibility measurements in the temperature range 4.6 to 310 K. The Cu-O-Cu angle is 133.5(1)° in the super-exchange pathway. The weak antiferromagnetic coupling of the complex is interpreted in terms of countercomplementary effects of the different bridging ligands which participate in the super-exchange interaction. The magnetic moment at 310 K is ca. 2.7 B. M., but 0.2 B. M. at 4.6 K. The magnetic susceptibility is at a maximum near 140 K and decreases rapidly as the temperature is lowered to liquid helium temperature.

Magnetic Properties and Crystal Structure of a Dinuclear Iron(III) Complex

2001 ◽  
Vol 56 (9) ◽  
pp. 897-900 ◽  
Author(s):  
A. Elmali ◽  
Y. Elerman ◽  
I. Svoboda
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Liquid Helium ◽  
Magnetic Moment ◽  
Helium Temperature ◽  
Temperature Dependent ◽  
Triclinic Space Group ◽  
Dinuclear Iron ◽  
Binuclear Unit

Abstract [FeL(MeOH)Cl]2 (L = N-(5-methylphenyl)-3-methoxysalicylaldimine) was synthesized and its crystal structure determined, [C30H26Cl2Fe2N2O6], triclinic, space group P1̄, a = 7.481(2), b = 9.436(2), c = 10.961(2) Å, α= 69.790(10), β= 82.440(10), γ= 83.690(10)°, V=718.1(3) Å3 , Z = 1. Two identical [FeLCl] fragments, related by an inversion centre, are connected by two bridging O atoms to form a binuclear unit. The iron(III) centers are separated by 3.196(2) Å and weakly antiferromagnetically coupled (J = -10.4(1) cm-1), which follows from temperature-dependent magnetic susceptibility measurements in the range 5.1 to 275.6 K. The magnetic moment at 275.6 K is ca. 7.02 B. M., but 0.99 B. M. at 5.1 K. The magnetic susceptibility is at a maximum near 80 K and decreases rapidly as the temperature is lowered to liquid helium temperature.

Synthesis, Crystal Structure and Magnetic Properties of a Novel GdIII -CuII Heterodinuclear Complex

2000 ◽  
Vol 55 (12) ◽  
pp. 1131-1136 ◽  
Author(s):  
H. Kara ◽  
Y. Elerman ◽  
K. Prout
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Exchange Interaction ◽  
Spin Exchange ◽  
Copper Ion ◽  
Hamiltonian Operator ◽  
Axial Position ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Oxygen Atoms

Preparation, crystal structure and magnetic properties of a heterodinuclear complex, LCu(Me2CO)Gd(NO3)3 (L = (N,N′-bis(3-methoxysalicylidene)propane- 1,2-diamine) are reported. The crystal structure of the complex was determined by X-ray diffraction methods at 200 K. (C19H22N2O4 )Cu(C3H6O)Gd(NO3)3, monoclinic, space group P21/c, with a = 9.795(9), b = 18.763(3), c = 15.579(2) Å , β = 95.297(2) V = 2850.9(7) Å3 and Z= 4. The central region of the complex is occupied by Cu(II) and Gd(III) ions which are bridged by two phenolato oxygen atoms of the ligand. The copper ion adopts a square-based 4+1 coordination mode, the equatorial N2O2 donors being afforded by the ligand while the axial position is occupied by an oxygen atom of the acetone molecule. The Gd(III) ion is deca-coordinated. In addition to the two phenolate oxygen atoms, the coordination sphere contains two oxygen atoms of the OMe side arms of L and six oxygen atoms from the three bidentate nitrate ions. The Gd... Cu separation is 3.425(3) Å and the dihedral angle between the GdO(l)Cu and GdO(2)Cu planes is 164.8°. The magnetic susceptibility of the complex was measured over the range 5 - 350 K and the observed data were successfully simulated by the equation based on the spin-Hamiltonian operator (H = -JSCu · SGd), giving the exchange integral J(Cu-Gd) = 5.6(1) cm-1. This indicates a weak ferromagnetic spin exchange interaction. The nature of the magnetic super-exchange interaction of the title compound is compared with similar [Gd(III)-Cu(II)] heterodinuclear complexes.

A Dimeric Mn(III) Complex of a Quadridentate Schiff Base Ligand. Synthesis, Structure and Ferromagnetic Exchange

2008 ◽  
Vol 63 (1) ◽  
pp. 6-10 ◽  
Author(s):  
Hulya Kara Balikesir
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Schiff Base ◽  
Low Temperature ◽  
Schiff Base Ligand ◽  
Dinuclear System ◽  
Ferromagnetic Exchange ◽  
Ligand Synthesis ◽  
Oxygen Atoms

The synthesis, crystal structure and magnetic properties of [Mn(III)L(H2O)]2(H2O)(ClO4) (1)(L = N,N'-bis(rac-5-chlorosalicylidenato)-1,2-diaminopropane) are reported. Compound 1 consists of a structurally dinuclear system in which two Mn ions are bridged by the oxygen atoms of μ-phenoxo ligands. Low temperature magnetic susceptibility measurements show a ferromagnetic intra-dimer interaction with J = +1.75 cm−1, g = 2.01 and α = −0.32.

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