Syntheses and structural characterization of coordination polymers of Cu(II) and Zn(II) chlorobenzoates and bis(pyridin-4-yl)-substituted species

2015 ◽  
Vol 70 (2) ◽  
pp. 95-100 ◽  
Author(s):  
Fu-Lin Mao ◽  
Jian-Qing Tao ◽  
Chun-Hua Dai
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Network Structure ◽  
Structural Characterization ◽  
Chain Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
A Chain

AbstractThe reaction of Cu(II) nitrate with sodium 2-chlorobenzoate (NaL1) and (E)-1,2-di(pyridin-4-yl)ethene (dpe) yields a new complex [Cu(L1)2(dpe)(H2O)] (1). When Zn(II) nitrate reacts with sodium 4-chlorobenzoate (NaL2) and 1,2-di(pyridin-4-yl)ethane (dpa), [Zn(L2)2(dpa)]·CH3OH (2) is obtained. Complexes 1 and 2 have been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. 1 shows a 3D CdS network structure with uninodal 4-connected (65.8) topology; complex 2 displays a chain structure.

Syntheses, crystal structures, and characterization of two Mn(II) coordination polymers with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands

2016 ◽  
Vol 71 (8) ◽  
pp. 869-874 ◽  
Author(s):  
Gao-Feng Wang ◽  
Xiao Zhang ◽  
Shu-Wen Sun ◽  
Hong Sun ◽  
Xia Yang ◽  
...  
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
X Ray Diffraction ◽  
X Ray ◽  
Distorted Octahedral ◽  
Elemental Analyses

AbstractTwo Mn(II) complexes, {[Mn(BIPMO)2Cl2] · 2(H2O)}n (1) and {[Mn(BIPMO)2(SCN)2] · 2(CH3OH)}n (2) (BIPMO = bis(4-(1H-imidazol-1-yl)phenyl)methanone) with V-shaped BIPMO ligands, were synthesized and characterized by IR spectroscopy and elemental analyses along with their single-crystal X-ray diffraction analyses. The Mn(II) ions in 1 and 2 are both six-coordinated to four nitrogen atoms of four BIPMO ligands and two anions (Cl− for 1, and SCN− for 2) to form a distorted octahedral geometry.

Synthesis and Structural Characterization of a Cu(II) Coordination Polymer from N1,N2-Di(pyridin-4-yl)oxalamide

2014 ◽  
Vol 69 (9-10) ◽  
pp. 1045-1049
Author(s):  
Hai-Wei Kuai ◽  
Tao Hu ◽  
Ding-Yun Jiang ◽  
Yun-Hua Qian ◽  
Deng-Hao Li
Keyword(s):  
Hydrogen Bonding ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Chain Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Triclinic System ◽  
A Chain ◽  
2D Network

Abstract The reaction of Cu(NO3)2·3H2O with N1,N2-di(pyridin- 4-yl)oxalamide (L) and KSCN in the presence of DMF by the layering method gives rise to a new complex [Cu(L2)(SCN)2(DMF)2]n (1). Complex 1 has been characterized by single-crystal and powder X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. It crystallizes in the triclinic system with space group P1̅ and shows a chain structure. Delicate N-H···O hydrogen bonding exists in individual units, and adjacent chains are linked by intermolecular interactions, resulting in an extended 2D network.

Syntheses and structural characterization of manganese and cadmium coordination polymers constructed with bis(4-(1H-imidazol-1-yl)phenyl)methanone and dicarboxylate ligands

2020 ◽  
Vol 75 (9-10) ◽  
pp. 859-863
Author(s):  
Gao-Feng Wang ◽  
Shu-Wen Sun ◽  
Hong Sun ◽  
Bing-Wei Chang ◽  
Jing Song ◽  
...  
Keyword(s):  
Ir Spectroscopy ◽  
Coordination Polymers ◽  
Structural Characterization ◽  
Topological Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Elemental Analyses ◽  
Butanedioic Acid ◽  
Solvothermal Methods

AbstractTwo coordination polymers (CPs), [Mn(bipmo)(pbtda)(H2O)]n (1), {[Cd(bipmo)(btda)]·2(H2O)]}n (2), (bipmo = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2pbtda = 2-phenylbutanedioic acid, H2btda = butanedioic acid), were synthesized by solvothermal methods. The products have been characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction. The topological structure of 1 is based on 2-nodal nets with the Schläfli symbol {63}{69·8}, while that of 2 features a system with a sixfold penetration with the Schläfli symbol {66}.

A Zn(II) complex from an imidazolyl-thiophene ligand: synthesis, structural characterization, and fluorescence

2018 ◽  
Vol 73 (6) ◽  
pp. 407-411
Author(s):  
Hai-Wei Kuai ◽  
Tao Hu ◽  
Ding-Yun Jiang ◽  
Xiao-Hong Zhu
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Single Crystals ◽  
Network Structure ◽  
Structural Characterization ◽  
Hydrothermal Reaction ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
Space Group ◽  
X Ray

AbstractThe hydrothermal reaction of ZnSO4 with 2,5-di(1H-imidazol-4-yl)thiophene (L) at 100°C yields a new complex [Zn(L)(SO4)]n (1). Complex 1 has been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. It crystallizes in the monoclinic system, space group P21/c with Z=4, and shows a (44.62) network structure. Complex 1 shows fluorescence. Single crystals of L·2H2O were accidentally obtained in hydrothermal reaction attempts of L with MnCl2 at 120°C.

Synthesis and structural characterization of a Ni(II) coordination polymer with a tripodal 4-imidazolyl-functional ligand

2019 ◽  
Vol 74 (11-12) ◽  
pp. 857-860
Author(s):  
Hai-Wei Kuai ◽  
Xiao-Hong Zhu ◽  
Ding-Yun Jiang ◽  
Xiao-Chun Cheng ◽  
Deng-Hao Li
Keyword(s):  
Infrared Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Network Structure ◽  
Structural Characterization ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray

Abstract1,3,5-Tri(1H-imidazol-4-yl)benzene (H3L) reacts with Ni(ClO4)2 · 6H2O under hydrothermal conditions at T = 100°C to yield a new complex: [Ni(H2L)2] · 5.5H2O (1). The product is characterized by single crystal and powder X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses. Complex 1 crystallizes in the monoclinic space group C2/c and exhibits a binodal (3,6)-connected 2D kgd network structure with (43)2(46.66.83) topology.

Syntheses, Spectral, Thermal And Structural Characterization Of 2-Hydroxyanilinium And 2-Amino-3-Hydroxy-Pyridinium Squarates

2007 ◽  
Vol 62 (6) ◽  
pp. 823-828
Author(s):  
Okan Zafer ◽  
Hümeyra Paşaoğlub ◽  
O. Ozan Yılan ◽  
Orhan Büyükgüngör
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Structural Characterization ◽  
Thermal Analyses ◽  
Squaric Acid ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
X Ray ◽  
Elemental Analyses

New salts of 2-hydroxyaniline and 2-amino-3-hydroxypyridine with squaric acid were synthesized and characterized by elemental analyses, IR spectroscopy and thermal analyses (TG, DTG and DTA). The crystal structures of bis(2-hydroxyanilinium) squarate, [(C6H8NO+)2(C4O4)2−] (1) and bis(2- amino-3-hydroxy-pyridinium) squarate dihydrate, [(C5H7N2O+)2(C4O4)2−] · 2 H2O (2) were determined by single crystal X-ray diffraction. Both compounds crystallize in the monoclinic system, space group P21/c. The organic ammonium squarates decompose in two thermal steps

A Co(II) complex from a pyridylamide ligand: synthesis and structural characterization

2018 ◽  
Vol 73 (3-4) ◽  
pp. 265-268
Author(s):  
Xiao-Hong Zhu ◽  
Ding-Yun Jiang ◽  
Tao Hu ◽  
Deng-Hao Li
Keyword(s):  
Thermogravimetric Analysis ◽  
Single Crystal ◽  
Structural Characterization ◽  
Hydrothermal Reaction ◽  
Chain Structure ◽  
X Ray Diffraction ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
X Ray ◽  
A Chain

Abstract The hydrothermal reaction of N3,N5-di(pyridin-4-yl)pyridine-3,5-dicarboxamide (L) with Co(NO3)2·6H2O and ErCl3·6H2O yields a new complex, {[Co(L)2(NO3)1.15(Cl)0.85]·4DMF}n (1). Complex 1 has been characterized by single-crystal and powder X-ray diffraction, IR, and elemental and thermogravimetric analysis. It crystallizes in the orthorhombic space group Fddd and shows a chain structure.

Preparation and Structural Characterization of Chain Ni (II) Coordination Polymer Material

2011 ◽  
Vol 322 ◽  
pp. 369-372
Author(s):  
Zhi Xiang Ji
Keyword(s):  
Coordination Polymer ◽  
Polymer Material ◽  
Chain Structure ◽  
Monoclinic Space Group ◽  
Dimensional Chain ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
A Chain

A chain Ni (II) coordination polymer material was prepared and characterized by elemental analysis and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group C2/c with a = 1.24348(13) nm, b = 1.29477(12) nm, c = 1.51480(17) nm and Dc = 1.401 g•cm-3. The results of structural analysis indicated that each Ni (II) ion forms six-coordinated with nitrogen atoms of pyridine and thiocyanate, and the Ni (II) coordination polymer material formed one dimensional chain structure by the interaction of pyridine rings.

scholarly journals Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid

2021 ◽  
Vol 47 (9) ◽  
pp. 593-600
Author(s):  
A. A. Lysova ◽  
V. A. Dubskikh ◽  
K. D. Abasheeva ◽  
A. A. Vasileva ◽  
D. G. Samsonenko ◽  
...  
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Coordination Polymers ◽  
Elemental Analysis ◽  
Metal Organic Frameworks ◽  
X Ray Diffraction ◽  
Phase Purity ◽  
X Ray ◽  
Metal Organic

Abstract Three new metal−organic frameworks based on scandium(III) cations and 2,5-thiophenedicarboxylic acid (H2Tdc) are synthesized: [Sc(Tdc)(OH)]·1.2DMF (I), [Sc(Tdc)(OH)]·2/3DMF (II), and (Me2NH2)[Sc3(Tdc)4(OH)2]·DMF (III) (DMF is N,N-dimethylformamide). The structures of the compounds are determined by single-crystal X-ray structure analysis (CIF file CCDC nos. 2067819 (I), 2067820 (II), and 2067821 (III)). The chemical and phase purity of compound I is proved by elemental analysis, thermogravimetry, X-ray diffraction analysis, and IR spectroscopy.

Synthesis and Characterization of the nido-Platinaborane 7,7-(PPh3)2-7-PtB10H11-11-OC(O)Me

2011 ◽  
Vol 66 (4) ◽  
pp. 387-391
Author(s):  
Jinling Miao ◽  
Yong Nie ◽  
Haiyan Chen ◽  
Daqi Wang ◽  
Markus Enders ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Hydrogen Bonds ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Chain Structure ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ir And Nmr Spectroscopy

The reaction of closo-B10H102− with PtCl2(PPh3)2 in the presence of MeCOSH afforded the title platinaborane nido-7,7-(PPh3)2-7-PtB10H11-11-OC(O)Me (1), which has been characterized by IR and NMR spectroscopy, MS, elemental analysis, and single-crystal X-ray diffraction. In contrast to the known products having exo-polyhedral Pt-S-C-O-B ring(s) from the same reaction with Ph- COSH, compound 1 has a B-acetoxy group on the open PtB4 face of the nido-PtB10 cluster. The structure of 1 features both intramolecular/intermolecular C-H· · ·O hydrogen bonds and intramolecular C-H· · ·H-B dihydrogen bonds, which link the molecules into a 1-D chain structure.

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