Synthesis and Structural Characterization of a Cu(II) Coordination Polymer from N1,N2-Di(pyridin-4-yl)oxalamide

2014 ◽  
Vol 69 (9-10) ◽  
pp. 1045-1049
Author(s):  
Hai-Wei Kuai ◽  
Tao Hu ◽  
Ding-Yun Jiang ◽  
Yun-Hua Qian ◽  
Deng-Hao Li
Keyword(s):  
Hydrogen Bonding ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Chain Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Triclinic System ◽  
A Chain ◽  
2D Network

Abstract The reaction of Cu(NO3)2·3H2O with N1,N2-di(pyridin- 4-yl)oxalamide (L) and KSCN in the presence of DMF by the layering method gives rise to a new complex [Cu(L2)(SCN)2(DMF)2]n (1). Complex 1 has been characterized by single-crystal and powder X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. It crystallizes in the triclinic system with space group P1̅ and shows a chain structure. Delicate N-H···O hydrogen bonding exists in individual units, and adjacent chains are linked by intermolecular interactions, resulting in an extended 2D network.

Preparation and Structural Characterization of Chain Ni (II) Coordination Polymer Material

2011 ◽  
Vol 322 ◽  
pp. 369-372
Author(s):  
Zhi Xiang Ji
Keyword(s):  
Coordination Polymer ◽  
Polymer Material ◽  
Chain Structure ◽  
Monoclinic Space Group ◽  
Dimensional Chain ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
A Chain

A chain Ni (II) coordination polymer material was prepared and characterized by elemental analysis and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group C2/c with a = 1.24348(13) nm, b = 1.29477(12) nm, c = 1.51480(17) nm and Dc = 1.401 g•cm-3. The results of structural analysis indicated that each Ni (II) ion forms six-coordinated with nitrogen atoms of pyridine and thiocyanate, and the Ni (II) coordination polymer material formed one dimensional chain structure by the interaction of pyridine rings.

A New 1D Coordination Polymer Constructed From a Dissymmetrical Oxamidate Ligand: Structure and Magnetic Properties

2011 ◽  
Vol 66 (3) ◽  
pp. 275-278
Author(s):  
Bao Lin Liu ◽  
Juan Dang ◽  
Ruo Jie Tao
Keyword(s):  
Magnetic Properties ◽  
Ir Spectroscopy ◽  
Chain Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Triclinic System ◽  
Ligand Structure ◽  
1D Coordination Polymer ◽  
A Chain ◽  
Complex Features

A new complex {{[Cu(oxbe)]Cu(tmen)}2・2ClO4}n (H3oxbe = N-benzoato-Nʹ-(2-aminoethyl)- oxamido, tmen = N,N,Nʹ,Nʹ-tetramethylethylenediamine) has been synthesized and characterized by IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction, and by its magnetic properties. It crystallizes in the triclinic system, space group P¯1, with a = 1.364(2), b = 1.379(2), c = 1.516(3) nm, α = 64.402(3), β = 66.098(3), γ = 89.604(3)°, V = 2.301(7) nm3, Z = 2, Dcalcd. = 1.71 g cm−3. The structure of 1 consists of tetranuclear units. Through syn-anti carboxylate bridges, the complex features a chain structure.

Synthesis, Crystal Structure and Characterization of a 1D Polyoxometalate-based Compound: {[Pr(H2O)7][CrMo6H6O24]} · 4H2O

2008 ◽  
Vol 63 (7) ◽  
pp. 799-803 ◽  
Author(s):  
Lijie Zhao ◽  
Shuchang Shen ◽  
Haiming Yu
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Ultraviolet Spectroscopy ◽  
Supramolecular Network ◽  
X Ray Diffraction ◽  
X Ray ◽  
A Chain

A novel polyoxometalated-based compound, {[Pr(H2O)7][CrMo6H6O24]} · 4H2O, was prepared and characterized by elemental analysis, infrared and ultraviolet spectroscopy, TG measurement and single crystal X-ray diffraction. A chain-like coordination polymer is formed from a heteropolyanion [CrMo6H6O24]3− as a building unit and [Pr(H2O)7]3+ cations as linker. The chains are linked into an extensive three-dimensional supramolecular network through hydrogen bonding. The synthesis of 1 is accomplished only from pre-synthesized Anderson clusters, but not from simple starting materials.

Syntheses and structural characterization of coordination polymers of Cu(II) and Zn(II) chlorobenzoates and bis(pyridin-4-yl)-substituted species

2015 ◽  
Vol 70 (2) ◽  
pp. 95-100 ◽  
Author(s):  
Fu-Lin Mao ◽  
Jian-Qing Tao ◽  
Chun-Hua Dai
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Network Structure ◽  
Structural Characterization ◽  
Chain Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
A Chain

AbstractThe reaction of Cu(II) nitrate with sodium 2-chlorobenzoate (NaL1) and (E)-1,2-di(pyridin-4-yl)ethene (dpe) yields a new complex [Cu(L1)2(dpe)(H2O)] (1). When Zn(II) nitrate reacts with sodium 4-chlorobenzoate (NaL2) and 1,2-di(pyridin-4-yl)ethane (dpa), [Zn(L2)2(dpa)]·CH3OH (2) is obtained. Complexes 1 and 2 have been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. 1 shows a 3D CdS network structure with uninodal 4-connected (65.8) topology; complex 2 displays a chain structure.

Synthesis and Structural Characterization of Zn(II) Coordination Polymer Material

2011 ◽  
Vol 282-283 ◽  
pp. 100-103 ◽  
Author(s):  
Li Hua Wang
Keyword(s):  
Hydrogen Bond ◽  
Coordination Polymer ◽  
Chain Structure ◽  
Title Complex ◽  
Dimensional Chain ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
One Dimensional ◽  
X Ray

In order to synthesize a new catalysis material, the title complex, [Zn(2,2’-bipyridine)(H2O)2(SO4)]n, was prepared and determined by X-ray diffraction. The results shows that the compound was crystallized in the monoclinic system, space groupC2/c, witha= 15.4304(14) Å,b= 12.7150(11) Å,c= 6.7068(5) Å,β= 102.103(10)º,V= 1286.61(19) Å3,Z= 4. The geometry of Zn(II) is a distortedcis-ZnN2O4octahedron. In the structure of the title complex, a one-dimensional chain structure is formed by hydrogen-bond.

Synthesis and structural characterization of a three-dimensional two-fold interpenetrated coordination polymer constructed from bis(4-(1H-imidazol-1-yl)phenyl)methanone and 1,1ʹ-biphenyl-2,2ʹ-dicarboxylate ligands for cadmium(II)

2020 ◽  
Vol 75 (8) ◽  
pp. 733-737
Author(s):  
Gao-Feng Wang ◽  
Shu-Wen Sun ◽  
Hong Sun ◽  
Bo-Hui Wei ◽  
Yan-Fei Zhao ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Topological Structure ◽  
Solvothermal Method ◽  
Three Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Elemental Analyses

AbstractA three-dimensional (3D) two-fold interpenetrated coordination polymer, {[Cd(bipmo)(bpda)]·1.25(H2O)}n (1), (bipmo = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2bpda = 1,1ʹ-biphenyl-2,2ʹ-dicarboxylic acid), was synthesized by a solvothermal method. It has been characterized by elemental analyses, infrared (IR) spectroscopy, and single-crystal X-ray diffraction. The topological structure of 1 consists of uninodal dia nets with two-fold penetration. The thermal stability and the luminescence properties of complex 1 were investigated.

A cobalt-based coordination polymer with a tripodal carboxylate ligand: synthese, structure and properties

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Long Tang ◽  
JiaoWei Nan ◽  
YuFei Zheng ◽  
JiJiang Wang ◽  
XiangYang Hou ◽  
...  
Keyword(s):  
Thermogravimetric Analysis ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Chain Structure ◽  
Carboxylate Ligand ◽  
Structure And Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
2D Structure

Abstract A new cobalt-based coordination polymer (CP), [Co(Htatb)(1,4-bib)]·DMF (1), has been hydrothermally synthesized from CoCl2 ·6H2O, 4,4′,4′′-s-triazine-2,4,6-tribenzoic acid (H3tatb), and 1,4-bis(1-imidazoly)benzene (1,4-bib). The product has been characterized by IR spectroscopy, elemental and thermogravimetric analysis, and single-crystal X-ray diffraction. In compound 1, the Htatb ligand links three CoII ions resulting in a double-strand chain structure, further bridged through the 1,4-bib ligands to generate a 2D structure with channels. The fluorescence and cyclovoltammetry characteristics of compound 1 have also been investigated.

Synthesis, structural characterization, and fluorescence of a Cd(II) coordination polymer with N-donor ligands

2017 ◽  
Vol 72 (3) ◽  
pp. 189-192 ◽  
Author(s):  
Hai-Wei Kuai ◽  
Jing-Jing Xia ◽  
Xiao-Hong Zhu ◽  
Jing Chen
Keyword(s):  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Structural Characterization ◽  
Hydrothermal Reaction ◽  
Ammonium Hydroxide ◽  
Donor Ligands ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
X Ray ◽  
2D Network

Abstract The hydrothermal reaction of CdSO4 with 2,5-di(1H-imidazol-4-yl)thiophene (L) in the presence of ammonium hydroxide at 100°C gives rise to a new complex [Cd(L)(SO4)]n (1). Complex 1 has been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. It crystallizes in the monoclinic system with the space group C2/c and shows a 2D network structure. Complex 1 can emit fluorescence.

scholarly journals Exploring the Structural Chemistry of Pyrophosphoramides: N,N′,N″,N‴-Tetraisopropylpyrophosphoramide

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 149-163
Author(s):  
Duncan Micallef ◽  
Liana Vella-Zarb ◽  
Ulrich Baisch
Keyword(s):  
Crystal Structure ◽  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Hydrogen Bonding ◽  
Nmr Spectroscopy ◽  
Ir Spectroscopy ◽  
Room Temperature ◽  
Intermolecular Hydrogen Bonding ◽  
X Ray Diffraction ◽  
X Ray

N,N′,N″,N‴-Tetraisopropylpyrophosphoramide 1 is a pyrophosphoramide with documented butyrylcholinesterase inhibition, a property shared with the more widely studied octamethylphosphoramide (Schradan). Unlike Schradan, 1 is a solid at room temperature making it one of a few known pyrophosphoramide solids. The crystal structure of 1 was determined by single-crystal X-ray diffraction and compared with that of other previously described solid pyrophosphoramides. The pyrophosphoramide discussed in this study was synthesised by reacting iso-propyl amine with pyrophosphoryl tetrachloride under anhydrous conditions. A unique supramolecular motif was observed when compared with previously published pyrophosphoramide structures having two different intermolecular hydrogen bonding synthons. Furthermore, the potential of a wider variety of supramolecular structures in which similar pyrophosphoramides can crystallise was recognised. Proton (1H) and Phosphorus 31 (31P) Nuclear Magnetic Resonance (NMR) spectroscopy, infrared (IR) spectroscopy, mass spectrometry (MS) were carried out to complete the analysis of the compound.

Syntheses, Structural Characterization and Fluorescence of Zn(II) and Cd(II) Polymers from 5-(Pyridin-2-ylmethylamino)isophthalic acid

2013 ◽  
Vol 68 (9) ◽  
pp. 1007-1014 ◽  
Author(s):  
Xiao-Chun Cheng ◽  
Xiao-Hong Zhu ◽  
Hai-Wei Kuai
Keyword(s):  
Water Clusters ◽  
Hydrothermal Reaction ◽  
Reaction System ◽  
Chain Structure ◽  
Isophthalic Acid ◽  
Auxiliary Ligand ◽  
X Ray Diffraction ◽  
X Ray ◽  
Alkaline Reaction ◽  
A Chain

The hydrothermal reaction of Zn(II) nitrate with 5-(pyridin-2-ylmethylamino)isophthalic acid (H2L) yields the complex [Zn(L)(H2O)] 2H2O (1). When 2,2'-bipyridine (bpy) as auxiliary ligand and Cd(II) nitrate were used in the alkaline reaction system, [Cd(L)(H2O)(bpy)] 3H2O (2) was obtained. Complexes 1 and 2 have been characterized by single-crystal and powder X-ray diffraction, IR, elemental and thermogravimetric analyses. Complex 1 shows a 2D fes network structure with uninodal 3-connected (4.82) topology, which is further linked by hydrogen bonding to give rise to a 3D supramolecular framework; complex 2 displays a chain structure. Interestingly, tetranuclear water clusters were generated in 1, which are interlinked to fabricate a water chain structure. The fluorescence properties of 1 and 2 were investigated

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