Syntheses, structures, and catalytic properties of two arene-ruthenium(II) complexes bearing N-(2-pyridinyl)aminodiphenylphosphine sulfide ligands
Keyword(s):
X Ray
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AbstractTreatment of [(arene)Ru(μ-Cl)Cl]2with Ph2P(S)NH(2-py) in the presence or absence of base gave two arene-ruthenium(II) complexes [(η6-p-cymene)Ru{κ2-N,N-Ph2P(S)N(2-py)}Cl] (1) and [(η6-benzene)Ru{κ1-N-Ph2P(S)NH(2-py)}Cl2] (2), which have been characterized by infrared, nuclear magnetic resonance spectroscopies, and mass spectrometry along with microanalyses. Crystal structures of Ph2P(S)NH(2-py) · ¼C6H14,1and2· ½CH2Cl2were determined by single-crystal X-ray diffraction. Two arene-ruthenium(II) complexes were tested as precatalysts for the transfer hydrogenation of acetophenone to give 1-phenyl ethanol.
1984 ◽
pp. 1903
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2018 ◽
Keyword(s):
2019 ◽
Vol 123
(29)
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pp. 17798-17807
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2018 ◽
1987 ◽
pp. 1169-1174
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