scholarly journals Phase Equilibrium, Thermodynamic Limit, and Melting Temperature in Nanocrystals

2018 ◽  
Vol 63 (11) ◽  
pp. 1036 ◽  
Author(s):  
L. A. Bulavin ◽  
O. M. Alekseev ◽  
Yu. F. Zabashta ◽  
M. M. Lazarenko
Keyword(s):  
Experimental Data ◽  
Phase Equilibrium ◽  
Melting Temperature ◽  
Thermodynamic Limit ◽  
Equilibrium Condition ◽  
Organic Materials ◽  
Porous Solids ◽  
Equilibrium Thermodynamic ◽  
Finite Systems ◽  
Phase Equilibrium Condition

The phase equilibrium condition is shown to be strictly satisfied only in the thermodynamic limit. The notion of melting temperature in the thermodynamic limit is introduced. Formulas are obtained that determine the melting conditions and the melting temperature for finite systems including nanocrystals. The validity of those formulas is confirmed, by comparing them with experimental data for organic materials in porous solids.

Phase equilibrium condition measurements in carbon dioxide hydrate forming system coexisting with seawater

2021 ◽  
Vol 152 ◽  
pp. 106276
Author(s):  
Rihito Nakane ◽  
Yusuke Shimosato ◽  
Eito Gima ◽  
Ryo Ohmura ◽  
Izuru Senaha ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Phase Equilibrium ◽  
Equilibrium Condition ◽  
Carbon Dioxide Hydrate ◽  
Phase Equilibrium Condition
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