Magnetic Transitions in the Double Perovskite Sr2FeRe1-xFexO6(0≤X≤0.5)

2008 ◽  
Vol 1119 ◽  
Author(s):  
Haitao Gao ◽  
Vadim Ksenofotov ◽  
Joachim Barth ◽  
Martin Panthöefer ◽  
Felser Claudia ◽  
...  
Keyword(s):  
Curie Temperature ◽  
Transport Properties ◽  
Solid Solutions ◽  
Magnetic Moment ◽  
Parent Compound ◽  
Structural Evolution ◽  
Double Perovskite ◽  
Magnetic Transitions ◽  
Mössbauer Data ◽  
Redox Buffer

AbstractThe synthesis, structure, and magnetic and transport properties of solid solutions Sr2FeRe1-xFexO6 (0≤x≤0.5) are reported. A structural evolution in the solid solutions from a double perovskite to perovskite is observed with increasing Fe/Re disorder. Except for the metallic parent compound all members of the series are semiconducting. For the Fe-doped samples a change from ferrimagnetic interactions in the parent compound to a complex superposition of ferrimagnetic and antiferromagnetic interactions was observed. The magnetic moment decreases with x, whereas the Curie temperature TC remains unaffected. The magnetic and Mössbauer data suggest Fe to act as a redox-buffer.

scholarly journals Thermoelectric Transport Properties of TmAg Cu1-Te2 Solid Solutions

2020 ◽  
Author(s):  
Qingyu Bai ◽  
Xinyue Zhang ◽  
Bing Shan ◽  
Xuemin Shi ◽  
Cheng Sun ◽  
...  
Keyword(s):  
Transport Properties ◽  
Solid Solutions ◽  
Thermoelectric Transport ◽  
Thermoelectric Transport Properties

Metallic ordered double-perovskite Sr2CrReO6 with maximal Curie temperature of 635 K

2002 ◽  
Vol 81 (2) ◽  
pp. 328-330 ◽  
Author(s):  
H. Kato ◽  
T. Okuda ◽  
Y. Okimoto ◽  
Y. Tomioka ◽  
Y. Takenoya ◽  
...  
Keyword(s):  
Curie Temperature ◽  
Double Perovskite

The Solid Solutions Gd2Cu2In1–xMgx – Drastic Increase of the Curie Temperature upon In/Mg Substitution

2010 ◽  
Vol 65 (12) ◽  
pp. 1516-1520 ◽  
Author(s):  
Wilfried Hermes ◽  
Falko M. Schappacher ◽  
Rainer Pöttgen
Keyword(s):  
Curie Temperature ◽  
Intermetallic Compounds ◽  
Solid Solutions ◽  
Temperature Increase ◽  
Magnesium Content ◽  
Lattice Parameter ◽  
Weiss Constant ◽  
Drastic Increase ◽  
Complete Set ◽  
Mg Substitution

The Mo2B2Fe-type intermetallic compounds Gd2Cu2In and Gd2Cu2Mg form a complete set of solid solutions Gd2Cu2In1−xMgx. The a lattice parameter, the Weiss constant and the Curie temperature increase with increasing magnesium content in an almost Vegard-like manner, while the c parameter remains almost constant. All members of the solid solutions show ferromagnetism with TCs between 114 and 80 K.

Structural and transport properties of La1.85−xNdxSr0.15CuO4Fy solid solutions

1993 ◽  
Vol 209 (1-3) ◽  
pp. 47-49
Author(s):  
J. Hejtmanek ◽  
E. Pollert ◽  
B. Chevalier ◽  
J. Etourneau ◽  
A. Tressaud
Keyword(s):  
Transport Properties ◽  
Solid Solutions

Thermoelectric Properties of K2Bi8−xSbxSe13Solid Solutions and Se Doping

2001 ◽  
Vol 691 ◽  
Author(s):  
Theodora Kyratsi ◽  
Jeffrey S. Dyck ◽  
Wei Chen ◽  
Duck-Young Chung ◽  
Ctirad Uher ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Charge Transport ◽  
Transport Properties ◽  
Thermoelectric Properties ◽  
Solid Solutions ◽  
Figure Of Merit ◽  
Lattice Thermal Conductivity ◽  
Se Doping ◽  
Mass Fluctuation ◽  
Thermal Conductivities

ABSTRACTOur efforts to improve the thermoelectric properties of β-K2Bi8Se13, led to systematic studies of solid solutions of the type β-K2Bi8−xSbxSe13. The charge transport properties and thermal conductivities were studied for selected members of the series. Lattice thermal conductivity decreases due to the mass fluctuation generated in the lattice by the mixed occupation of Sb and Bi atoms. Se excess as a dopant was found to increase the figure-of merit of the solid solutions.

Magnetic and Transport properties of the mixed 3d-5d-4f double perovskite Sm2CoIrO6

2021 ◽  
Author(s):  
Suman Kalyan Pradhan ◽  
Biswajit Dalal ◽  
Rafikul Ali Saha ◽  
Raktim Datta ◽  
Subham Majumdar ◽  
...  
Keyword(s):  
Transport Properties ◽  
Double Perovskite

scholarly journals Studying the structural and electronic effects of substituted (Bi0.5Na0.5)TiO3

2014 ◽  
Vol 70 (a1) ◽  
pp. C1522-C1522
Author(s):  
Peter Blanchard ◽  
Brendan Kennedy ◽  
Chris Ling
Keyword(s):  
Solid Solutions ◽  
Structural Changes ◽  
Structural Evolution ◽  
Rhombohedral Phase ◽  
Rhombohedral Structure ◽  
Electronic Effects ◽  
Spectra Analysis ◽  
Space Group ◽  
Industry Standard ◽  
Made In

Significant efforts have been made in the development of (Bi0.5Na0.5)TiO3 ferroelectrics as an alternative to the lead-based industry standard PbTi1-xZrxO3.[1] It has also been shown that doping the A- and B-site of (Bi0.5Na0.5)TiO3 can greatly improve the ferroelectric behavior of these materials,[2] possibly due to the formation of two or more ferroelectric phases at a morphotropic phase boundary (MPB). As such, there is a significant interest in understanding the structural changes in (Bi0.5Na0.5)TiO3-based solid solutions. (Bi0.5Na0.5)TiO3 was originally described as adopting a rhombohedral structure in space group R3c, However, the accuracy of this description has been greatly debated. It was recently suggested that (Bi0.5Na0.5)TiO3 actually adopts a monoclinic structure in space group Cc.[3] Given this recent controversy, we investigated the structural evolution of (Bi0.5Na0.5)TiO3-based solid solutions, particularly the (Bi0.5Na0.5)Ti1-xZrxO3 and (1-x)(Bi0.5Na0.5)TiO3–xBiFeO3 solid solutions., using both diffraction and spectroscopy techniques. Diffraction measurements on (Bi0.5Na0.5)TiO3 confirm that both monoclinic Cc and rhombohedral R3c phases are present at room temperature. Diffraction analysis showed that doping (Bi0.5Na0.5)TiO3 with a small amount of (Bi0.5Na0.5)ZrO3 and BiFeO3 can stabilizes the rhombohedral phase. The Ti/Fe K-edge and Zr L3-edge XANES spectra analysis was performed to determine the effects doping has on the local displacement of the B-site cations.

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