A Study of the Temperature-Dependence of Low-Frequency, Raman-Active Phonons in Stage-2 Graphite-K and Graphite-Rb Intercalation Compounds
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ABSTRACTWe report results from a Raman scattering study of stage 2 Graphite-Rb and Graphite-K in the low frequency region (ω < 150 cm-1) as a function of temperature (80K < T < 300K). Four features are seen in the 80K spectra and are interpreted in terms of a Born– von Kármán lattice dynamics model. The temperature-dependence of the Raman spectra is discussed in connection with reported phase transitions in stage 2 alkalimetal graphite compounds.
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1981 ◽
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pp. C6-430-C6-432
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pp. 6475-6490
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pp. 794-797
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pp. 117-124
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