Modulation in Electric Conduction of PVK and Ferrocene-Doped PVK Thin Films

In this article, the dielectric properties of poly (9-vinylcarbazole) (PVK) and ferrocene-doped PVK thin films are studied. The thin films were grown by the isothermal solution casting technique. Dielectric properties of grown films were studied as function of ferrocene concentration, frequency, and temperature. The relative permittivity (ε′) is increased with increasing ferrocene percentage (~1%) due to the free charge carriers. The relative permittivity decreases for higher ferrocene percentage (~2%). However, the relative permittivity of PVK and ferrocene-doped PVK samples remains almost constant for studied temperature range (313–413 K). The frequency dependence of tan δ for all samples is studied. The frequency dependence of dielectric parameter exhibits frequency dispersion behavior, which suggests all types of polarization present in the lower frequency range. The loss tangent (tanδ) values are larger at higher temperatures in the low frequency region. However, the tan δ values at different temperatures are almost similar in the high frequency region. It is observed that the relative permittivity is maximum, dielectric loss is minimum, and AC conductivity is minimum for 1% ferrocene doped PVK as compared to pure PVK and 2% ferrocene doped PVK samples.

Theoretical studies of low-frequency Alfvén modes in tokamak plasmas

Linear wave properties of the low-frequency Alfvén modes (LFAMs) observed in the DIII-D tokamak experiments with reversed magnetic shear [Nucl. Fusion 61, 016029 (2021)] are theoretically studied and delineated based on the general fishbone-like dispersion relation. By adopting the representative experimental equilibrium parameters, it is found that, in the absence of energetic ions, the LFAM is a kinetic ballooning mode instability of reactive-type with a dominant Alfvénic polarization. More specifically, due to diamagnetic and trapped particle effects, the LFAM can be coupled with the beta-induced Alfvén-acoustic mode in the low-frequency region (frequency much less than the thermal-ion transit and/or bounce frequency); or with the beta-induced Alfvén eigenmode in the high frequency region (frequency higher than or comparable to the thermal-ion transit frequency); resulting in reactive-type instabilities. Moreover, the ‘Christmas light’ and ‘mountain peak’ spectral patterns of LFAMs as well as the dependence of instability drive on the electron temperature observed in the experiments can be theoretically interpreted by varying the relevant physical parameters. Conditions when dissipative-type instabilities may set in are also discussed.

Relative Weights of Temporal Envelope Cues in Different Frequency Regions for Mandarin Vowel, Consonant, and Lexical Tone Recognition

Objectives: Mandarin-speaking users of cochlear implants (CI) perform poorer than their English counterpart. This may be because present CI speech coding schemes are largely based on English. This study aims to evaluate the relative contributions of temporal envelope (E) cues to Mandarin phoneme (including vowel, and consonant) and lexical tone recognition to provide information for speech coding schemes specific to Mandarin.Design: Eleven normal hearing subjects were studied using acoustic temporal E cues that were extracted from 30 continuous frequency bands between 80 and 7,562 Hz using the Hilbert transform and divided into five frequency regions. Percent-correct recognition scores were obtained with acoustic E cues presented in three, four, and five frequency regions and their relative weights calculated using the least-square approach.Results: For stimuli with three, four, and five frequency regions, percent-correct scores for vowel recognition using E cues were 50.43–84.82%, 76.27–95.24%, and 96.58%, respectively; for consonant recognition 35.49–63.77%, 67.75–78.87%, and 87.87%; for lexical tone recognition 60.80–97.15%, 73.16–96.87%, and 96.73%. For frequency region 1 to frequency region 5, the mean weights in vowel recognition were 0.17, 0.31, 0.22, 0.18, and 0.12, respectively; in consonant recognition 0.10, 0.16, 0.18, 0.23, and 0.33; in lexical tone recognition 0.38, 0.18, 0.14, 0.16, and 0.14.Conclusion: Regions that contributed most for vowel recognition was Region 2 (502–1,022 Hz) that contains first formant (F1) information; Region 5 (3,856–7,562 Hz) contributed most to consonant recognition; Region 1 (80–502 Hz) that contains fundamental frequency (F0) information contributed most to lexical tone recognition.

The low-frequency limiting behavior of ambipolar diffusive models of impedance spectroscopy

The Poisson–Nernst–Planck (PNP) diffusional model is a successful theoretical framework to investigate the electrochemical impedance response of insulators containing ionic impurities to an external ac stimulus. Apparent deviations of the experimental spectra from the predictions of the PNP model in the low frequency region are usually interpreted as an interfacial property. Here, we provide a rigorous mathematical analysis of the low-frequency limiting behavior of the model, analyzing the possible origin of these deviation related to bulk properties. The analysis points toward the necessity to consider a bulk effect connected with the difference in the diffusion coefficients of cations and anions (ambipolar diffusion). The ambipolar model does not continuously reach the behavior of the one mobile ion diffusion model when the difference in the mobility of the species vanishes, for a fixed frequency, in the cases of ohmic and adsorption–desorption boundary conditions. The analysis is devoted to the low frequency region, where the electrodes play a fundamental role in the response of the cell; thus, different boundary conditions, charged to mimic the non-blocking character of the electrodes, are considered. The new version of the boundary conditions in the limit in which one of the mobility is tending to zero is deduced. According to the analysis in the dc limit, the phenomenological parameters related to the electrodes are frequency dependent, indicating that the exchange of electric charge from the bulk to the external circuit, in the ohmic model, is related to a surface impedance, and not simply to an electric resistance.

Electrical transport properties of V2O5-added Ni–Co–Zn ferrites

Frequency-dependent dielectric constant, dielectric loss, AC conductivity values and complex impedance spectra of V2O5-added Ni–Co–Zn ferrites (Ni[Formula: see text]Co[Formula: see text]Zn[Formula: see text]Fe2O4 + [Formula: see text]V2O5, where [Formula: see text] = 0, 0.5, 1 and 1.5 wt.%) have been investigated at room temperature. The dielectric properties of the samples follow the Maxwell–Wagner polarization model. An inverse relationship was found between dielectric constant and AC electrical resistivity for all the samples. The dielectric constants decreased with the addition of V2O5, while the electrical resistivities of V2O5-added Ni–Co–Zn ferrites are found to be larger than that of pure Ni–Co–Zn ferrite. The AC conductivity was reduced with the addition of V2O5 to Ni–Co–Zn ferrite at lower-frequency region. However, AC conductivity shows a sharp increase at higher-frequency region, which could be attributed to the enhancement of electron hopping between the Fe[Formula: see text] and Fe[Formula: see text] ions in the ferrite matrix due to the activity of the grains. The complex impedance spectroscopy results through Cole–Cole/Nyquist plot have demonstrated a single semicircular arc. It indicates that conduction mechanism takes place predominantly through the grain/bulk property, which could be ascribed to the larger grain size of V2O5-added Ni–Co–Zn ferrites.

Intermolecular Hydrogen-Bond Interactions in DPPE and DMPC Phospholipid Membranes Revealed by Far-Infrared Spectroscopy

The vibrational signature in the far-infrared region of two different phospholipids, phosphatidylcholine (PC) and phosphatidylethanolamine (PE), was investigated as a function of relative humidity from 0 to 75% in order to evaluate the effect of headgroup composition on the formation of intermolecular interactions. The substructures of the frequency region between 50 and 300 cm−1 were identified, and changes in the frequency and intensity of the related vibrations with hydration were analyzed. Interestingly, in PE, two additional vibrational bands with respect to PC were found at 162 and 236 cm−1 and assigned to intermolecular hydrogen bonds between the hydrogen-bond-donating groups, -NH3+, and hydrogen-bond-accepting groups, —P—O− and —COO, of adjacent molecules. The presence of these interactions also affected the penetration of water, severely reducing the hydration capability of PE lipids.

Substrate integrated waveguide bandpass filter for short range device application using rectangular open loop resonator

The substrate integrated waveguide (SIW) structure is the candidate for many application in microwave, terahertz and millimeter wave application. It because of SIW structure can integrate with any component in one substrate than others structure. A kind components using SIW structure is a filter component, especialy bandpass filter. This research recommended SIW bandpass filter using rectangular open loop resonator for giving more selectivity of filter. It can be implemented for short range device (SRD) application in frequency region 2.4 - 2.483 GHz. Two types of SIW bandpass filter are proposed. First, SIW bandpass filter is proposed using six rectangular open loop resonators while the second SIW bandpass filter used eight rectangular open loop resonators. The simulation results for two kinds of the recommended rectangular open loop resonators have insertion loss (S₂₁ parameter) below 2 dB and return loss (S₁₁ parameter) more than 10 dB. Fabrication of the recommended two kind filters was validated by Vector Network Analyzer. The measurement results for six rectangular open loop resonators have 1.32 dB for S₂₁ parameter at 2.29 GHz while the S₁₁ parameter more than 18 dB at 2.26 GHz – 2.32 GHz. While the measurement results has good agreement for eight rectangular open loop resonators. Its have S₂₁ below 2.2 dB at 2.41 – 2.47 GHz and S₁₁ 16.27 dB at 2.38 GHz and 11.5 dB at 2.47 GHz.