Single-Component Routes to Perovsktte Phase Mixed Metal Oxides
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ABSTRACTCrystalline perovskite phase mixed metal oxides have been prepared at low temperatures from single-component mixed metal-organic precursors specifically designed for this purpose. Pyridine solutions of divalent metal α-hydroxycarboxylates of general empirical formula A(O2CMe2OH)2 where A = Pb, Ca, Sr, Ba; Me = methyl, react with metal alkoxide compounds such as B(OR')4, where B = Ti, Zr, Sn with the elimination of two equivalents of alcohol to form species with a fixed A:B stoichiometry of 1:1 according to the equation below.
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1994 ◽
Vol 2
(1-3)
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pp. 305-309
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2018 ◽
Vol 97
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pp. 144-148
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1992 ◽
Vol 188
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pp. 165-169
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2021 ◽
Vol 155
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pp. 105103
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