scholarly journals Synthesis and Characterization of Polysulfone-based Graft Copolymer Possessing Quaternary Ammonium Salts via Photoiniferter Polymerization

2017 ◽  
pp. 117-132 ◽  
Author(s):  
Mehmet Atilla Tasdelen ◽  
Serhat Oran
Keyword(s):  
Graft Copolymer ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Synthesis And Characterization

Synthesis and characterization of antibacterial polyurethane coatings from quaternary ammonium salts functionalized soybean oil based polyols

2013 ◽  
Vol 33 (1) ◽  
pp. 153-164 ◽  
Author(s):  
Hadi Bakhshi ◽  
Hamid Yeganeh ◽  
Shahram Mehdipour-Ataei ◽  
Mohammad Ali Shokrgozar ◽  
Abbas Yari ◽  
...  
Keyword(s):  
Soybean Oil ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Synthesis And Characterization ◽  
Polyurethane Coatings

Systematic Characterization of Different Quaternary Ammonium Salts to be Used in Organoclays

2012 ◽  
Vol 727-728 ◽  
pp. 1552-1556
Author(s):  
Renata Barbosa ◽  
Dayanne Diniz Souza ◽  
Edcleide Maria Araújo ◽  
Tomás Jefférson Alves de Mélo
Keyword(s):  
Thermal Stability ◽  
Quaternary Ammonium ◽  
Chemical Structure ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Degradation Mechanisms ◽  
Scanning Calorimetry ◽  
Higher Temperature ◽  
Thermal Stability Of

Studies of degradation have verified that the decomposition of some quaternary ammonium salts can begin to be significant at the temperature of about 180 ° C and like most thermoplastics are processed at least around this temperature, the thermal stability of the salt in clay should always be considered. Some salts are more stable than others, being necessary to study the degradation mechanisms of each case. In this work, four quaternary ammonium salts were characterized by differential scanning calorimetry (DSC) and thermogravimetry (TG). The results of DSC and TG showed that the salts based chloride (Cl-) anion begin to degrade at similar temperatures, while the salt based bromide (Br-) anion degrades at higher temperature. Subsequently, a quaternary ammonium salt was chosen to be used in organoclays, depending on its chemical structure and its thermal behavior.

Characterization of Novel Deep Eutectic Ionic Liquids and their Application in Green Synthesis

2010 ◽  
Vol 113-116 ◽  
pp. 1212-1216 ◽  
Author(s):  
Bao You Liu ◽  
Yuan Yuan Wang ◽  
Fu Xiang Wei
Keyword(s):  
Catalytic Activity ◽  
Ionic Liquids ◽  
Low Temperature ◽  
Quaternary Ammonium ◽  
Room Temperature ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Sonogashira Reaction ◽  
Good Catalytic Activity

Five novel deep eutectic ionic liquids were prepared from relatively simple quaternary ammonium salts and imidazole. All of these salts are liquids at room temperature, and are steady up to 150°C. They exhibit low viscosities and moderate conductivities at low temperature. Especially, Bu4NCl-IM is a green alternative solvent in Sonogashira reaction with good catalytic activity.

Synthesis of Amidation Agents and their Reactivity in Condensation Reactions

Synthesis ◽  
2020 ◽  
Author(s):  
Roberto Sole ◽  
Vanessa Gatto ◽  
Silvia Conca ◽  
Lodovico Agostinis ◽  
Noemi Bardella ◽  
...  
Keyword(s):  
Quaternary Ammonium ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
The Novel ◽  
Reaction Conditions ◽  
1H And 13C Nmr ◽  
Full Characterization ◽  
Ft Ir

Nowadays, the development of new approaches which smartly bypass the use of harsh reaction conditions and hazardous chemicals covers a pivotal role. In this research paper the synthesis, characterization and application of novel libraries of triazine bis-quaternary ammonium salts, employed as coupling agents to produce amides, is reported. Full characterization of the novel compounds by 1H and 13C NMR, FT-IR spectroscopy, ESI-HRMS and elemental analysis (EA) is provided. Furthermore, a comparison in terms of activity of the preformed triazine compounds versus in situ formulations has been evaluated for the formation of amides in the presence of phenylethylamine and different aliphatic or aromatic acids. A possible correlation between the chemical structure of the triazine and their reactivity for the formation of the triazine bis-quaternary ammonium salts is also reported. Moreover, best performing condensation agents have been further tested for the cross-linking of collagen powder as possible wet white tanning systems, for sustainable and environmentally friendly leather tanning.

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