Obtaining copper in the form of a dispersed metal by reduction from an aqueous acid solution

Author(s):  
R.K. Bartagov ◽  
1965 ◽  
Vol 43 (4) ◽  
pp. 940-949 ◽  
Author(s):  
R. A. Abramovitch ◽  
G. Tertzakian

The decomposition of the diazonium salt from 3-(o-aminobenzoyl)pyridine has been studied under various conditions. A competitive-type cyclization of an equimolar mixture of the diazonium salts of 2-aminobenzophenone and 2-amino-3′-nitrobenzophenone has also been carried out. The results are interpreted in terms of a radical process in the copper-catalyzed reactions. It is suggested that the uncatalyzed thermal decompositions in aqueous acid solution give rise to a diradical cation intermediate in equilibrium with the aryl cation.


1980 ◽  
Vol 11 (3) ◽  
pp. 377-381 ◽  
Author(s):  
Yasuhiro Awakura ◽  
Shinya Kamei ◽  
Hiroshi Majima

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