scholarly journals Electrochemical Behaviour of a Gold Film- Glassy Carbon Electrode for Determination of Chromium (VI)

2021 ◽  
Author(s):  
Nevila Broli ◽  
Loreta Vallja ◽  
Majlinda Vasjari
Keyword(s):  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Electrochemical Behaviour ◽  
Supporting Electrolyte ◽  
Anodic Stripping Voltammetry ◽  
Carbon Electrode ◽  
Modulation Amplitude ◽  
Chromium Vi ◽  
Relative Standard

A gold nanostructured film modified glassy carbon electrode (Aufilm/GCE) was developed for the determination of chromium (VI) in water sample. GCE was immersed into HAuCl4 solution (10-3M) and electrodeposition of thin gold layer was conducted at –0.4 V (vs Ag/AgCl) for 10 min. The strong affinity between Au and Cr species resulted with increasing of Cr (VI) signal, compared with the bare glassy carbon electrode. The electrodepositing time, type of supporting electrolyte, pH, the scan rate, modulation amplitude, and modulation time were optimized using differential pulse anodic stripping voltammetry (DP-ASV). The calibration graph using accumulation time of 120 s was linear from 10 to 120 µgL-1 with a sensitivity 1.3 x 10-2 µA/µgL-1. Under optimum experimental conditions, a good correlation coefficient R2=0.9971, and a low detection limit 5.5 µg/L Cr (VI) was obtained. The signal was reproducible with a relative standard deviation ±4.5 %. The developed Aufilm/GCE sensor was applied for the Cr (VI) determination of in sewage water samples.

scholarly journals Electrochemical Behaviour of Gold Thin Film Glassy Carbon Electrode for Determination of Chromium(VI)

2021 ◽  
Vol 33 (5) ◽  
pp. 1001-1005
Author(s):  
N. Broli ◽  
L. Vallja ◽  
M. Vasjari ◽  
A. Shehu ◽  
S. Duka
Keyword(s):  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Water Samples ◽  
Electrochemical Behaviour ◽  
Anodic Stripping Voltammetry ◽  
Carbon Electrode ◽  
Modulation Amplitude ◽  
Chromium Vi ◽  
Relative Standard

A modified glassy carbon electrode (Aufilm/GCE) using a gold film was constructed for determination of chromium(VI) in real water samples. A GCE was immersed in HAuCl4 solution (10-3 M) and the thin layer of gold was electrodeposited for 10 min at −0.4 V (vs. Ag/AgCl). Compared with only GCE, a strong affinity between chromium and gold species was observed with an increase in Cr(VI) signal. The type of supporting electrolytes, electrodeposition time, scan rate, pH, modulation time and the modulation amplitude were optimized through differential pulse-anodic stripping voltammetry (DP-ASV). A calibration graph acquired using the accumulation time of 120 s with a sensitivity of 1.3 × 10-2 μA/μgL-1 was linear in the range of 10-120 μg L-1. A low detection limit of 5.5 μg/L Cr(VI) and a strong correlation coefficient R2 = 0.9971 were obtained under the optimal experimental conditions. Signals were reproducible and exhibited a relative standard deviation of ±4.5%. A modified sensor was employed to determine the Cr(VI) content in the sewage water samples.

Determination of chromium(vi) by anodic stripping voltammetry using a silver-plated glassy carbon electrode

2018 ◽  
Vol 10 (24) ◽  
pp. 2917-2923 ◽  
Author(s):  
Zorica Stojanović ◽  
Zuzana Koudelkova ◽  
Eliska Sedlackova ◽  
David Hynek ◽  
Lukas Richtera ◽  
...  
Keyword(s):  
Glassy Carbon Electrode ◽  
Hexavalent Chromium ◽  
Glassy Carbon ◽  
Anodic Stripping Voltammetry ◽  
Stripping Voltammetry ◽  
Differential Pulse ◽  
Carbon Electrode ◽  
Chromium Vi ◽  
Anodic Stripping

In this work, differential pulse anodic stripping voltammetry (DP-ASV) for the determination of trace amounts of hexavalent chromium (Cr(vi)) at a silver plated glassy carbon electrode (Ag plated-GCE) is described in detail.

scholarly journals The effect of tamoxifen on the electrochemical behavior of Bi+3/Bi on the glassy carbon electrode and its determination via differential pulse anodic stripping voltammetry

2019 ◽  
Vol 63 (1) ◽  
Author(s):  
Mehdi Jalali ◽  
Zeinab Deris Falahieh ◽  
Mohammad Alimoradi ◽  
Jalal Albadi ◽  
Ali Niazi
Keyword(s):  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Electrochemical Behavior ◽  
Electrochemical Impedance ◽  
Anodic Stripping Voltammetry ◽  
Stripping Voltammetry ◽  
Differential Pulse ◽  
Peak Height ◽  
Carbon Electrode

The electrochemical behavior of Bi+3 ions on the surface of a glassy carbon electrode, in acidic media and in the presence of tamoxifen, was investigated. Cyclic voltammetry, chronoamperometry, differential pulse voltammetry, electrochemical impedance spectroscopy, and scanning electron microscopy with energy-dispersive X-ray spectroscopy were used to find the probable mechanism contributing to the reduction of the peak height of bismuth oxidation with an increase in the concentration of tamoxifen. The obtained results show a slight interaction between the bismuth species and tamoxifen which co-deposit on the surface of glassy carbon electrode. Therefore, the reduction in the peak height of bismuth oxidation as a function of tamoxifen concentration was used to develop a new differential pulse anodic striping voltammetry method for determination of trace amount of tamoxifen. The effects of experimental parameters on the in situ DPASV of Bi+3 ions in the presence of tamoxifen shown the optimal conditions as: 2 mol L-1 H2SO4 (1% v v-1 MeOH), a deposition potential of -0.5 V, a deposition time of 60 s, and a glassy carbon electrode rotation rate of 300 rpm. The calibration curve was plotted in the range of 0.5 to 6 µg mL-1 and the limits of detection and quantitation were calculated to be 3.1 × 10-5 µg mL-1 and 1.0 × 10-4 µg mL-1, respectively. The mean, RSD, and relative bias for 0.5 µg mL-1 (n=5) were found to be 0.49 µg mL-1, 0.3%, and 2%, respectively. Finally, the proposed method was successfully used for the determination of tamoxifen in serum and pharmaceutical samples.

scholarly journals Electrochemical Determination of Trace Pb (II) by The Modified Glassy Carbon Electrode Compositing MultiWalled Carbon Nanotubes-Nafion-Bi Film

2020 ◽  
pp. 1-12
Keyword(s):  
Carbon Nanotubes ◽  
Glassy Carbon Electrode ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Anodic Stripping Voltammetry ◽  
Electrochemical Sensing ◽  
Carbon Electrode ◽  
Bismuth Film ◽  
Modified Glassy Carbon Electrode

A modified glassy carbon electrode (GCE) compositing multi-walled carbon nanotubes (MWCNTs), Nafion and bismuth film was prepared and applied for the sensitive detection of trace Pb (II). MWCNTs were dispersed into ethanol by ultrasonication in the presence of Nafion and the nanotubes are coated onto the bare GCE. After that, an extra Nafion adhesion agent is added to the electrode. By the in situ plating, a bismuth film was fabricated on the MWCNTs-NA/GCE, making the desired electrode, MWCNTs-NA-Bi/GCE. The modified electrode was characterized by differential pulse anodic stripping voltammetry, scanning electron microscopy, and cyclic voltammetry. A deposition potential of –1.4 V (vs. Ag/AgCl) and a deposition time of 300 s were applied to the working electrode under stirred conditions after optimizing. Nanotubes and Nafion concentrations and pH were carefully optimized to determine trace lead ions by using the electrode as an electrochemical-sensing platform. Nafion effectively increased the stability and adhesivity of the composite film. The MWCNTs-NA-Bi film modified electrode can remarkably increase the anodic peak current of Pb2+. The sensitivity of MWCNTs-NA-Bi/GCE is 4.35 times higher than that of the bare GCE with bismuth film. The prepared electrode showed excellent stability and reproducibility and can be applied for determination of Pb2+ contained wastewater.

scholarly journals Voltammetric determination of dopamine in the presence of ascorbic and uric acids using partial least squares regression: determination of dopamine in human urine and plasma

2009 ◽  
Vol 7 (3) ◽  
pp. 524-531 ◽  
Author(s):  
Morteza Bahram ◽  
Khalil Farhadi ◽  
Farzin Arjmand
Keyword(s):  
Least Squares ◽  
Partial Least Squares ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Limit Of Detection ◽  
Relative Standard Error ◽  
Carbon Electrode ◽  
Least Squares Regression ◽  
Relative Standard

AbstractA new differential pulse voltammetric method for dopamine determination at a bare glassy carbon electrode has been developed. Dopamine, ascorbic acid (AA) and uric acid (UA) usually coexist in physiological samples. Because AA and UA can be oxidized at potentials close to that of DA it is difficult to determine dopamine electrochemically, although resolution can be achieved using modified electrodes. Additionally, oxidized dopamine mediates AA oxidation and the electrode surface can be easily fouled by the AA oxidation product. In this work a chemometrics strategy, partial least squares (PLS) regression, has been applied to determine dopamine in the presence of AA and UA without electrode modification. The method is based on the electrooxidation of dopamine at a glassy carbon electrode in pH 7 phosphate buffer. The dopamine calibration curve was linear over the range of 1–313 μM and the limit of detection was 0.25 μM. The relative standard error (RSE %) was 5.28%. The method has been successfully applied to the measurement of dopamine in human plasma and urine.

Ultra-Sensitive Anodic Stripping Voltammetry for the Determination of Xanthine at a Glassy Carbon Electrode

2004 ◽  
Vol 144 (4) ◽  
pp. 249-256 ◽  
Author(s):  
Mohamed S. Ibrahim ◽  
Yassien M. Temerk ◽  
Moustafa M. Kamal ◽  
Gamal A.-W. Ahmed ◽  
Hossieny S. M. Ibrahim
Keyword(s):  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Anodic Stripping Voltammetry ◽  
Stripping Voltammetry ◽  
Carbon Electrode ◽  
Anodic Stripping

scholarly journals Glassy carbon and boron doped glassy carbon electrodes for voltammetric determination of linuron herbicide in the selected samples

2012 ◽  
Vol 10 (4) ◽  
pp. 1271-1279 ◽  
Author(s):  
Jelena Đorđević ◽  
Ana Kalijadis ◽  
Ksenija Kumrić ◽  
Zoran Jovanović ◽  
Zoran Laušević ◽  
...  
Keyword(s):  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Supporting Electrolyte ◽  
Electrochemical Determination ◽  
Temperature Treatment ◽  
Voltammetric Determination ◽  
Carbon Electrode ◽  
Glassy Carbon Electrodes ◽  
Boron Doped

AbstractIn this study the application of home-made unmodified (GC) and bulk modified boron doped glassy carbon (GCB) electrodes for the voltammetric determination of the linuron was investigated. The electrodes were synthesized with a moderate temperature treatment (1000°C). Obtained results were compared with the electrochemical determination of the linuron using a commercial glassy carbon electrode (GC-Metrohm). The peak potential (E p ) of linuron oxidation in 0.1 mol dm−3 H2SO4 as electrolyte was similar for all applied electrodes: 1.31, 1.34 and 1.28 V for GCB, GC and GC-Metrohm electrodes, respectively. Potential of linuron oxidation and current density depend on the pH of supporting electrolyte. Applying GCB and GC-Metrohm electrodes the most intensive electrochemical response for linuron was obtained in strongly acidic solution (0.1 mol dm−3 H2SO4). Applying the boron doped glassy carbon electrode the broadest linear range (0.005–0.1 µmol cm−3) for the linuron determination was obtained. The results of voltammetric determination of the linuron in spiked water samples showed good correlation between added and found amounts of linuron and also are in good agreement with the results obtained by HPLC-UV method. This appears to be the first application of a boron doped glassy carbon electrode for voltammetric determination of the environmental important compounds.

Sign in / Sign up

Export Citation Format

Share Document