scholarly journals Synthesis and Characterization of LiNi1/3Co1/3Mn1/3O2 as Cathode Materials for Li-Ion Batteries via an Efficacious Sol- Gel Method

Author(s):  
Xiaoyu Cao ◽  
2013 ◽  
Vol 01 (04) ◽  
pp. 1340015
Author(s):  
WENJUAN HAO ◽  
HAN CHEN ◽  
YANHONG WANG ◽  
HANHUI ZHAN ◽  
QIANGQIANG TAN ◽  
...  

Li [ Li 0.2 Mn 0.56 Ni 0.16 Co 0.08] O 2 cathode materials for Li -ion batteries were synthesized by a facile sol–gel method followed by calcination at various temperatures (700°C, 800°C and 900°C). Lithium acetate dihydrate, manganese (II) acetate tetrahydrate, nickel (II) acetate tetrahydrate and cobalt (II) acetate tetrahydrate are employed as the metal precursors, and citric acid monohydrate as the chelating agent. For the obtained Li [ Li 0.2 Mn 0.56 Ni 0.16 Co 0.08] O 2 materials, the metal components existed in the form of Mn 4+, Ni 2+ and Co 3+, and their molar ratio was in good agreement with 0.56 : 0.16 : 0.08. The calcination temperature played an important role in the particle size, crystallinity and further electrochemical properties of the cathode materials. The Li [ Li 0.2 Mn 0.56 Ni 0.16 Co 0.08] O 2 material calcined at 800°C for 6 h showed the best electrochemical performances. Its discharge specific capacities cycled at 0.1 C, 0.5 C, 1 C and 2 C rates were 266.0 mAh g−1, 243.1 mAh g−1, 218.2 mAh g−1 and 192.9 mAh g−1, respectively. When recovered to 0.1 C rate, the discharge specific capacity was 260.2 mAh g−1 and the capacity loss is only 2.2%. This work demonstrates that the sol–gel method is a facile route to prepare high performance Li [ Li 0.2 Mn 0.56 Ni 0.16 Co 0.08] O 2 cathode materials for Li -ion batteries.


2016 ◽  
Vol 42 (1) ◽  
pp. 1897-1902 ◽  
Author(s):  
Li Yang ◽  
Guoxi Xi ◽  
Tianjun Lou ◽  
Xinsheng Wang ◽  
Jingjing Wang ◽  
...  

2007 ◽  
Vol 11 (12) ◽  
pp. 1671-1677 ◽  
Author(s):  
K. Suryakala ◽  
K. R. Marikkannu ◽  
G. Paruthimal Kalaignan ◽  
T. Vasudevan

2014 ◽  
Vol 14 (9) ◽  
pp. 7060-7065 ◽  
Author(s):  
Shuxin Liu ◽  
Hengbo Yin ◽  
Haibin Wang ◽  
Hong Wang

2021 ◽  
Author(s):  
Nanda Saridewi ◽  
Heri T. Syaputro ◽  
Isalmi Aziz ◽  
Dasumiati Dasumiati ◽  
Biaunik N. Kumila

2011 ◽  
Vol 13 (6) ◽  
pp. 1232-1234 ◽  
Author(s):  
Vaishali Patil ◽  
Arun Patil ◽  
Ji-Won Choi ◽  
Seok-Jin Yoon

2006 ◽  
Vol 60 (20) ◽  
pp. 2443-2446 ◽  
Author(s):  
Yan Feng Zhang ◽  
Jiu Xing Zhang ◽  
Qing Mei Lu ◽  
Qing Yun Zhang

2011 ◽  
Vol 37 (1) ◽  
pp. 175-180 ◽  
Author(s):  
Masoud Hafezi-Ardakani ◽  
Fatollah Moztarzadeh ◽  
Mohammad Rabiee ◽  
Ali Reza Talebi

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