scholarly journals Fabrication of Nanostructured Functional Materials Using Exfoliated Nanosheets as a Building Block

2007 ◽  
Vol 115 (1337) ◽  
pp. 9-16 ◽  
Author(s):  
Takayoshi SASAKI
Keyword(s):  
Building Block ◽  
Functional Materials

[closo-B10H8-1,10-(COOH)2]2-: A building block for functional materials?

2022 ◽  
Author(s):  
Szymon Kapuscinski ◽  
Oleksandr Hietsoi ◽  
Anna Pietrzak ◽  
Andrienne C. Friedli ◽  
Piotr Kaszynski
Keyword(s):  
Building Block ◽  
Functional Materials

[closo-B10H8-1,10-(COOH)2]2- was obtained in five steps and 40% overall yield from [closo-B10H10]2-. It can converted to [closo-B10H8-1,10-(CO)2] and subsequently to carbonium ylides [closo-B10H8-1-COOH-10-(C(NRCH2)2)]. The diacid, its derivatives and also di-ylide...

Acenaphthylene as a building block for π-electron functional materials

2021 ◽  
Vol 9 (37) ◽  
pp. 12448-12461
Author(s):  
Ying-Hsuan Liu ◽  
Dmitrii F. Perepichka
Keyword(s):  
Building Block ◽  
Functional Materials ◽  
Optoelectronic Properties ◽  
Conjugated Molecules

The paper reviews synthetic design and optoelectronic properties of π-conjugated molecules and polymers based on the acenaphthylene building block.

Functional architectures derived from guanine quartets

2016 ◽  
Vol 14 (7) ◽  
pp. 2157-2163 ◽  
Author(s):  
Jyotirmayee Dash ◽  
Puja Saha
Keyword(s):  
Ion Channels ◽  
Building Block ◽  
Functional Materials ◽  
Self Assembling ◽  
Recent Developments ◽  
Design And Construction

This paper highlights recent developments in the design and construction of functional materials such as supramolecular hydrogels and ion channels using a guanine motif as a self-assembling building block.

scholarly journals Triazole: a unique building block for the construction of functional materials

2011 ◽  
Vol 47 (31) ◽  
pp. 8740 ◽  
Author(s):  
Michal Juríček ◽  
Paul H. J. Kouwer ◽  
Alan E. Rowan
Keyword(s):  
Building Block ◽  
Functional Materials

scholarly journals Macroheterocyclic Compounds - a Key Building Block in New Functional Materials and Molecular Devices

2020 ◽  
Vol 13 (4) ◽  
pp. 311-467
Author(s):  
Oskar I. Koifman ◽  
Tatyana A. Ageeva ◽  
Irina P. Beletskaya ◽  
Alexei D. Averin ◽  
Alexei A. Yakushev ◽  
...  
Keyword(s):  
Building Block ◽  
Functional Materials ◽  
Molecular Devices ◽  
Macroheterocyclic Compounds

scholarly journals Linking metal-organic cages pairwise as a design approach for assembling multivariate crystalline materials

2021 ◽  
Author(s):  
Adrian Markwell-Heys ◽  
Michael Roemelt ◽  
Ashley Slattery ◽  
Oliver Linder-Patton ◽  
Witold Bloch
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Building Blocks ◽  
Design Approach ◽  
Crystalline Materials ◽  
Chemical Complexity ◽  
Pore Architecture ◽  
Metal Organic ◽  
Powerful Strategy

Using metal-organic cages (MOCs) as preformed supermolecular building-blocks (SBBs) is a powerful strategy to design functional metal-organic frameworks (MOFs) with control over the pore architecture and connectivity. However, introducing chemical complexity into the network via this route is limited as most methodologies focus on only one type of MOC as the building-block. Herein we present the pairwise linking of MOCs as a design approach to introduce defined chemical complexity into porous materials. Our methodology exploits preferential Rh-aniline coordination and stoichiometric control to rationally link Cu4L4 and Rh4L4 MOCs into chemically complex, yet extremely well-defined crystalline solids. This strategy is expected to open up significant new possibilities to design bespoke multi-functional materials with atomistic control over the location and ordering of chemical functionalities.

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