scholarly journals Linking metal-organic cages pairwise as a design approach for assembling multivariate crystalline materials

2021 ◽  
Author(s):  
Adrian Markwell-Heys ◽  
Michael Roemelt ◽  
Ashley Slattery ◽  
Oliver Linder-Patton ◽  
Witold Bloch
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Building Blocks ◽  
Design Approach ◽  
Crystalline Materials ◽  
Chemical Complexity ◽  
Pore Architecture ◽  
Metal Organic ◽  
Powerful Strategy

Using metal-organic cages (MOCs) as preformed supermolecular building-blocks (SBBs) is a powerful strategy to design functional metal-organic frameworks (MOFs) with control over the pore architecture and connectivity. However, introducing chemical complexity into the network via this route is limited as most methodologies focus on only one type of MOC as the building-block. Herein we present the pairwise linking of MOCs as a design approach to introduce defined chemical complexity into porous materials. Our methodology exploits preferential Rh-aniline coordination and stoichiometric control to rationally link Cu4L4 and Rh4L4 MOCs into chemically complex, yet extremely well-defined crystalline solids. This strategy is expected to open up significant new possibilities to design bespoke multi-functional materials with atomistic control over the location and ordering of chemical functionalities.

scholarly journals Linking metal-organic cages pairwise as a design approach for assembling multivariate crystalline materials

2021 ◽  
Author(s):  
Adrian W Markwell-Heys ◽  
Michael Roemelt ◽  
Ashley D Slattery ◽  
Oliver Michael Linder-Patton ◽  
Witold Marek Bloch
Keyword(s):  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Design Approach ◽  
Crystalline Materials ◽  
Pore Architecture ◽  
Metal Organic ◽  
Powerful Strategy

Using metal-organic cages (MOCs) as preformed supermolecular building-blocks (SBBs) is a powerful strategy to design functional metal-organic frameworks (MOFs) with control over the pore architecture and connectivity. However, introducing chemical...

Planar-chiral building blocks for metal–organic frameworks

2015 ◽  
Vol 51 (23) ◽  
pp. 4796-4798 ◽  
Author(s):  
Murat Cakici ◽  
Zhi-Gang Gu ◽  
Martin Nieger ◽  
Jochen Bürck ◽  
Lars Heinke ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Chiral Building Block ◽  
Metal Organic

The first example of a planar-chiral building block being used for chiral metal–organic frameworks (MOFs) is presented.

Extended metal-carbohydrate frameworks

2014 ◽  
Vol 86 (9) ◽  
pp. 1323-1334 ◽  
Author(s):  
Zhichang Liu ◽  
J. Fraser Stoddart
Keyword(s):  
Materials Science ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Environmentally Benign ◽  
Crystalline Materials ◽  
The World ◽  
Potential Applications ◽  
Metal Organic ◽  
Industry And Commerce

AbstractCyclodextrins (CDs) – a family of cyclic oligosaccharides – are ideal building blocks for the construction of environmentally benign materials. Herein, we reflect upon the serendipitous discovery of two classes of extended crystalline materials – referred to as cyclodextrin metal-organic frameworks (CD-MOFs) and CD-Bamboo – based on CDs which offer opportunities for potential applications in the world of industry and commerce all the way from sequestering carbon dioxide to extracting gold in an eco-friendly manner. The crucial role of serendipity in scientific research expresses itself two times over at the boundaries between coordination chemistry with materials science.

scholarly journals Porphyrin MOF-Derived Porous Carbons: Preparation and Applications

2021 ◽  
Vol 7 (2) ◽  
pp. 47
Author(s):  
Flávio Figueira ◽  
Filipe A. Almeida Paz
Keyword(s):  
Chemical Composition ◽  
Carbon Material ◽  
Metal Organic Frameworks ◽  
Electrochemical Reactions ◽  
Porous Carbon Material ◽  
Important Class ◽  
Porous Carbons ◽  
Preparation Methods ◽  
Crystalline Materials ◽  
Metal Organic

Metal–organic frameworks (MOFs) are crystalline materials with permanent porosity, composed of metal nodes and organic linkers whose well-ordered arrangement enables them to act as ideal templates to produce materials with a uniform distribution of heteroatom and metal elements. The hybrid nature of MOFs, well-defined pore structure, large surface area and tunable chemical composition of their precursors, led to the preparation of various MOF-derived porous carbons with controlled structures and compositions bearing some of the unique structural properties of the parent networks. In this regard, an important class of MOFs constructed with porphyrin ligands were described, playing significant roles in the metal distribution within the porous carbon material. The most striking early achievements using porphyrin-based MOF porous carbons are here summarized, including preparation methods and their transformation into materials for electrochemical reactions.

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

Four metal–organic frameworks built from distinct secondary building blocks: Syntheses, structures, photoluminescence and photocatalytical properties

Polyhedron ◽  
2014 ◽  
Vol 70 ◽  
pp. 180-187 ◽  
Author(s):  
Peng Du ◽  
Yan Yang ◽  
Ying-Ying Liu ◽  
Yuan-Chun He ◽  
Hong-Mei Zhang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Metal Organic

A Molecular Artisans Guide to Supramolecular Coordination Complexes and Metal Organic Frameworks

2015 ◽  
Vol 03 (01n02) ◽  
pp. 1540004 ◽  
Author(s):  
Xialu Wu ◽  
David J. Young ◽  
T. S. Andy Hor
Keyword(s):  
Chemical Reactivity ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Coordination Complexes ◽  
Large Molecules ◽  
Molecular Building Blocks ◽  
Supramolecular Coordination ◽  
Metal Organic ◽  
Molecular Synthesis ◽  
And Function

As molecular synthesis advances, we are beginning to learn control of not only the chemical reactivity (and function) of molecules, but also of their interactions with other molecules. It is this basic idea that has led to the current explosion of supramolecular science and engineering. Parallel to this development, chemists have been actively pursuing the design of very large molecules using basic molecular building blocks. Herein, we review the general development of supramolecular chemistry and particularly of two new branches: supramolecular coordination complexes (SCCs) and metal organic frameworks (MOFs). These two fields are discussed in detail with typical examples to illustrate what is now possible and what challenges lie ahead for tomorrow's molecular artisans.

Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks

2008 ◽  
Vol 130 (6) ◽  
pp. 1833-1835 ◽  
Author(s):  
Farid Nouar ◽  
Jarrod F. Eubank ◽  
Till Bousquet ◽  
Lukasz Wojtas ◽  
Michael J. Zaworotko ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Building Blocks ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Highly Porous

A series of porous 3D inorganic–organic hybrid framework crystalline materials based on 5-aminoisophthalic acid for photocatalytic degradation of crystal violet

2021 ◽  
Vol 45 (7) ◽  
pp. 3432-3440
Author(s):  
Yu Xin ◽  
Jun Zhou ◽  
Yong Heng Xing ◽  
Feng Ying Bai ◽  
Li Xian Sun
Keyword(s):  
Photocatalytic Degradation ◽  
Crystal Violet ◽  
Metal Organic Frameworks ◽  
Synthetic Method ◽  
Crystalline Materials ◽  
Organic Hybrid ◽  
Hybrid Framework ◽  
Metal Organic ◽  
Degradation Properties

Seven 3D metal-organic frameworks have been designed and synthesized by the hydrothermal synthetic method based on the ligand 5-aminoisophthalic acid. Complexes 1-4 have better photocatalytic degradation properties for dyes CV.

Sign in / Sign up

Export Citation Format

Share Document