scholarly journals Dynamic heterogeneity in active glass-forming liquids is qualitatively different compared to its equilibrium behaviour

Author(s):  
Kallol Paul ◽  
Saroj Kumar Nandi ◽  
Smarajit Karmakar

Abstract Activity driven glassy dynamics is ubiquitous in collective cell migration,intracellular transport, dynamics in bacterial and ants colonies as well as artificially driven synthetic systems such as vibrated granular materials, etc. Active glasses are hitherto assumed to be qualitatively similar to their equilibrium counterparts at a suitably defined effective temperature, ff. Combining large-scale simulations with analytical mode-coupling theory for such systems, we show that, in fact, an active glass is qualitatively different from an equilibrium glassy system. Although the relaxation dynamics can be similar to an equilibrium system at a ff, effects of activity on the dynamic heterogeneity (DH), which has emerged as a cornerstone of glassy dynamics, is quite nontrivial and complex. In particular, active glasses show dramatic growth of DH, and systems with similar relaxation time and ff can have widely varying DH. Comparison of our non-equilibrium extended mode-coupling theory for such systems with simulation results show that the theory captures the basic characteristics of such systems. Our study raises fundamental questions on the supposedly central role of DH in controlling the relaxation dynamics in a glassy system and can have important implications even for the equilibrium glassy dynamics.

2008 ◽  
Author(s):  
Song-Ho Chong ◽  
Michio Tokuyama ◽  
Irwin Oppenheim ◽  
Hideya Nishiyama

1995 ◽  
Vol 407 ◽  
Author(s):  
Yongwu Yang ◽  
Laura J. Muller ◽  
Keith A. Nelson

ABSTRACTImpulsive stimulated thermal scattering (ISTS), a time-domain light scattering technique, provides a more than 6-decade time range from sub-ns to many ms. It permits characterization of the structural relaxation dynamics and determination of the relaxation strength or Debye-Waller factor in supercooled liquids, and thus allows testing of the mode coupling theory of the liquidglass transition. ISTS experiments were performed on glass formers salol, butylbenzene, and the molten salt [Ca(N03)]0.4[KNO3]0.6. The relaxational dynamics and the Debye-Waller factorfq=0 were obtained. A square-root anomaly was observed in fq=0 (T) at a crossover temperature Tc for all three materials, consistent with the prediction of mode coupling theory.


1998 ◽  
Vol 235-237 ◽  
pp. 254-267 ◽  
Author(s):  
H.Z Cummins ◽  
Y.H Hwang ◽  
Gen Li ◽  
W.M Du ◽  
W Losert ◽  
...  

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