Europium oxidation state and local structure in silicate glasses

2012 ◽  
Vol 97 (5-6) ◽  
pp. 918-929 ◽  
Author(s):  
M. R. Cicconi ◽  
G. Giuli ◽  
E. Paris ◽  
W. Ertel-Ingrisch ◽  
P. Ulmer ◽  
...  
Author(s):  
Gabriele Giuli ◽  
Sigrid Griet Eeckhout ◽  
Maria Rita Cicconi ◽  
Christian Koeberl ◽  
Giovanni Pratesi ◽  
...  

2002 ◽  
Vol 47 (19) ◽  
pp. 3151-3161 ◽  
Author(s):  
A.N Mansour ◽  
P.H Smith ◽  
W.M Baker ◽  
M Balasubramanian ◽  
J McBreen

2010 ◽  
Vol 114 (7) ◽  
pp. 3309-3317 ◽  
Author(s):  
E. Deprez ◽  
Miguel A. Muñoz-Márquez ◽  
Manuel A. Roldán ◽  
C. Prestipino ◽  
F. Javier Palomares ◽  
...  

2021 ◽  
Vol 1 (1) ◽  
pp. 1-4
Author(s):  
Vera Laviara Maghfirohtuzzoimah ◽  
Sahara Hamas Intifadhah ◽  
Pelangi Az-zahra ◽  
Wantana Klysubun ◽  
Dita Puspita Sari ◽  
...  

The oxidation state and local structure of LiFeSi0.01P0.99O4/C composites as a cathode on lithium-ion battery were investigated by Fe K-edge X-ray Absorption Near Edge Spectroscopy (XANES) and Extended X-ray Absorption Fine Structure (EXAFS). The LiFeSi0.01P0.99O4/C sample was prepared by solid-state reaction process. Based on the XANES analysis, the absorption of edge energy (E0) of the sample was 7124.92 eV. In addition, linear combination fitting (LCF) analysis of XANES confirmed the oxidation state of iron mixture of 2+ and 3+ as the effect of silicon doped in LiFePO4. The Fourier Transform (FT) of the Fe K-edge EXAFS fitting analysis showed that the nearest neighbors surrounding atom Fe were the main peak with high intensity that confirmed Fe-O bond; the second and third peak with lower intensity confirmed Fe-P and Fe-Fe bonds, respectively. In addition, the SQUID magnetometer result of LiFeSi0.01P0.99O4/C indicated the antiferromagnetic order temperature of LiFeSi0.01P0.99O4/C at ~51 K with the indication of the presence of impurity and structural distortion.


2011 ◽  
Vol 45 (17) ◽  
pp. 7267-7274 ◽  
Author(s):  
Regina Kirsch ◽  
David Fellhauer ◽  
Marcus Altmaier ◽  
Volker Neck ◽  
Andre Rossberg ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3539
Author(s):  
Andris Antuzevics ◽  
Guna Krieke ◽  
Haralds Ozols ◽  
Andris Fedotovs ◽  
Anatolijs Sarakovskis ◽  
...  

LaOCl doped with 0–10 mol% Cr was synthesized by thermal decomposition of chlorides. X-ray diffraction (XRD) analysis revealed that incorporation of chromium results in a decrease of the lattice parameter a and a simultaneous increase of the lattice parameter c. The local structure of chromium ions was studied with X-ray photoelectron (XPS), X-ray absorption (XANES), multifrequency electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) spectroscopy techniques. It was determined that synthesis in oxidizing atmosphere promotes the incorporation of chromium ions predominantly in the 5+ oxidation state. Changes of chromium oxidation state and local environment occur after a subsequent treatment in reducing atmosphere. Spin-Hamiltonian (SH) parameters for a Cr5+ and two types of Cr3+ centers in LaOCl were determined from the EPR spectra simulations.


2014 ◽  
Vol 68 ◽  
pp. 179-188 ◽  
Author(s):  
A.H. Pohl ◽  
A.A. Guda ◽  
V.V. Shapovalov ◽  
R. Witte ◽  
B. Das ◽  
...  

2004 ◽  
Vol 108 (42) ◽  
pp. 16372-16376 ◽  
Author(s):  
Aline Léon ◽  
Oliver Kircher ◽  
Jörg Rothe ◽  
Maximilian Fichtner

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