scholarly journals Literature survey: methods for the removal of iodine species from off-gases and liquid waste streams of nuclear power and nuclear fuel reprocessing plants, with emphasis on solid sorbents

Author(s):  
D.W. Holladay
2021 ◽  
Author(s):  
Yayoi Inomata ◽  
Michio Aoyama

<p>The spatial and temporal variations in <sup>137</sup>Cs concentrations in the surface seawater in the global ocean from 1957 to 2018 were analyzed by using the ''HAM database - global 2018'' and “IAEA-MARIS database” in order to understand the behaviors of <sup>137</sup>Cs originated atmospheric weapons tests, nuclear fuel reprocessing plants, and nuclear power plant accidents at Chernobyl and Fukushima. The global ocean was divided into 37 boxes. The 0.5yr average value of <sup>137</sup>Cs, apparent half residence times (Tap), and <sup>137</sup>Cs inventory in each box was estimated. The 0.5yr average value of <sup>137</sup>Cs in each oceanic region (box) indicate that <sup>137</sup>Cs decreased exponentially from 1970 to 2010 in the Pacific Ocean (PO), Indian Ocean (IO), and Atlantic Ocean (AO), except for the Arctic Ocean, North Atlantic Ocean and its marginal sea due to the discharge of<sup> 137</sup>Cs from the nuclear fuel reprocessing plants. The geographical difference of <sup>137</sup>Cs activity concentrations in the global ocean become to be small in the year of 2010. The temporal variation of <sup>137</sup>Cs column inventory suggests that <sup>137</sup>Cs derived from the large scale atmospheric weapon tests exist largely in the subtropical NPO, equatorial PO, and subtropical SPO (25°N-25°S). <sup>137</sup>Cs transport from the PO to the IO occurs in the region from 0°-15°S via Indonesian through flow. The signature of <sup>137</sup>Cs transport from the IO to the AO is also detected. The <sup>137</sup>Cs inventory in the surface seawater in the year 2010 is estimated to be 57±17 PBq. Considering that the radioactive decay <sup>137</sup>Cs are estimated to be 347 PBq, the<sup> 137</sup>Cs existed into the ocean interior is estimated to 173±52 PBq. These indicate that about 30% of <sup>137</sup>Cs released into the surface seawater have been transported into the ocean interior in 2010. The <sup>137</sup>Cs inventory in 2011 in the surface seawater in the global ocean were 69±15 PBq. The<sup> 137</sup>Cs released by the Fukushima Nuclear Power Plant 1 accident increased to 16.5±4.8 PBq and this value is in good agreement with previous studies.</p>


2002 ◽  
Vol 17 (5) ◽  
pp. 541-543 ◽  
Author(s):  
Wendy A. Reed ◽  
Iain May ◽  
Francis R. Livens ◽  
John M. Charnock ◽  
Andrew P. Jeapes ◽  
...  

2002 ◽  
Vol 90 (3) ◽  
Author(s):  
Y. Sugo ◽  
Y. Sasaki ◽  
S. Tachimori

SummaryHydrolytic and radiolytic stabilities of a promising extractant, N,N,N′,N′-tetraoctyl-3-oxapentane-1,5-diamide (TODGA), for actinides in high-level radioactive liquid waste from nuclear fuel reprocessing were investigated in air at room temperature. Hydrolysis by nitric acid was not observed, whereas radiolysis by gamma irradiation was notably observed. The radiolysis study showed that an amide-bond, an ether-bond, and a bond adjacent to the ether-bond tended to be broken by gamma irradiation, and dioctylamine and various N,N-dioctylmonoamides were identified as the main degradation products by GC/MS and NMR analyses. The


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