scholarly journals FY05 HPCRM Annual Report: High-Performance Corrosion-Resistant Iron-Based Amorphous Metal Coatings Evaluation of Corrosion Reistance FY05 HPCRM Annual Report # Rev. 1DOE-DARPA Co-Sponsored Advanced Materials Program

2007 ◽  
Author(s):  
J Farmer ◽  
J Haslam ◽  
S Day
Author(s):  
J. C. Farmer ◽  
J. J. Haslam ◽  
S. D. Day ◽  
D. J. Branagan ◽  
C. A. Blue ◽  
...  

New corrosion-resistant, iron-based amorphous metals have been identified from published data or developed through combinatorial synthesis, and tested to determine their relative corrosion resistance. Many of these materials can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS # N06022) in some very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. One of these compositions, SAM1651, is discussed in detail to illustrate the promise of this general class of materials.


2007 ◽  
Vol 22 (8) ◽  
pp. 2297-2311 ◽  
Author(s):  
J.C. Farmer ◽  
J.J. Haslam ◽  
S.D. Day ◽  
T. Lian ◽  
C.K. Saw ◽  
...  

An iron-based amorphous metal, Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4 (SAM2X5), with very good corrosion resistance has been developed. This material was prepared as a melt-spun ribbon, as well as gas atomized powder and a thermal-spray coating. During electrochemical testing in several environments, including seawater at 90 °C, the passive film stability was found to be comparable to that of high-performance nickel-based alloys and superior to that of stainless steels, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates. This material also performed very well in standard salt fog tests. Chromium (Cr), molybdenum (Mo), and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber and suitable for criticality control applications. This material and its parent alloy maintained corrosion resistance up to the glass transition temperature and remained in the amorphous state during exposure to relatively high neutron doses.


2009 ◽  
Vol 40 (6) ◽  
pp. 1289-1305 ◽  
Author(s):  
Joseph Farmer ◽  
Jor-Shan Choi ◽  
Cheng Saw ◽  
Jeffrey Haslam ◽  
Dan Day ◽  
...  

Author(s):  
Karl V. Hoose ◽  
Eric E. Shorey

The traditional reciprocating I.C. engine has evolved to a point where significant improvements in thermal efficiency and specific power are not expected. Modifications to existing engines may prove to be difficult and expensive while resulting in only marginal gains. In addition, most modifications result in added components that often increase cost and decrease reliability of the system as a whole. For applications requiring major advances in performance, such as unmanned vehicles, meeting mission requirements will likely stem from a revolutionary rather than an evolutionary engine design. The slider crank mechanism is a major impediment to the traditional reciprocating I.C. engine. Although this mechanism has been used for the past 100 years, it is very wasteful of the available energy supplied by the combustion process, where piston-liner interactions from this arrangement accounts for 50–70% of the total friction losses in this engine design. Eliminating the slider crank could significantly reduce friction losses and provide additional benefits that can increase fuel conversion efficiency. The HiPerTEC engine is an opposed, free-piston engine arranged in a toroidal configuration with two counter reciprocating sets of pistons. The counter reciprocating masses eliminate the vibration found in linear free-piston engines. The HiPerTEC employs a unique shared volume configuration where the swept volume is twice the physical cylinder volume. This attribute offers a significant increase in specific power, while the free-piston characteristics provide for substantial gains in thermodynamic cycle efficiency. An eight cylinder/chamber arrangement offers balanced operation in both two and four-stroke cycle modes to allow for a wide operating envelope. The final HiPerTEC configuration will require advanced materials to address lubrication and cooling requirements. This paper discusses the HiPerTEC design, operating characteristics, development progress to date, and the challenges that lie ahead.


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