Recent Advancement in MoS2 for Hydrogen Evolution Reactions

2020 ◽  
Vol 3 (1) ◽  
pp. 11-25
Author(s):  
Kwadwo Mensah-Darkwa ◽  
Rita N. Tabi ◽  
Maxwell Owusu ◽  
Tenzin Ingsel ◽  
Pawan K. Kahol ◽  
...  

The economic growth of any country depends on certain factors of which energy is a part and even prominent. The global economy has depended heavily on fossil fuels as the main source of reliable energy for so many decades. Their adverse long-term impact on society has led to a substantial increase in research activities both in industry and academia. Most of the research has been dominated by the development of green energy technologies and the expansion of such technologies in order to meet increasing future demands of energy. Prominent among the research drive is the development of fuel cells, whose driving force comes from hydrogen. This is because hydrogen is economical considering its relative abundance, low cost, yet high activity in production. Materials such as Pt, C, Fe, MoS2 have gained popularity in the production of hydrogen for use in fuel cell devices. The high efficiency of MoS2, amorphous or crystalline, in hydrogen evolution reactions (HER) depends on a suitable architecture that increases the exposure of its edge sites. Such architecture could be determined by the design of catalysts in terms of proportions of molybdenum and dopant ions, the composite structure between MoS2 and electrically conductive materials, synthesis temperature and the synthesis method. Therefore, a review is made on recent achievements for different nanoarchitectures of MoS2 as well as its composite structures for use as electro-catalysts in HER performance and future prospects.

2021 ◽  
Author(s):  
Meng Wang ◽  
Zepeng Lv ◽  
Xuewei Lv ◽  
Qian Li ◽  
Jie Dang

Abstract Density functional theory (DFT) calculation indicators (ΔG, densities of state, D-band and bader charge) are commonly used to predict and analyze the hydrogen evolution reaction (HER) activity of catalysts, and most studies discuss only one or few of these indicators’ impact on catalysis, but still no report has comprehensively evaluated the influence of all these indicators on catalytic performance. Herein, foreseen by comprehensive consideration first, we report transition metal doped Ni3N nanosheets combined on Ni foam for utra-efficient alkaline hydrogen evolution. For dual transition metals doped Ni3N, Co,V-Ni3N exhibits remarkable HER performance with a significantly low overpotential of only 10 mV in alkaline electrolyte and 41 mV in alkaline seawater electrolyte at 10 mA cm− 2; while for single transition metal doped Ni3N, V-Ni3N exhibits the best performance with an overpotential of 15 mV and a Tafel slope of 37 mV dec− 1. Our work highlights the importance of comprehensive evaluation of DFT calculation indexes, and opens up a new method for the rational design of efficient and low-cost catalysts.


Author(s):  
Minmin Wang ◽  
Tongming Sun ◽  
Weiting Zhong ◽  
Mengke Zhang ◽  
Jin Wang ◽  
...  

Transition metal-based nanohybrid has recently been demonstrated an electrocatalyst which show great potential to replace commercial precious metal catalysts in hydrogen evolution reactions. Herein, tungsten trioxide/nickel disulfide (WO3/Ni3S2) heterojunction is...


2015 ◽  
Vol 112 (16) ◽  
pp. 4964-4969 ◽  
Author(s):  
Joseph A. Rollin ◽  
Julia Martin del Campo ◽  
Suwan Myung ◽  
Fangfang Sun ◽  
Chun You ◽  
...  

The use of hydrogen (H2) as a fuel offers enhanced energy conversion efficiency and tremendous potential to decrease greenhouse gas emissions, but producing it in a distributed, carbon-neutral, low-cost manner requires new technologies. Herein we demonstrate the complete conversion of glucose and xylose from plant biomass to H2 and CO2 based on an in vitro synthetic enzymatic pathway. Glucose and xylose were simultaneously converted to H2 with a yield of two H2 per carbon, the maximum possible yield. Parameters of a nonlinear kinetic model were fitted with experimental data using a genetic algorithm, and a global sensitivity analysis was used to identify the enzymes that have the greatest impact on reaction rate and yield. After optimizing enzyme loadings using this model, volumetric H2 productivity was increased 3-fold to 32 mmol H2⋅L−1⋅h−1. The productivity was further enhanced to 54 mmol H2⋅L−1⋅h−1 by increasing reaction temperature, substrate, and enzyme concentrations—an increase of 67-fold compared with the initial studies using this method. The production of hydrogen from locally produced biomass is a promising means to achieve global green energy production.


2019 ◽  
Vol 7 (12) ◽  
pp. 6708-6719 ◽  
Author(s):  
Kyoung-Won Park ◽  
Alexie M. Kolpak

Overall photocatalytic water splitting with a high efficiency has recently been observed for CoO nanoparticle suspensions in the absence of an applied bias or co-catalyst. This study clarifies the mechanism of spontaneous overall water splitting with the prominent efficiency observed on the CoO nanoparticle.


2019 ◽  
Vol 7 (8) ◽  
pp. 3752-3756 ◽  
Author(s):  
Hong Wu ◽  
Xingxing Li ◽  
Ruiqi Zhang ◽  
Jinlong Yang

Proposal of a B3S nanosheet as a low-cost and high-efficiency catalyst for hydrogen evolution.


2014 ◽  
Vol 953-954 ◽  
pp. 83-86 ◽  
Author(s):  
Lin Jun Wang ◽  
Li Xiao Xu ◽  
Jing Men ◽  
Dong Zhang ◽  
Zhang Wei Gao ◽  
...  

Solar energy is a kind of clean and green energy, its use can reduce the dual pressure of resources and environmental pollution. Firstly, this paper introduces groove, tower and dish type solar thermal power generation system. Then it introduces the components of dish-stirling system and the principle and features of stirling engine. The system has simple structure, reliable operation, high efficiency, low noise, low cost of power generation and good commercial prospects. But for some key parts of system, there are many problems that need to be solved. The main research of dish-stirling system is to optimize the key parts of system and reduce the system costs.


2016 ◽  
Vol 4 (18) ◽  
pp. 6824-6830 ◽  
Author(s):  
Heng Deng ◽  
Chi Zhang ◽  
Yunchao Xie ◽  
Travis Tumlin ◽  
Lily Giri ◽  
...  

The direct laser writing method has emerged as a novel technique for fabricating MoS2/carbon hybrid HER catalysts with low cost, high efficiency, and flexible designability.


Nanoscale ◽  
2019 ◽  
Vol 11 (48) ◽  
pp. 23318-23329 ◽  
Author(s):  
Lina Jia ◽  
Chen Li ◽  
Yaru Zhao ◽  
Bitao Liu ◽  
Shixiu Cao ◽  
...  

Non-precious metal-based electrocatalysts with high activity and stability for efficient hydrogen evolution reactions are of critical importance for low-cost and large-scale water splitting.


2020 ◽  
Vol 1 (5) ◽  
pp. 1161-1167
Author(s):  
Zhixing Cheng ◽  
Ali Saad ◽  
Samira Adimi ◽  
Haichuan Guo ◽  
Siqi Liu ◽  
...  

A new means of producing MOF derived TMN materials, which in conjunction with suitable dyes, offer high-efficiency and low-cost avenues for making photocatalysts for hydrogen production.


2021 ◽  
Author(s):  
Lijun Ma ◽  
Jing Xu ◽  
Juan Zhang ◽  
Zhenlu Liu ◽  
Xinyu Liu

The development of high-efficiency and low-cost photocatalysts for hydrogen production reaction is very important to solve energy problems. This paper studied the photocatalytic H2 evolution activity of CeO2/CoS2 heterojunction catalyst...


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