scholarly journals Kinetics of Metal Smelting Reaction Ⅰ―Rate Controlling Step and Mass Transfer Rate―

Materia Japan ◽  
2021 ◽  
Vol 60 (2) ◽  
pp. 89-95
Author(s):  
Shin-ya Kitamura
Keyword(s):  
Mass Transfer ◽  
Transfer Rate ◽  
Mass Transfer Rate ◽  
Kinetics Of ◽  
Rate Controlling Step

scholarly journals How to avoid mass transfer limitations in ozonation kinetics of phenylphenol isomers?

2016 ◽  
Vol 37 (1) ◽  
pp. 5-13 ◽  
Author(s):  
Magdalena Olak-Kucharczyk ◽  
Stanisław Ledakowicz
Keyword(s):  
Mass Transfer ◽  
Rate Constants ◽  
Transfer Rate ◽  
Mass Transfer Rate ◽  
Liquid System ◽  
Chemical Absorption ◽  
Mass Transfer Limitation ◽  
Fast Reactions ◽  
Liquid Mass Transfer ◽  
Kinetics Of

Abstract Ozonation is a heterogeneous process of chemical absorption often controlled by a gas-liquid mass transfer rate. This paper presents the results of kinetics in a reaction between phenylphenol isomers and ozone. The degradation of phenylphenol isomers during ozonation proceeds quite fast. In order to avoid the influence of mass transfer limitation the kinetics experiments were conducted in a homogenous liquid-liquid system. The second-order rate constants were determined using classical and competition methods, which are especially recommended for fast reactions. The determined rate constants at pH 2 using the two different methods are almost the same. The increase of pH causes an increase of rate constants for the reaction of phenylphenol isomers with ozone.

Free Convective Mass Transfer at Isosceles Triangular Surfaces of Varying Inclination

2003 ◽  
Vol 68 (11) ◽  
pp. 2080-2092 ◽  
Author(s):  
Martin Keppert ◽  
Josef Krýsa ◽  
Anthony A. Wragg
Keyword(s):  
Mass Transfer ◽  
Transfer Rate ◽  
Mass Transfer Rate ◽  
Mass Transfer Process ◽  
Sulfate Solution ◽  
Convective Mass Transfer ◽  
Varying Length ◽  
Inclined Surface ◽  
Vertical Case ◽  
Limiting Diffusion Current

The limiting diffusion current technique was used for investigation of free convective mass transfer at down-pointing up-facing isosceles triangular surfaces of varying length and inclination. As the mass transfer process, copper deposition from acidified copper(II) sulfate solution was used. It was found that the mass transfer rate increases with inclination from the vertical to the horizontal position and decreases with length of inclined surface. Correlation equations for 7 angles from 0 to 90° were found. The exponent in the ShL-RaL correlation ranged from 0.247 for the vertical case, indicating laminar flow, to 0.32 for inclinations of 60 to 90°, indicating mixed or turbulent flow. The general correlation ShL = 0.358(RaL sin θ)0.30 for the RaL sin θ range from 7 × 106 to 2 × 1011 and inclination range from 15 to 90° was obtained.

Distributed mass transfer rate for modelling the leaching of porous granular materials containing soluble pollutants

2000 ◽  
Vol 55 (7) ◽  
pp. 1257-1267 ◽  
Author(s):  
Tiruta-Barna Ligia ◽  
Barna Radu ◽  
Moszkowicz Pierre ◽  
Bae Hae-Ryong
Keyword(s):  
Mass Transfer ◽  
Granular Materials ◽  
Transfer Rate ◽  
Mass Transfer Rate

Enhancement of formic acid production from CO2 in formate dehydrogenase reaction using nanoparticles

RSC Advances ◽  
2016 ◽  
Vol 6 (111) ◽  
pp. 109978-109982 ◽  
Author(s):  
Young-Kee Kim ◽  
Sung-Yeob Lee ◽  
Byung-Keun Oh
Keyword(s):  
Mass Transfer ◽  
Formic Acid ◽  
Acid Production ◽  
Transfer Rate ◽  
Formate Dehydrogenase ◽  
Mass Transfer Rate ◽  
Liquid Mass ◽  
Dehydrogenase Reaction ◽  
Liquid Mass Transfer ◽  
Mesoporous Nanoparticles

In an enzyme process using a gas substrate, the enhanced gas liquid mass transfer rate of the gas substrate by methyl-functionalized mesoporous nanoparticles could improve the productivity.

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