Infinite octamolybdate chains cross-linked by paramagnetic iron (II) centers

Adrian Patrut; Adrian Nicoara; Dragos Margineanu; Michael Koop; Paul Kögerler; Hartmut Bögge; Marc Schmidtmann

doi:10.2478/bf02475576

Infinite octamolybdate chains cross-linked by paramagnetic iron (II) centers

Open Chemistry ◽

10.2478/bf02475576 ◽

2004 ◽

Vol 2 (2) ◽

pp. 323-333

Author(s):

Adrian Patrut ◽

Adrian Nicoara ◽

Dragos Margineanu ◽

Michael Koop ◽

Paul Kögerler ◽

...

Keyword(s):

Magnetic Properties ◽

Single Crystal ◽

Diffraction Analysis ◽

X Ray Diffraction ◽

X Ray ◽

Sodium Cations

AbstractThe paper presents a new polymeric polyoxomolybdate cluster with infinite octamolybdate chains cross-linked by iron (II) centers. The layer-type substance contains sodium cations sandwiched between the [Fe(H2O)4Mo8O27]∞ layers. The structure was determined by single crystal X-ray diffraction analysis. Magnetic properties, due to the presence of paramagnetic iron (II) centers, are presented and discussed.

Download Full-text

STUDIES ON THE CONFORMATIONS OF 4-N,N-DIMETHYLAMINOTHIANES AND THE CORRESPONDING METHIODIDES. EVIDENCE FROM A SINGLE CRYSTAL X-RAY DIFFRACTION ANALYSIS THAT A TWIST-BOAT CONFORMER EXISTS IN THE SOLID STATE FOR TRIMETHYL-[2,2-DIMETHYL-trans−6-PHENYLTHIAN-r-4-YL]-AMMONIUM IODIDE

Phosphorous and Sulfur and the Related Elements ◽

10.1080/03086648308077555 ◽

1983 ◽

Vol 17 (3) ◽

pp. 343-365 ◽

Cited By ~ 2

Author(s):

Pullachipatti K. Subramanian ◽

Kondareddiar Ramalingam ◽

Nantelle S. Pantaleo ◽

Dick Van Der Helm ◽

Nagichettiar Satyamurthy ◽

...

Keyword(s):

Solid State ◽

Single Crystal ◽

Diffraction Analysis ◽

Ammonium Iodide ◽

X Ray Diffraction ◽

X Ray ◽

Twist Boat

Download Full-text

Synthesis of 4-(3-coumarinyl)-3-benzyl-4-thiazolin-2-one 4-methylbenzylidenehydrazone and determination of the isomeric structure by X-ray analysis

Zeitschrift für Kristallographie - Crystalline Materials ◽

10.1524/zkri.218.12.819.20549 ◽

2003 ◽

Vol 218 (12) ◽

Author(s):

Süheyla Özbey ◽

Nilgün Karalı ◽

Aysel Gürsoy

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

Spectral Data ◽

X Ray Diffraction ◽

X Ray ◽

Isomeric Structure ◽

Elemental Analyses

AbstractIn this study 4-(3-coumarinyl)-3-benzyl-4-thi azolin-2-one 4-methylbenzylidenehydrazone 3 was synthesised. An independent proof of the thiazolylhydrazone structure of 3 was achieved by single crystal X-ray diffraction analysis. Elemental analyses and spectral data (IR,

Download Full-text

Single-crystal X-ray diffraction analysis of nonplanar autoepitaxial silicon layers

Inorganic Materials ◽

10.1134/s0020168509140179 ◽

2009 ◽

Vol 45 (14) ◽

pp. 1610-1613

Author(s):

V. T. Bublik ◽

L. V. Kozhitov ◽

T. T. Kondratenko

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

X Ray Diffraction ◽

X Ray

Download Full-text

Functionalized triphenylphosphine oxide-based manganese(II) complexes for luminescent printing

Dalton Transactions ◽

10.1039/d1dt00914a ◽

2021 ◽

Author(s):

Xiaomeng Huang ◽

Yanyan Qin ◽

Pengfei She ◽

Haixing Meng ◽

Shu-Juan Liu ◽

...

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

Triphenylphosphine Oxide ◽

X Ray Diffraction ◽

X Ray

Three novel neutral manganese(II) complexes (TPhPONMe2)2MnBr2, (TPhPOOMe)2MnBr2, and (TPhPOCF3)2MnBr2 have been designed and synthesized based on functionalized Ph3PO ligand. These structures are clarified by single crystal X-ray diffraction analysis, which...

Download Full-text

A Single Crystal X-Ray Diffraction Analysis of (1R,1′S)-1,1′-Ethylenebis(1,2,3,4-tetrahydro-4,4-dimethyl-1-phenylphosphinolinium) Diperchlorate

ACS Symposium Series - Phosphorus Chemistry ◽

10.1021/bk-1981-0171.ch116 ◽

1981 ◽

pp. 561-565

Author(s):

NARAYANASAMY GURUSAMY ◽

K. DARRELL BERLIN ◽

DICK VAN DER HELM ◽

M. BILAYET HOSSAIN

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

X Ray Diffraction ◽

X Ray

Download Full-text

Synthesis, Structure and Magnetism of ErCoIn5

MRS Proceedings ◽

10.1557/proc-848-ff3.7 ◽

2004 ◽

Vol 848 ◽

Author(s):

Evan Lyle Thomas ◽

Erin E. Erickson ◽

Monica Moldovan ◽

David P. Young ◽

Julia Y. Chan

Keyword(s):

Magnetic Properties ◽

Electrical Resistivity ◽

Magnetic Susceptibility ◽

Single Crystal ◽

Experimental Results ◽

Flux Growth ◽

X Ray Diffraction ◽

Metallic Behavior ◽

X Ray ◽

Growth Method

AbstractA new member of the LnMIn5 family, ErCoIn5, has been synthesized by a flux-growth method. The structure of ErCoIn5 was determined by single crystal X-ray diffraction. It crystallizes in the tetragonal space group P4/mmm, Z = 1, with lattice parameters a = 4.5400(4) and c = 7.3970(7) Å, and V = 152.46(2) Å3. Electrical resistivity data show metallic behavior. Magnetic susceptibility measurements show this compound to be antiferromagnetic with TN = 5.1 K. We compare these experimental results with those of LaCoIn5 in an effort to better understand the effect of the structural trends observed on the transport and magnetic properties.

Download Full-text

Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis

Beilstein Journal of Organic Chemistry ◽

10.3762/bjoc.12.177 ◽

2016 ◽

Vol 12 ◽

pp. 1877-1883 ◽

Cited By ~ 5

Author(s):

Sambasivarao Kotha ◽

Rama Gunta

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

X Ray Diffraction ◽

Ring Closing Metathesis ◽

X Ray ◽

Synthetic Strategy ◽

Norbornene Derivatives

Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules.

Download Full-text