From Academia to the Market – Air-stable Ni(ii)/Josiphos Catalysts
2021 ◽
Vol 75
(11)
◽
pp. 943-947
Keyword(s):
The design, synthesis, commercialization and application of air-stable Ni(II)/Josiphos complexes has been realized in a collaboration between Solvias and ICBMS (University Lyon 1). The Ni-complexes are utilized as versatile precatalysts for diverse cross-coupling reactions. Apart from being active in established C–C and C–N couplings at low catalyst loadings, the novel Ni-precatalysts enabled the development of the challenging monoarylation of ammonia, ammonia surrogates and even alkylammonium chlorides with aryl carbamates. Finally, the α-arylation of acetone with aryl chlorides, carbamates and pivalates was demonstrated using the Ni(II)/Josiphos precatalysts.
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2014 ◽
Vol 136
(40)
◽
pp. 14027-14030
◽
2001 ◽
Vol 66
(25)
◽
pp. 8677-8681
◽
Keyword(s):
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