Synthesis and X-ray Characterization of Organotelluroxane
2018 ◽
Vol 2
(01)
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Keyword(s):
X Ray
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The reactions of diethyl tellurium (IV) diiodide [(C2H5)2TeI2 ] with conc. HNO3 afford diorganotelluroxane. The X-ray crystal structures of organotelluroxane reveal the immediate co-ordination geometry about the central tellurium atom to be pseudotrigonal bipyramidal ( TBP) with one stereochemically active electron lone pair. The supramolecular associations of the diorganotelluroxanes (IV) generated through Te---O secondary bonds.
1998 ◽
Vol 282
(2)
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pp. 155-162
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