Roles of Polymer Layer in Interfacial Engineering Perovskite Solar Cells with High Photovoltaic Performance

Author(s):  
Fengjiu Yang ◽  
HongEn Lim ◽  
Mashahi Ozaki ◽  
Ai Shimazaki ◽  
Yuhei Miyauchi ◽  
...  
2021 ◽  
Vol 42 (11) ◽  
pp. 112201
Author(s):  
Xiao Zhang ◽  
Sai Ma ◽  
Jingbi You ◽  
Yang Bai ◽  
Qi Chen

Abstract Interfacial engineering has made an outstanding contribution to the development of high-efficiency perovskite solar cells (PSCs). Here, we introduce an effective interface passivation strategy via methoxysilane molecules with different terminal groups. The power conversion efficiency (PCE) has increased from 20.97% to 21.97% after introducing a 3-isocyanatopropyltrimethoxy silane (IPTMS) molecule with carbonyl group, while a trimethoxy[3-(phenylamino)propyl] silane (PAPMS) molecule containing aniline group deteriorates the photovoltaic performance as a consequence of decreased open circuit voltage. The improved performance after IPTMS treatment is ascribed to the suppression of non-radiative recombination and enhancement of carrier transportation. In addition, the devices with carbonyl group modification exhibit outstanding thermal stability, which maintain 90% of its initial PCE after 1500 h exposure. This work provides a guideline for the design of passivation molecules aiming to deliver the efficiency and thermal stability simultaneously.


2017 ◽  
Vol 121 (3) ◽  
pp. 1562-1568 ◽  
Author(s):  
Feijiu Wang ◽  
Ai Shimazaki ◽  
Fengjiu Yang ◽  
Kaito Kanahashi ◽  
Keiichiro Matsuki ◽  
...  

2017 ◽  
Vol 5 (3) ◽  
pp. 1701256 ◽  
Author(s):  
Fengjiu Yang ◽  
Hong En Lim ◽  
Feijiu Wang ◽  
Masashi Ozaki ◽  
Ai Shimazaki ◽  
...  

2020 ◽  
Vol 479 ◽  
pp. 228811 ◽  
Author(s):  
M. Thambidurai ◽  
Benny Febriansyah ◽  
Shini Foo ◽  
P.C. Harikesh ◽  
Koh Teck Ming ◽  
...  

2015 ◽  
Vol 3 (48) ◽  
pp. 24254-24260 ◽  
Author(s):  
Zhuowei Gu ◽  
Lijian Zuo ◽  
Thue T. Larsen-Olsen ◽  
Tao Ye ◽  
Gang Wu ◽  
...  

A self-assembled monolayer is employed to modify the HTL in inverted perovskite solar cells, which results in significant photovoltaic performance enhancement, and can be applied on roll-to-roll fabricated flexible perovskite solar cells.


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