Unleashing non-conjugated polymers as charge relay mediators

Electron relay of interim polymer layer boosts photocatalytic organic transformation.

Study on Parameter Optimization and Mechanism of Rigid-Flexible Coupling Underground Engineering Structure of Steel Panel and Polymer

Polymer grouting is carried out between the steel panel and surrounding soil in underground engineering, and the polymer material consists of isocyanates and polyols. The isocyanate/polyol composite slurry expands rapidly due to chemical reaction and solidifies immediately. Then, a dense impermeable polymer layer is formed after rapid expansion of isocyanate and polyol, which is widely used for ground reinforcement and foundation remediation. Thus, a steel panel-polymer composite structure is developed. Mechanical properties of the steel panel-polymer structure are studied. The results show that the steel panel-polymer structure exhibited excellent mechanical properties. The steel panel and polymer layer should be designed above 3 mm and 10 mm in thickness, respectively. The steel panel showed superior mechanical properties to those of polymer layers. Considering good rigidity of the steel panel and good flexibility of the polymer layer, the steel panel and polymer layer presented perfect interfacial contact. It is concluded that the mechanical properties of the whole structure were increasingly enhanced with the increase of the steel panel thickness and the structural flexibility increased with the thickness of the polymer layer. Besides, the combination of the steel panel and polymer layer could also improve the mechanical properties of this coupling structure. This study provided an initial attempt for investigating the feasibility of applying polyurethane foam to steel panels in underground engineering. The stress analysis along the grouting direction inside the prefabricated wall was conducted. It may lay the foundation for further application of polymer grouting in underground engineering.

Heterogeneity in Lateral Distribution of Polycations at the Surface of Lipid Membrane: From the Experimental Data to the Theoretical Model

Natural and synthetic polycations of different kinds attract substantial attention due to an increasing number of their applications in the biomedical industry and in pharmacology. The key characteristic determining the effectiveness of the majority of these applications is the number of macromolecules adsorbed on the surface of biological cells or their lipid models. Their study is complicated by a possible heterogeneity of polymer layer adsorbed on the membrane. Experimental methods reflecting the structure of the layer include the electrokinetic measurements in liposome suspension and the boundary potential of planar bilayer lipid membranes (BLM) and lipid monolayers with a mixed composition of lipids and the ionic media. In the review, we systematically analyze the methods of experimental registration and theoretical description of the laterally heterogeneous structures in the polymer layer published in the literature and in our previous studies. In particular, we consider a model based on classical theory of the electrical double layer, used to analyze the available data of the electrokinetic measurements in liposome suspension with polylysines of varying molecular mass. This model suggests a few parameters related to the heterogeneity of the polymer layer and allows determining the conditions for its appearance at the membrane surface. A further development of this theoretical approach is discussed.

Multimode Robust Lasing in a Dye-Doped Polymer Layer Embedded in a Wedge-Shaped Cholesteric

Cholesteric liquid crystals (CLCs) with induced defects are one of the most prominent materials to realize compact, low-threshold and tunable coherent light sources. In this context, the investigation of optical properties of induced defect modes in such CLCs is of great interest. In particular, many studies have been devoted to the spectral control of the defect modes depending on their thickness, optical properties, distribution along the CLC, etc. In this paper, we investigate the lasing possibilities of a dye-doped polymer layer embedded in a wedge-shaped CLC. We show that multimode laser generation is possible due to the observed multiple defect modes in the PBG that enlarges the application range of the system. Furthermore, our simulations based on a Berreman 4 × 4 matrix approach for a wide range of CLC thickness show both periodic and continuous generation of defect modes along particular spectral lines inside the PBG. Such a robust spectral behaviour of induced defect modes is unique, and, to our knowledge, is not observed in similar CLC-based structures.

Development of Resistance Spot Welding Processes of Metal–Plastic Composites

Metal–plastic composites (MPCs) are gaining importance mainly due to high strength to weight ratio. They consist of three layers, two outer metallic cover sheets, and a plastic core. The presence of that inner plastic layer makes them rather unsuitable for joining by means of any conventional welding processes, which significantly reduces the application range of MPC. In this work, three various resistance spot welding (RSW)-based concepts were developed to overcome that limitation and join Litecor to DP600 steel. In all cases, a dedicated initial stage was implemented to RSW, which was aimed at removing the non-conductive polymer layer from the welding zone and creating the proper electrical contact for the resistance welding. These were, namely: (i) shunt current-assisted RSW; (ii) induction heating-assisted RSW; and (iii) ultrasonic-assisted RSW. The development of each concept was supported by finite element modeling, which was focused on setting the proper process parameters for polymer layer removal. Finally, the macro- and microstructure of exemplary RSW joints are shown and the most common spot weld features as well as the further development possibilities are discussed.