3-(2-Pyridyl)-5,6-di(2-furyl)-1,2,4-triazine-5',5''-disulfonic Acid, Disodium Salt

2021 ◽  
Keyword(s):  
Disodium Salt ◽  
Disulfonic Acid

scholarly journals 9,10-ANTHRAQUINONE-2,6-DISULFONIC ACID DISODIUM SALT/ EPOXY GRAPHITE COMPOSITE FOR ANODE IN MICROBIAL FUEL CELL

2017 ◽  
Vol 79 (5-3) ◽  
Author(s):  
Mimi Hani Abu Bakar ◽  
Neil F Pasco ◽  
Ravi Gooneratne ◽  
Kim Byung Hong
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Conductive Filler ◽  
Internal Resistance ◽  
Disodium Salt ◽  
Disulfonic Acid ◽  
Graphite Composite ◽  
Design Flexibility ◽  
Matrix Surface ◽  
The Matrix

Properties such as electrical conductivity, low resistivity, chemicals and corrosion resistance are mostly found in carbon based materials. Epoxy resin is excellent for electrical insulation and can be used as a conductor with the addition of conductive filler. Combinations of carbon and epoxy show qualities of a conductive electrode, mechanically strong with design flexibility and thus makes them suitable as electrodes in microbial fuel cell (MFC). In this study, graphite-epoxy composites were fabricated with multi-walled carbon nanotube (MWCNT) embedded in the matrix surface. 9,10-Anthraquinone-2,6-disulfonic acid disodium salt/polypyrrole (PPy/AQDS) was used as mediator, covalently electrografted on electrode’s surface. Electrochemical stability of anodes during continuous operation were measured in air-cathode MFCs. It appears that maximum power in MFC could be increased up to 42% with surface modification using PPy/AQDS. Internal resistance (Rint) could be reduced up to 66% with the inclusion of MWCNT. These findings show that a one-day fabrication of a-ready-to-use conductive electrode is possible for graphite content between 70-80% (w/w).

scholarly journals Photometric determination of aqueous cobalt (II), nickel (II), copper (II) and iron (III) with 1-nitroso-2-naphthol-3,6-disulfonic acid disodium salt in gelatin films

2012 ◽  
Vol 10 (5) ◽  
pp. 1617-1623 ◽  
Author(s):  
Elena Reshetnyak ◽  
Nataliia Ivchenko ◽  
Nataliya Nikitina
Keyword(s):  
Metal Complexes ◽  
Simultaneous Determination ◽  
Isoelectric Point ◽  
Electrostatic Interaction ◽  
Photometric Determination ◽  
Disodium Salt ◽  
Photographic Film ◽  
Disulfonic Acid ◽  
Gelatin Films

AbstractPhotometric determination of aqueous Co(II), Cu(II), Ni(II) and Fe(III) was performed using indicator films prepared by immobilization of 1-nitroso-2-naphthol-3,6-disulfonic acid disodium salt (NRS) into hardened photographic film. Immobilization was based on electrostatic interaction of reagent and metal complexes with the gelatin. The isoelectric point pH of hardened gelatin (4.46±0.04) was evaluated by viscometry. Co(II), Fe(III), Ni(II) form 1:3 complexes with NRS in gelatin at pH 2 and Cu(II) forms 1:2 complexes. Their log β′ values were: Co-6.7, Fe-8.6, Cu-8.0, and Ni-6.4. The absorption maxima were: 370nm for NRS, and 430nm, 470nm, 495nm and 720nm for complexes of Co(II), Ni(II), Cu(II) and Fe(III). An algorithm for their simultaneous determination using the indicator films was developed. The detection limits were: clim(Co2+) = 0.45×10−5 M, clim(Fe3+) = 0.50×10−5 M, clim(Cu2+) = 0.67×10−5 M, clim(Ni2+) = 0.75×10−5 M,; and their sum clim(ΣMn+) = 0.82×10−5 M.

scholarly journals A Simple and Sensitive Inhibitory Kinetic Method for the Carbocisteine Determination

2021 ◽  
Vol 66 (1) ◽  
Author(s):  
Abhishek Srivastava ◽  
Vivek Sharma ◽  
Vinay Kumar Singh ◽  
Krishna Srivastava
Keyword(s):  
Good Accuracy ◽  
Quantitative Estimation ◽  
Kinetic Method ◽  
Fixed Time ◽  
Disodium Salt ◽  
Disulfonic Acid ◽  
Stable Complex ◽  
Reaction Conditions ◽  
Kinetic Determination

Abstract. A fast, reproducible, and sensitive method is proposed for the kinetic determination of carbocisteine (CCys). The method depends on the inhibitory property of carbocisteine, which reduces the Hg2+ catalyzed substitution rate of cyanide from [Ru(CN)6]4- with N-R-salt (1-Nitroso-2-naphthol-3,6-disulfonic acid disodium salt) via forming a stable complex with Hg2+. Spectrophotometric measurements were carried out by recording the absorbance at 525 nm (λmax of [Ru(CN)5 Nitroso-R-Salt]3- complex) at a fixed time of 10 and 15 min under the optimized reaction conditions with [N-R-salt] = 4.5 × 10-4 M, I = 0.05 M (KNO3), Temp = 45.0 ± 0.2 o C, pH = 7.0 ± 0.03, [Hg2+] = 8.0 × 10-5 M and [Ru(CN)64-] = 4.25 × 10-5  M. With the proposed method, CCys can be determined quantitatively down to 3.0 × 10-6 M. This methodology can be effectively used for the rapid quantitative estimation of CCys in the pharmaceutical samples with good accuracy and reproducibility. The addition of common excipients in pharmaceuticals even up to 1000 times with [CCys] does not interfere significantly in the estimation of CCys.   Resumen. Se propone un método rápido, reproducibley sensible para la determinación cinética de la carbocisteina (CCys). El método depende de la propiedad inhibitoria de la carbocisteina que reduce la tasa de sustitución catalizada por Hg2+ del cianuro de [Ru(CN)6]4- con la sal N-R (sal disódica del ácido 1-Nitroso-2-naftol-3,6-disulfónico) mediante la formación de un complejo estable con Hg2+. Las mediciones espectrofotométricas se llevaron a cabo registrando la absorbancia a 525 nm (λmax del complejo [Ru(CN)5 Sal-Nitroso-R]3-) en un tiempo fijo de 10 y 15 min en las condiciones de reacción optimizadas con [sal-NR] = 4.5 × 10-4 M, I = 0.05 M (KNO3), Temp = 45.0 ± 0.2 o C, pH = 7.0 ± 0.03, [Hg2+] = 8.0 × 10-5 M y [Ru(CN)64-] = 4.25 × 10-5 M. Con el método propuesto, CCys se puede determinar cuantitativamente hasta 3,0 × 10-6 M. Esta metodología se puede utilizar eficazmente para la estimación cuantitativa rápida de CCys en las muestras farmacéuticas con buena precisión y reproducibilidad. La adición de excipientes comunes en productos farmacéuticos incluso hasta 1000 veces con [CCys] no interfiere significativamente en la estimación de CCys.

Effects of cations on pH gradient-stimulated sulfate transport in rabbit ileal brush-border membrane vesicles

1985 ◽  
Vol 249 (5) ◽  
pp. G614-G621 ◽  
Author(s):  
C. M. Schron ◽  
R. G. Knickelbein ◽  
P. S. Aronson ◽  
J. Della Puca ◽  
J. W. Dobbins
Keyword(s):  
Brush Border ◽  
Brush Border Membrane ◽  
Electrical Potential ◽  
Membrane Vesicles ◽  
Disodium Salt ◽  
Brush Border Membrane Vesicles ◽  
Ph Gradient ◽  
Disulfonic Acid ◽  
Rabbit Ileum ◽  
External K

In brush-border membrane vesicles from rabbit ileum, we previously reported pH gradient-stimulated SO4 uptake and presented evidence that this represents carrier-mediated SO4-OH exchange. In the present study inhibitors of SO4-OH exchange (H-SO4 cotransport) were shown not to inhibit Na-SO4 cotransport, suggesting that these are two separate carrier-mediated transport mechanisms. While pH gradient-stimulated SO4 uptake was inhibited 87% by 0.1 mM 4,4'-diisothiocyanostilbene-2,2'-disulfonic acid, disodium salt (DIDS) and 79% by 1.0 mM furosemide, Na+-stimulated SO4 uptake was only inhibited 11 and 0%, respectively. K+ (20 mM), Cl (5 mM), and oxalate (0.25 mM) inhibited pH gradient-stimulated SO4 uptake (38-65%) but had no effect on Na+-stimulated SO4 uptake. Finally, at Na+ concentrations (10 mM) significantly less than that required for Na+-stimulated SO4 uptake (60-100 mM), external Na+ inhibited pH gradient-stimulated SO4 uptake, suggesting two independent effects of this cation. SO4 uptake was also inhibited by external K+ both in the presence and absence of a pH gradient. A Dixon plot of the DIDS-sensitive SO4 uptake under pH gradient conditions yielded a straight line, indicating a single site of interaction between external K+ and the SO4-OH carrier (apparent Ki = 7.2 mM). In contrast to the inhibition by external K+, internal K+ stimulated SO4 uptake. This effect was DIDS sensitive and not enhanced by valinomycin, suggesting an interaction of internal K+ with the SO4-OH exchanger independent of a K+-induced electrical potential. SO4 uptake and the effects of K+ were pH modulated with less SO4 uptake and less K+ effect at higher pH.(ABSTRACT TRUNCATED AT 250 WORDS)

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