scholarly journals Enantioselective synthesis of compounds containing bis-benzylic quaternary stereocenters through palladium-catalyzed conjugate additions of arylboronic acids

2017 ◽  
Author(s):  
Abhishek Ashok Kadam
2016 ◽  
Vol 52 (72) ◽  
pp. 10882-10885 ◽  
Author(s):  
Zhong Yan ◽  
Bo Wu ◽  
Xiang Gao ◽  
Yong-Gui Zhou

A highly enantioselective synthesis of quaternary aminophosphonates was developed by palladium-catalyzed arylation of cyclic ketiminophosphonates with arylboronic acids.


2014 ◽  
Vol 5 (12) ◽  
pp. 4840-4844 ◽  
Author(s):  
B. A. Hopkins ◽  
J. P. Wolfe

Asymmetric palladium-catalyzed carboamination reactions of aminoalkene substrates provide substituted six-membered heterocycles bearing quaternary stereocenters in good yield and high enantioselectivity.


2014 ◽  
Vol 12 (31) ◽  
pp. 5883-5890 ◽  
Author(s):  
Jeffrey Buter ◽  
Renée Moezelaar ◽  
Adriaan J. Minnaard

Palladium catalyzed asymmetric conjugate addition of ortho-substituted arylboronic acids to cyclic enones and its application in natural product synthesis.


2020 ◽  
Vol 11 (18) ◽  
pp. 4602-4607 ◽  
Author(s):  
Doohyun Baek ◽  
Huijeong Ryu ◽  
Ji Yeon Ryu ◽  
Junseong Lee ◽  
Brian M. Stoltz ◽  
...  

The first palladium-catalyzed enantioselective conjugate addition reactions of arylboronic acids to 2-substituted chromones with chiral pyridine-dihydroisoquinoline ligands have been developed.


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