scholarly journals Effects of Carrier Materials on Anaerobic Hydrogen Production by Continuous Mixed Immobilized Sludge Reactors

2020 ◽  
Vol 65 (1) ◽  
pp. 124-132
Author(s):  
Qiaoyan Li ◽  
Yikun Cao ◽  
Yongfeng Li

To enhance hydrogen production rate and increase substrate utilization efficiency of anaerobic fermentation, three carrier materials, Granular Activated Carbon (GAC), Zeolite Molecular Sieve (ZMS) and Biological Ceramic Ring (BCR), were used as carrier materials in Continuous Mixed Immobilized Sludge Reactors (CMISRs). The effects of carrier materials and substrate organic loading rate (OLR, OLR = 12, 24, 36, 48 kg/m3/d) on biohydrogen production were investigate, respectively. The highest HPRs of ZMS, GAC and BCR were achieved under the OLR of 36 kg COD/m3/d, and were 2.01, 1.81, and 2.86 L/L/d, respectively. The highest COD removal efficiencies of ZMS, GAC and BCR were 38.95 % (OLR = 24 kg COD/m3/d), 36.47 % (OLR = 36 kg COD/m3/d), and 41.03 % (OLR = 36 kg COD/m3/d), respectively. The best substrate degradation rate of ZMS, GAC and BCR were 40.33 % (OLR = 24 kg COD/m3/d), 38.30 % (OLR = 24 kg COD/m3/d) and 45.60 % (OLR = 12 kg COD/m3/d). The results indicated that biological ceramic ring get better hydrogen production and wastewater treatment performance as sludge carrier material for hydrogen production in immobilized bioprocesses.


2010 ◽  
Vol 113-116 ◽  
pp. 1132-1137 ◽  
Author(s):  
Yong Feng Li ◽  
Yong Ming Hui ◽  
Xin Yao ◽  
Lu Wang ◽  
Qian Wen Song ◽  
...  

In this experiment, brown sugar was chosen as the substrate of continuous operation. A lab-scale expanded granular sludge blanket (EGSB) reactor was employed. Stable ethanol-type fermentation was formed by controlling the organic loading rate (OLR). The results showed a maximum hydrogen production rate of 5.73L / L reactor•d was achieved, under the condition that the hydraulic retention time (HRT) = 2h, OLR = 97.2kg COD/m3 reactor•d. The average hydrogen content in the biogas during the 73-day operation was 41.27%.





2012 ◽  
Vol 37 (22) ◽  
pp. 16925-16934 ◽  
Author(s):  
Géssia Momoe Shida ◽  
Leandro Takano Sader ◽  
Eduardo Lucena Cavalcante de Amorim ◽  
Isabel Kimiko Sakamoto ◽  
Sandra Imaculada Maintinguer ◽  
...  


2010 ◽  
Vol 152-153 ◽  
pp. 377-382
Author(s):  
Kun Liu ◽  
An Ying Jiao ◽  
Li Ran Yue ◽  
Yong Feng Li

By the researches and analyses of the fermentation type in the bio-hydrogen production system, ethanol-type fermentation bacteria had the largest H2-production capability, butyric acid type fermentation bacteria took the second place, and propionic acid-type fermentation bacteria had the least H2-poduction capability. When the organic loading rate (OLR) is 24kgCOD/m3•d, HRT is 8h and temperature is 35 °C, the highest hydrogen production capability corresponding were 4.2, 1.3 and 0.018 mol•kg MLVSS−1•d−1, so ethanol-type fermentation was optimal type for hydrogen production.



2010 ◽  
Vol 113-116 ◽  
pp. 1170-1175
Author(s):  
Zi Rui Guo ◽  
An Ying Jiao ◽  
Xiao Ye Liu ◽  
Yong Feng Li

Hydrogen is a kind of ideal clean energy sources. With low energy consumption, environmental protection and other advantages, biological hydrogen production technology become the hotspot of current study home and abroad. The distribution energy technology for producing hydrogen can get hydrogen when deal with waste water. For finding out the industralized feasibility of continuous H2 bio-production,the ability of H2-production via facultative anaerobe,optimum hydraulic retention time(HRT) and optimum organic loading rate(OLR) were aslo studied. With a temperature of (35±1)°C,HRT of 8 h,the CSTR inoculated with activated sludge ,and the progression is increasing organic loading rate gradually. Six OLRs were examined, ranging from 2 to 12 g COD/L.d, with the mass of molasses ranging from 1.3 to 10 g COD/L. While COD was up to 4g/L(OLR 12kg/(m3•d)), all molasses was utilized and the H2 yield was not significantly influenced by OLR. At the intermediate COD of 6g/l (OLR 18kg/(m3•d)), the H2 yield was maximized at about 30 L/d H2 (mol molasses. Conv.), which was 17.9% and 55.9% higher than those of OLR 6 kg/(m3.d) and OLR 12 kg/(m3.d),respectively. When the influent COD concentration raised to 12g/L(OLR 30kg/(m3•d)), the reactor were overloaded, the hydrogen yield decreased drastically,hydrogen evolution rate decreased to zero. Exceeding OLR would arouse great change of internal environment parameters, such as pH, ALK(aikalinity), ORP(oxidation-reduction potential) in CSTR, and the microbial community structure would change while the metabolism of microorganism was inhibited badly.



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