scholarly journals Effect of Several Oxoacid Salts on Crevice Corrosion of Type 304 Stainless Steel in Chloride Solutions at 423K

1996 ◽  
Vol 45 (3) ◽  
pp. 131-137 ◽  
Author(s):  
Hitoshi Yashiro ◽  
Akihiro Miura ◽  
Yuji Ishii ◽  
Kazuo Tanno
CORROSION ◽  
10.5006/3324 ◽  
2020 ◽  
Vol 76 (4) ◽  
pp. 424-435
Author(s):  
Abinaya Kamaraj ◽  
Johann Wilhelm Erning

The susceptibility of Type 304 stainless steel (SS) to crevice corrosion upon contacting with electrochemically active fluids was investigated using exposure tests and stepwise potentiostatic polarization. Crevice materials made of 304 SS and polyether ether ketone (PEEK) were focused on in this study. The combined influence of oxidant and chloride concentration on crevice corrosion was examined in detail in the two types of crevice combinations (304 SS-to-PEEK and 304 SS-to-304 SS). The 304 SS specimens were strongly susceptible to crevice corrosion when coupled with 304 SS. Even at a low concentration of 5 mg/L free chlorine and 150 mg/L chloride, which is below nominal dilutions in beverage industries, the examined specimens underwent crevice corrosion in both crevices. The effect of water composition on crevice corrosion was also studied, indicating high susceptibility of 304 SS to crevice corrosion in low pH (pH ≤ 5) solutions. The corroded surface morphology was analyzed using scanning electron microscope, energy dispersive x-ray, and confocal microscope.


CORROSION ◽  
1996 ◽  
Vol 52 (2) ◽  
pp. 109-114 ◽  
Author(s):  
H. Yashiro ◽  
K. Tanno ◽  
S. Koshiyama ◽  
K. Akashi

1992 ◽  
Vol 294 ◽  
Author(s):  
Guen Nakayama ◽  
Hisao Wakamatsu ◽  
Masatsune Akashi

ABSTRACTIn addition to mild steel, several stainless alloys are being proposed as materials for packages for geological disposal of high-level nuclear waste. When buried deep underground, the greatest detriment to the integrity of packages made of these alloys is localized corrosion, for which critical conditions for initiation of crevice corrosion in chloride environments, with or without other ions, need be precisely known.Crevice corrosion behavior of Type 304 stainless steel, Type 316 stainless steel, Alloy 825, Ti-Gr.1, and Ti-Gr.12 in solutions containing ions of chloride, bromide (these two for their ordinary presence in natural waters), or thiosulphate (this for the likelihood of microbially influenced corrosion) to varying concentrations have been empirically examined. All of these alloys exhibit much the same concentration dependency of crevice corrosion sensitivity for chloride and bromide ions, while Type 304 stainless steel is particularly sensitive to the thiosulphate ion. The region of insensitivity for chloride ion is wider in the increasing order of Type 304 stainless steel, Type 316 stainless steel, Ti-Gr. 1, and Ti-Gr. 12, with that of Alloy 825 lying somewhere in between.


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