Study of Triple System Calcium Iodide-HMTA-Water

Research relevance: synthesis, physicochemical studies of complexes bioactivity with salts of biometals and organic ligands are of great interest for bio-coordination chemistry. Materials and research methods: isothermal method was used to study heterogeneous equilibria at 25 °C. The concentration limits of compounds existence and the types of their solubility have been established. Research objectives: to investigate compounds of hexamethylenetetramine with salts of biometals with organic ligands in order to reduce toxicity, increase the bioactivity and bioavailability of coordination compounds. Research results: concentration limits of compounds existence and types of their solubility have been established. Conclusions: in obtained complexes, HMTA ligand contains four equivalent electron donor nitrogen atoms.

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Molecular kinetic aspects of the vapo¬rization processes of volatile coordination compounds with organic ligands

Журнал структурной химии ◽

10.26902/jsc20170802 ◽

2017 ◽

Vol 58 (8) ◽

pp. 1534-1542

Author(s):

V.V. Lukashov ◽

◽

M.S. Makarov ◽

S.N. Makarova ◽

I.K. Igumenov ◽

...

Keyword(s):

Coordination Compounds ◽

Organic Ligands

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Lanthanide coordination compounds with organic ligands as prospective electroluminescent materials

Conference Digest. 2000 Conference on Lasers and Electro-Optics Europe (Cat. No.00TH8505) ◽

10.1109/cleoe.2000.910018 ◽

2002 ◽

Author(s):

R.A. Ivanov ◽

A.A. Egorov ◽

N.P. Kuzmina

Keyword(s):

Coordination Compounds ◽

Organic Ligands

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Enhanced NLO properties of molybdenum push–pull coordination compounds with tridentate ONO organic ligands

Inorganica Chimica Acta ◽

10.1016/j.ica.2015.11.008 ◽

2016 ◽

Vol 442 ◽

pp. 10-15 ◽

Cited By ~ 10

Author(s):

Tomás Guerrero ◽

Pascal G. Lacroix ◽

Héctor García-Ortega ◽

Omar G. Morales-Saavedra ◽

Dominique Agustin ◽

...

Keyword(s):

Coordination Compounds ◽

Organic Ligands ◽

Nlo Properties

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Comprehensive Coordination Chemistry. The Synthesis, Reactions, Properties and Applications of Coordination Compounds (7 Bände). Herausgegeben vonG. Wilkinson, R. Gillard andJ. A. McCleverty. Pergamon Press, Oxford 1987. Insgesamt ca. 7000 S., geb. $ 2450.00. – ISBN 0-08-026232-5. Volume 5: Late Transition Elements

Angewandte Chemie ◽

10.1002/ange.19891010644 ◽

1989 ◽

Vol 101 (6) ◽

pp. 809-810

Author(s):

Carl Krüger

Keyword(s):

Coordination Chemistry ◽

Coordination Compounds ◽

Transition Elements ◽

Comprehensive Coordination Chemistry ◽

Late Transition ◽

Synthesis Reactions

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Coordination compounds of substituted 1,10-Phenanthrolines and related dipyridyls. VII. Complexes of copper(I) and 4,6,4',6'-Tetramethyl-2,2'-bipyridine

Australian Journal of Chemistry ◽

10.1071/ch9651339 ◽

1965 ◽

Vol 18 (9) ◽

pp. 1339 ◽

Cited By ~ 5

Author(s):

JR Hall ◽

MR Litzow ◽

RA Plowman

Keyword(s):

Solid State ◽

Physical Properties ◽

Copper Atom ◽

Coordination Compounds ◽

Donor Nitrogen ◽

Partial Dissociation

A number of diamagnetic complexes of copper(I) and 4,6,4',6'-tetramethyl-2,2'-bipyridine (tmb) have been prepared and some physical properties measured. The complexes of formula Cu(tmb)2X where X = NO3, ClO4, Br, and I behave as 1 : 1 electrolytes in nitrobenzene and nitromethane, while the complex Cu(tmb)2Cl,H2O apparently undergoes partial dissociation in these solvents. All are expected to have a tetrahedral arrangement of the four donor nitrogen atoms about the copper atom. The mono complexes CuXtmb, where X = Cl, Br, and I, appear to be dimeric in the solid state with halogen bridging, but in solution the chloro and bromo complexes rearrange to varying degrees depending on the solvent, forming the salt-type compounds [Cu(tmb)2][CuX2]. CuItmb is insoluble in all common solvents.

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When Stereochemistry Raised Its Ugly Head in Coordination Chemistry—An Appreciation of Howard Flack

Chemistry ◽

10.3390/chemistry2030049 ◽

2020 ◽

Vol 2 (3) ◽

pp. 759-776

Author(s):

Edwin C. Constable ◽

Catherine E. Housecroft

Keyword(s):

Organic Chemistry ◽

Coordination Chemistry ◽

Absolute Configuration ◽

Coordination Compounds ◽

Routine Method ◽

Absolute Determination ◽

Chiral Compounds ◽

The Absolute

Chiral compounds have played an important role in the development of coordination chemistry. Unlike organic chemistry, where mechanistic rules allowed the establishment of absolute configurations for numerous compounds once a single absolute determination had been made, coordination compounds are more complex. This article discusses the development of crystallographic methods and the interplay with coordination chemistry. Most importantly, the development of the Flack parameter is identified as providing a routine method for determining the absolute configuration of coordination compounds.

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