Enhancement of Hydrogen-Storage Characteristics of Magnesium Hydride via Reaction-Involved Milling with Nickel and Lithium Borohydride

2014 ◽  
Vol 52 (12) ◽  
pp. 1031-1036 ◽  
Author(s):  
Myoung Youp Song ◽  
Young Jun Kwak ◽  
Seong Ho Lee ◽  
Hye Ryoung Park
2012 ◽  
Vol 512-515 ◽  
pp. 1438-1441 ◽  
Author(s):  
Hong Min Kan ◽  
Ning Zhang ◽  
Xiao Yang Wang ◽  
Hong Sun

An overview of recent advances in hydrogen storage is presented in this review. The main focus is on metal hydrides, liquid-phase hydrogen storage material, alkaline earth metal NC/polymer composites and lithium borohydride ammoniate. Boron-nitrogen-based liquid-phase hydrogen storage material is a liquid under ambient conditions, air- and moisture-stable, recyclable and releases H2controllably and cleanly. It is not a solid material. It is easy storage and transport. The development of a liquid-phase hydrogen storage material has the potential to take advantage of the existing liquid-based distribution infrastructure. An air-stable composite material that consists of metallic Mg nanocrystals (NCs) in a gas-barrier polymer matrix that enables both the storage of a high density of hydrogen and rapid kinetics (loading in <30 min at 200°C). Moreover, nanostructuring of Mg provides rapid storage kinetics without using expensive heavy-metal catalysts. The Co-catalyzed lithium borohydride ammoniate, Li(NH3)4/3BH4 releases 17.8 wt% of hydrogen in the temperature range of 135 to 250 °C in a closed vessel. This is the maximum amount of dehydrogenation in all reports. These will reduce economy cost of the global transition from fossil fuels to hydrogen energy.


2013 ◽  
Vol 117 (25) ◽  
pp. 12973-12980 ◽  
Author(s):  
Chengshang Zhou ◽  
Zhigang Zak Fang ◽  
Chai Ren ◽  
Jingzhu Li ◽  
Jun Lu

JOM ◽  
2021 ◽  
Author(s):  
Jimoh Mohammed Abdul ◽  
Sharafadeen Kunle Kolawole ◽  
Ganiyat Abiodun Salawu

2016 ◽  
Vol 52 (4) ◽  
pp. 705-708 ◽  
Author(s):  
Yongfeng Liu ◽  
Hufei Du ◽  
Xin Zhang ◽  
Yaxiong Yang ◽  
Mingxia Gao ◽  
...  

A 2D Ti3C2 synthesized by the exfoliation of Ti3AlC2 powders exhibits superior catalytic properties for the hydrogen storage reaction of MgH2.


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