scholarly journals Simulation of a purification plant for pyrolysis gas based on plastic waste

2021 ◽  
Author(s):  
Ebrahim Qaredaghi ◽  
Sara Ronasi ◽  
Britt M. E. Moldestad
Keyword(s):  
Plastic Waste ◽  
Pyrolysis Gas ◽  
Purification Plant

scholarly journals Thermo-catalytic studies on a mixture of plastic waste and biomass

2021 ◽  
Author(s):  
Zoltán Sebestyén ◽  
Marianne Blazsó ◽  
Emma Jakab ◽  
Norbert Miskolczi ◽  
János Bozi ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Plastic Waste ◽  
Zeolite Catalysts ◽  
Beta Zeolite ◽  
Gas Chromatography Mass Spectrometry ◽  
Fast Heating ◽  
Alumina Support ◽  
Pyrolysis Gas ◽  
Decomposition Products ◽  
Waste Mixture

AbstractThe effects of various catalysts on the composition of volatile pyrolysis products of a plastic waste and biomass mixture (1:1) were studied, by pyrolyzing the mixture sample using slow and fast heating rate. Various zeolite catalysts (β-and Y-zeolites, ZSM-5 and FCC) and nickel-molybdenum catalyst on alumina support were applied to find suitable catalysts for upgrading the quality of the thermal decomposition products of the waste mixture. A sample to catalyst ratio of 2:1 was used in the experiments. The rate of evolution of the decomposition products under slow pyrolysis was measured by thermogravimetry/mass spectrometry (TG/MS). The composition of the pyrolyzates was analyzed in detail by pyrolysis–gas chromatography/mass spectrometry (Py-GC/MS) method. The influence of all applied catalysts was more pronounced on the plastic content of the sample than on biomass. The pyrolysis experiments revealed that the catalysts promoted the cracking reactions of the evolved hydrocarbons; furthermore, the formation of aromatic products was enhanced remarkably in the presence of all zeolite catalysts. Beta-zeolite and ZSM-5 catalysts were found the most effective in cracking hydrocarbons to gaseous products and in aromatization, while the highest CO2 formation was obtained by FCC from the biomass part of the studied waste mixture. NiMo catalyst promoted the H2 production from the plastic part; furthermore, slight aromatization and cracking effects were also observed.

Study of the Kinetics of Thermal Destruction of Crossed Polyethylene

2019 ◽  
Vol 5 (12) ◽  
pp. 37-46
Author(s):  
K. Chalov ◽  
Yu. Lugovoy ◽  
Yu. Kosivtsov ◽  
E. Sulman
Keyword(s):  
Total Yield ◽  
Calorific Value ◽  
High Heat ◽  
Process Temperature ◽  
Optimum Process ◽  
Quantitative Composition ◽  
Pyrolysis Gas ◽  
Gaseous Products ◽  
Liquid Products ◽  
Kinetics Of

This paper presents a study of the process of thermal degradation of crosslinked polyethylene. The kinetics of polymer decomposition was studied by thermogravimetry. Crosslinked polyethylene showed high heat resistance to temperatures of 400 °C. The temperature range of 430–500 °C was determined for the loss of the bulk of the sample. According to thermogravimetric data, the decomposition process proceeds in a single stage and includes a large number of fracture, cyclization, dehydrogenation, and other reactions. The process of pyrolysis of a crosslinked polymer in a stationary-bed metal reactor was investigated. The influence of the process temperature on the yield of solid, liquid, and gaseous pyrolysis products was investigated. The optimum process temperature was 500 °C. At this temperature, the yield of liquid and gaseous products was 85.0 and 12.5% (mass.), Respectively. Samples of crosslinked polyester decomposed almost completely. The amount of carbon–containing residue was 3.5% by weight of the feedstock. With increasing temperature, the yield of liquid products decreased slightly and the yield of gaseous products increased, but their total yield did not increase. For gaseous products, a qualitative and quantitative composition was determined. The main components of the pyrolysis gas were hydrocarbons C1–C4. The calorific value of pyrolysis gas obtained at a temperature of 500 °C was 17 MJ/m3. Thus, the pyrolysis process can be used to process crosslinked polyethylene wastes to produce liquid hydrocarbons and combustible gases.

Study on Wheat Gluten Biopolymer: a Novel Way to Eradicate Plastic Waste

2011 ◽  
Vol 3 (8) ◽  
pp. 253-255
Author(s):  
Neha Patni ◽  
◽  
Pujita Yadava ◽  
Anisha Agarwal ◽  
Vyoma Maroo
Keyword(s):  
Wheat Gluten ◽  
Plastic Waste

Niobium Oxide as Catalyst for the Pyrolysis of Polypropylene and Polyethylene Plastic Waste

2016 ◽  
Vol 10 (4) ◽  
pp. 465-472 ◽  
Author(s):  
Debora Almeida ◽  
◽  
Maria de Fatima Marques ◽  
Keyword(s):  
Thermogravimetric Analysis ◽  
Niobium Oxide ◽  
Plastic Waste

In the present work, the pyrolysis of polypropylene and polyethylene was evaluated with and without the addition of niobium oxide as catalyst by means of thermogravimetric analysis and experiments in a glass reactor. The results revealed that niobium oxide performed well in the pyrolysis of both polypropylene and polyethylene separately. For the mixture of polypropylene with polyethylene, the catalyst reduced the pyrolysis time.

Thermo-Oxidative Decomposition of Lovage (Levisticum officinale) and Davana (Artemisia pallens) Essential Oils under Simulated Tobacco Heating Product Conditions

2020 ◽  
Vol 29 (1) ◽  
pp. 27-43
Author(s):  
Emma Jakab ◽  
Zoltán Sebestyén ◽  
Bence Babinszki ◽  
Eszter Barta-Rajnai ◽  
Zsuzsanna Czégény ◽  
...  
Keyword(s):  
Low Temperature ◽  
Essential Oils ◽  
Relative Yield ◽  
Gas Chromatography Mass Spectrometry ◽  
Intramolecular Rearrangement ◽  
Oxidation Reactions ◽  
Pyrolysis Gas ◽  
Oxidative Decomposition ◽  
Oxidative Pyrolysis ◽  
Artemisia Pallens

SummaryThe thermo-oxidative decomposition of lovage (Levisticum officinale) and davana (Artemisia pallens) essential oils has been studied by pyrolysis-gas chromatography/mass spectrometry in 9% oxygen and 91% nitrogen atmosphere at 300 °C to simulate low-temperature tobacco heating conditions. Both lovage and davana oils contain numerous chemical substances; the main components of both oils are various oxygen-containing compounds. Isobenzofuranones are the most important constituents of lovage oil, and their relative intensity changed significantly during oxidative pyrolysis. (Z)-ligustilide underwent two kinds of decomposition reactions: an aromatization reaction resulting in the formation of butylidenephthalide and the scission of the lactone ring with the elimination of carbon dioxide or carbon monoxide. Davanone is the main component of davana oil, which did not decompose considerably during low-temperature oxidative pyrolysis. However, the relative yield of the second most intensive component, bicyclogermacrene, reduced markedly due to bond rearrangement reactions. Davana ether underwent oxidation reactions leading to the formation of various furanic compounds. The changes in the composition of both essential oils could be interpreted in terms of bond splitting, intramolecular rearrangement mechanisms and oxidation reactions of several constituents during low-temperature oxidative pyrolysis. The applied thermo-oxidative method was found to be suitable to study the stability of the essential oils and monitor the decomposition products under simulated tobacco heating conditions. In spite of the complicated composition of the essential oils, no evidence for interaction between the oil components was found. [Beitr. Tabakforsch. Int. 29 (2020) 27–43]

CHARACTERISATION OF DISSOLVED ORGANIC CARBON (DOC) LEACHED FROM LEAVES IN WATER

2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Markus Heryanto Langsa
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Total Organic Carbon ◽  
Gas Chromatography Mass Spectrometry ◽  
Pyrolysis Gas ◽  
Pyrolysis Gas Chromatography ◽  
Chromatography Mass Spectrometry ◽  
Pinus Radiate

<p>Penelitian ini bertujuan untuk menentukan senyawa organik khususnya organic karbon terlarut (DOC) dari dua spesies daun tumbuhan (<em>wandoo eucalyptus </em>and <em>pinus radiate, conifer</em>) yang larut dalam air selama periode 5 bulan leaching eksperimen. Kecepatan melarutnya senyawa organic ditentukan secara kuantitatif dan kualitatif menggunakan kombinasi dari beberapa teknik diantaranya Total Organic Carbon (TOC) analyser, Ultraviolet-Visible (UV-VIS) spektrokopi dan pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS).</p><p>Hasil analisis DOC dan UV menunjukkan peningkatan yang tajam dari kelarutan senyawa organic di awal periode pengamatan yang selanjutnya berkurang seiring dengan waktu secara eksponensial. Jumlah relatif senyawa organic yang terlarut tergantung pada luas permukaan, aktifitas mikrobiologi dan jenis sampel tumbuhan (segar atau kering) yang digunakan. Fluktuasi profil DOC dan UV<sub>254</sub> disebabkan oleh aktifitas mikrobiologi. Diperoleh bahwa daun kering lebih mudah terdegradasi menghasilkan senyawa organic dalam air dibandingkan dengan daun segar. Hasil pyrolysis secara umum menunjukkan bahwa senyawa hidrokarbon aromatic dan fenol (dan turunannya) lebih banyak ditemukan pada residue sampel setelah proses leaching kemungkinan karena adanya senyawa lignin atau aktifitas humifikasi mikrobiologi membuktikan bahwa senyawa-senyawa tersebut merupakan komponen penting dalam proses karakterisasi DOC.</p>

Experience in Implementation of Systems Applied for Drainage Water Ion-Selective Purification from Radionuclides at Units 1,2 of Novovoronezh-2 NPP

ANRI ◽  
2020 ◽  
Vol 0 (4) ◽  
pp. 64-70
Author(s):  
Vladimir Povarov ◽  
Igor' Gusev ◽  
Sergey Rosnovsky ◽  
Dmitriy Statsura ◽  
Vladimir Kazansky ◽  
...  
Keyword(s):  
Water Purification ◽  
Drainage Water ◽  
Purification Method ◽  
Selective Sorbent ◽  
Iron Based ◽  
Purification Plant ◽  
Nickel Ferrocyanide ◽  
Satisfactory Quality

The article is dedicated to the assessment of the experience in drainage water purification from radionuclides using ion-selective purification method on Units 1,2 Novovoronezh-2 NPP. Application of an ion-selective sorbent based on nickel ferrocyanide, as well as the preliminary oxidation of corrosive origin radiongjuclides, allow to achieve a satisfactory quality of purification from Cs-134, Cs-137, Co-60, Co 58, Mn-54, Cr-51. However, this method turned out to be ineffective for drainage water purification from Be-7, Sb-124, Sb-125. The article presents a possible method for drainage water purification from Be-7, Sb-124, Sb-125 using an iron-based coagulant, prospects for the modernization of the ion-selective drainage water purification plant, as well as plans to improve methods for drainage water purification at Novovoronezh-2 NPP

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