scholarly journals Analysis of Chemisorbed Tribo-Film for Ceramic-on-Ceramic Hip Joint Prostheses by Raman Spectroscopy

2021 ◽  
Vol 12 (2) ◽  
pp. 29
Author(s):  
Risha Rufaqua ◽  
Martin Vrbka ◽  
Dušan Hemzal ◽  
Dipankar Choudhury ◽  
David Rebenda ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Hyaluronic Acid ◽  
Hip Joint ◽  
Total Joint Replacement ◽  
Film Formation ◽  
Frictional Coefficient ◽  
Synovial Fluids ◽  
Frictional Coefficients ◽  
Joint Prostheses ◽  
Ceramic On Ceramic

To understand the possible lubricant mechanism in ceramic-on-ceramic hip joint prostheses, biochemical reactions of the synovial fluid and the corresponding frictional coefficients were studied. The experiments were performed in a hip joint simulator using the ball-on-cup configuration with balls and cups made from two types of ceramics, BIOLOX®forte and BIOLOX®delta. Different lubricants, namely albumin, γ-globulin, hyaluronic acid and three model synovial fluids, were studied in the experiments and Raman spectroscopy was used to analyze the biochemical responses of these lubricants at the interface. BIOLOX®delta surface was found less reactive to proteins and model fluid lubricants. In contrast, BIOLOX®forte ball surface has shown chemisorption with both proteins, hyaluronic acid and model fluids imitating total joint replacement and osteoarthritic joint. There was no direct correlation between the measured frictional coefficient and the observed chemical reactions. In summary, the study reveals chemistry of lubricant film formation on ceramic hip implant surfaces with various model synovial fluids and their components.

Luxation Test of Different Ceramic on Ceramic Couplings

2007 ◽  
Vol 330-332 ◽  
pp. 1235-1238
Author(s):  
Thomas Oberbach ◽  
Sabine Begand ◽  
Wilfried Glien ◽  
Christian Kaddick
Keyword(s):  
Mechanical Strength ◽  
Hip Joint ◽  
Ceramic Materials ◽  
Surface Areas ◽  
Joint Prostheses ◽  
Stressed Surface ◽  
Ceramic On Ceramic

Alumina and zirconia have been used for hip joint prostheses for decades. With mixtures of both materials (ZTA and ATZ) mechanical strength can be increased. The resistance against damaging of the surface of the ceramic articulation partners head and liner was investigated using a special luxation apparatus (PI-3:1997-07, Endolab GmbH, Thansau, Germany). Both new ceramic materials ZTA and ATZ showed a better resistance against roughening and damaging of the stressed surface areas during the luxation test compared to alumina.

Tribological property of the cobalt—chromium femoral head with different regions of wear in total hip arthroplasty

2009 ◽  
Vol 224 (4) ◽  
pp. 541-549 ◽  
Author(s):  
C-T Duong ◽  
J-S Nam ◽  
E-M Seo ◽  
B P Patro ◽  
J-D Chang ◽  
...  
Keyword(s):  
Surface Roughness ◽  
Femoral Head ◽  
Total Hip Arthroplasty ◽  
Tribological Properties ◽  
Hip Arthroplasty ◽  
Frictional Coefficient ◽  
Cobalt Chromium ◽  
Bearing Materials ◽  
Frictional Coefficients ◽  
Wear Region

The tribological properties of engineering and biological materials have been investigated at microscale levels through the calculation of the surface roughness and frictional coefficient using atomic force microscopy (AFM). Although a number of previous studies have reported the frictional coefficients of diverse bearing materials in total hip arthroplasty (THA), the relationship between the surface roughness and frictional coefficient of bearing materials of THA have not been reported, and furthermore, the tribological properties for different wear regions of a cobalt-chromium (Co—Cr) femoral head have not been well identified. Therefore, the objective of this study is to investigate the relationships between the surface roughness, frictional coefficient, and hardness for both the main-wear and the least-wear regions of a Co—Cr femoral head 10 years after THA. The average Vickers hardness of the Co—Cr femoral head was 380.7 ± 11.3 HV. With the scanned area of 25 μm×25 μm through AFM, the frictional coefficients of the main-wear and the least-wear regions were 0.229 ± 0.054 and 0.243 ± 0.059, respectively, and showed no statistical differences between these two regions ( p = 0.449). However, differences in the surface roughness ( Rq) between the main-wear region ( Rq = 96.5 ± 26.2 nm) and the least-wear region ( Rq = 17.7 ± 4.2 nm) were statistically significant ( p<0.0001). The results of the current study suggest that the frictional property of the Co—Cr femoral head is not significantly correlated with its surface roughness, and also provide guidelines for improving the surface characteristics of metallic implant materials.

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