scholarly journals A Novel TiZrHfMoNb High-Entropy Alloy for Solar Thermal Energy Storage

Nanomaterials ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 248 ◽  
Author(s):  
Huahai Shen ◽  
Jianwei Zhang ◽  
Jutao Hu ◽  
Jinchao Zhang ◽  
Yiwu Mao ◽  
...  

An equiatomic TiZrHfMoNb high-entropy alloy (HEA) was developed as a solar thermal energy storage material due to its outstanding performance of hydrogen absorption. The TiZrHfMoNb alloy transforms from a body-centered cubic (BCC) structure to a face-centered cubic (FCC) structure during hydrogen absorption and can reversibly transform back to the BCC structure after hydrogen desorption. The theoretical calculations demonstrated that before hydrogenation, the BCC structure for the alloy has more stable energy than the FCC structure while the FCC structure is preferred after hydrogenation. The outstanding hydrogen absorption of the reversible single-phase transformation during the hydrogen absorption–desorption cycle improves the hydrogen recycling rate and the energy efficiency, which indicates that the TiZrHfMoNb alloy could be an excellent candidate for solar thermal energy storage.

2019 ◽  
Author(s):  
Karolina Matuszek ◽  
R. Vijayaraghavan ◽  
Craig Forsyth ◽  
Surianarayanan Mahadevan ◽  
Mega Kar ◽  
...  

Renewable energy has the ultimate capacity to resolve the environmental and scarcity challenges of the world’s energy supplies. However, both the utility of these sources and the economics of their implementation are strongly limited by their intermittent nature; inexpensive means of energy storage therefore needs to be part of the design. Distributed thermal energy storage is surprisingly underdeveloped in this context, in part due to the lack of advanced storage materials. Here, we describe a novel family of thermal energy storage materials based on pyrazolium cation, that operate in the 100-220°C temperature range, offering safe, inexpensive capacity, opening new pathways for high efficiency collection and storage of both solar-thermal energy, as well as excess wind power. We probe the molecular origins of the high thermal energy storage capacity of these ionic materials and demonstrate extended cycling that provides a basis for further scale up and development.


Author(s):  
Mohammad Alhuyi Nazari ◽  
Akbar Maleki ◽  
Mamdouh El Haj Assad ◽  
Marc A. Rosen ◽  
Arman Haghighi ◽  
...  

2019 ◽  
pp. 23
Author(s):  
XU Xiao-Hong ◽  
TIAN Jiang-Zhou ◽  
WU Jian-Feng ◽  
ZHANG Qian-Kun ◽  
JIN Hao ◽  
...  

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