Study of Antioxidant and Anticorrosion Activity of Some Microwave Synthesized Thiourea Derivative Ligands and Complexes

In the title compound, C16H17N3OS, a benzoyl thiourea derivative, the planes of the pyridine and benzene rings are inclined to one another by 66.54 (9)°. There is an intramolecular N—H...O hydrogen bond present forming anS(6) ring motif. In the crystal, molecules are linkedviapairs of N—H...N hydrogen bonds, forming inversion dimers, which are reinforced by pairs of C—H...S hydrogen bonds. The dimers are linkedviaC—H...π interactions, forming ribbons along [010].

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Development of a thiourea derivative polymer combined to a Direct Mercury Analyser for screening and pre-concentration of mercury species

Talanta ◽

10.1016/j.talanta.2016.10.048 ◽

2017 ◽

Vol 162 ◽

pp. 612-617 ◽

Cited By ~ 4

Author(s):

S. Zarco-Fernández ◽

S. Montalvo-Quirós ◽

M.J. Mancheño ◽

C. Cámara ◽

R. Muñoz-Olivas

Keyword(s):

Mercury Species ◽

Thiourea Derivative

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Synthesis of new artificial receptors for anion recognition: calix[4]arenes thiourea derivative

10.5151/chempro-14bmos-r0118-1 ◽

2013 ◽

Author(s):

Claudio Saitz ◽

Eduardo Bastidas ◽

Horacio Gómez ◽

Carolina Jullian ◽

Julio De la Fuente ◽

...

Keyword(s):

Anion Recognition ◽

Thiourea Derivative ◽

Artificial Receptors

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A Phosphino-substituted Isoindole Obtained by Cyclization of a Thiourea Derivative

Heterocycles ◽

10.3987/com-04-10286 ◽

2005 ◽

Vol 65 (3) ◽

pp. 643

Author(s):

Gabriel García-Herbosa ◽

Jorge R. Angulo-Cornejo ◽

Arancha Carbayo ◽

Elva Cueva-Talledo ◽

José V. Cuevas ◽

...

Keyword(s):

Thiourea Derivative

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[Fe4S4I2(C6H10(NHCSNHMe)2)]: ein neutraler Eisen-Schwefel-Cluster mit zweizähnigem Liganden / [Fe4S4I2(C6H10(NHCSNHMe)2)]: A Neutral Iron-Sulfur Cluster with a Bidentate Ligand

Zeitschrift für Naturforschung B ◽

10.1515/znb-1992-0909 ◽

1992 ◽

Vol 47 (9) ◽

pp. 1266-1270 ◽

Cited By ~ 2

Author(s):

Siegfried Pohl ◽

Ulrich Bierbach

Keyword(s):

Solid State ◽

Bidentate Ligand ◽

Striking Feature ◽

Monoclinic Space Group ◽

Thiourea Derivative ◽

Iron Sulfur Cluster ◽

Sulfur Cluster ◽

Space Group ◽

Iron Sulfur ◽

Neutral Ligands

The reaction of [Fe4S4I2(SC(NMe2)2)2] with racemic trans-1,2-bis(3-methylthioureido)-cyclohexane in tetrahydrofuran (thf) yields [Fe4S4I2(C6H10(NHCSNHMe)2)] · 4 thf (2). 2 crystallizes in the monoclinic space group C 2/c with a = 1471.7(2), b = 1329.7(2), c = 2339.3(3) pm, β = 107.70(1), V = 4362.3 × 106 pm3, Z = 4, R = 0.057. The cluster exhibits C2 symmetry in the solid state. The replacement of the monodentate neutral ligands results in a cluster in which the bifunctional thiourea derivative bridges two different iron sites of the slightly compressed [Fe4S4] core. The most striking feature are the differences of the Fe–Fe distances which are 269.8 pm between thiourea coordinated atoms and 280.7 pm between Fe atoms with iodide ligation. The Fe–S thiourea distance was found to be 229.3 pm.

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