Geochemical Modeling of the Speciation of Uranium in an Acid Mine Drainage Environment in the Witwatersrand Basin

Author(s):  
Hlanganani Tutu ◽  
Ewa Cukrowska ◽  
T McCarthy
Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 547 ◽  
Author(s):  
Darrell Kirk Nordstrom

Geochemical modeling of precipitation reactions in the complex matrix of acid mine drainage is fundamental to understanding natural attenuation, lime treatment, and treatment procedures that separate constituents for potential reuse or recycling. The three main dissolved constituents in acid mine drainage are iron, aluminum, and sulfate. During the neutralization of acid mine drainage (AMD) by mixing with clean tributaries or by titration with a base such as sodium hydroxide or slaked lime, Ca(OH)2, iron precipitates at pH values of 2–3 if oxidized and aluminum precipitates at pH values of 4–5 and both processes buffer the pH during precipitation. Mixing processes were simulated using the ion-association model in the PHREEQC code. The results are sensitive to the solubility product constant (Ksp) used for the precipitating phases. A field example with data on discharge and water composition of AMD before and after mixing along with massive precipitation of an aluminum phase is simulated and shows that there is an optimal Ksp to give the best fit to the measured data. Best fit is defined when the predicted water composition after mixing and precipitation matches most closely the measured water chemistry. Slight adjustment to the proportion of stream discharges does not give a better fit.


2014 ◽  
Vol 9 (1) ◽  
pp. 79-86 ◽  
Author(s):  
Aneta Petrilakova ◽  
Magdalena Balintova ◽  
Marian Holub

Abstract Geochemical modeling plays an increasingly vital role in a number of areas of geoscience, ranging from groundwater and surface water hydrology to environmental preservation and remediation. Geochemical modeling is also used to model the interaction processes at the water - sediment interface in acid mine drainage (AMD). AMD contains high concentrations of sulfate and dissolved metals and it is a serious environmental problem in eastern Slovakia. The paper is focused on comparing the results of laboratory precipitation of metal ions from AMD (the Smolnik creek, Slovakia) with the results obtained by geochemical modeling software Visual Minteq 3.0.


2014 ◽  
Vol 130 (10_11) ◽  
pp. 488-493 ◽  
Author(s):  
Hiroshi OTSUKA ◽  
Shinsuke MURAKAMI ◽  
Jiro YAMATOMI ◽  
Ryu KOIDE ◽  
Chiharu TOKORO

2014 ◽  
Vol 64 ◽  
pp. 78-91 ◽  
Author(s):  
Nymphodora Papassiopi ◽  
Christina Zaharia ◽  
Anthimos Xenidis ◽  
Katerina Adam ◽  
Alexandros Liakopoulos ◽  
...  

2021 ◽  
Author(s):  
Sereyroith Tum ◽  
Tsutomu Sato ◽  
Tsubasa Otake ◽  
Yoko Ohtomo ◽  
Tatsuya Matsui ◽  
...  

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