scholarly journals Study on the Interaction Between Melamine-Cored Schiff Bases with Cucurbit[n]urils of Different Sizes and Its Application in Detecting Silver Ion

2021 ◽  
Author(s):  
Jun-Xian Gou ◽  
yang luo ◽  
Xi-Nan Yang ◽  
Wei Zhang ◽  
Ji-Hong Lu ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Outer Surface ◽  
Precious Metal ◽  
Surface Interaction ◽  
Silver Ion ◽  
Uv Detector ◽  
Form Complex ◽  
Metal Detection

Three different complexes, TMeQ[6]-TBT, Q[7]-TBT and Q[8]-TBT, are constructed by three different cucurbiturils and synthesized guest melamine-cored Schiff base (TBT) through outer-surface interaction and host-guest interaction, where TBT and TMeQ[6] form complex TMeQ[6]-TBT through outer-surface interaction, while TBT and Q[7,8] form complexs Q[7]-TBT and Q[8]-TBT through host-guest interaction., and finally, Q[7]-TBT is selected as a UV detector for the detection of precious metal Ag+. This work makes full use of the characteristics of each cucurbiturils and combines that of Schiff bases to construct a series of complexes and apply them to metal detection.

scholarly journals Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions

2021 ◽  
Vol 17 ◽  
pp. 2950-2958
Author(s):  
Jun-Xian Gou ◽  
Yang Luo ◽  
Xi-Nan Yang ◽  
Wei Zhang ◽  
Ji-Hong Lu ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Outer Surface ◽  
Silver Ions ◽  
Surface Interaction ◽  
Uv Detector ◽  
Metal Detection

Three different complexes, TMeQ[6]-TBT, Q[7]-TBT, and Q[8]-TBT are constructed by three different cucurbiturils and synthesized by guest melamine-cored Schiff bases (TBT) through outer-surface interaction and host–guest interactions. TBT forms a TMeQ[6]-TBT complex with TMeQ[6] through outer-surface interaction, while Q[7]-TBT and Q[8]-TBT form complexes with Q[7,8] through host–guest interactions. Among them, Q[7]-TBT is selected as a UV detector for the detection of silver ions (Ag+). This work makes full use of the characteristics of each cucurbituril and melamine-cored Schiff base to construct a series of complexes and these are applied to metal detection.

scholarly journals Synthesis and Evaluation of Schiff Bases of 4-Amino-5-(chlorine substituted phenyl)-4H-1,2,4-triazole-3-thione as Antimicrobial Agents

2020 ◽  
Vol 41 (1) ◽  
pp. 26-35
Author(s):  
Kishor Devkota ◽  
Govinda Pathak ◽  
Bhushan Shakya
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Antimicrobial Agents ◽  
Triazole Ring ◽  
Antimicrobial Activities ◽  
Biologically Active ◽  
Spectral Techniques ◽  
Schiff Base Derivatives ◽  
Bacteria And Fungi ◽  
Different Strains

Triazole ring system has attracted a continuously growing interest of synthetic organic chemists and those dealing with the medicinal compounds due to its versatile potential to interact with biological systems. Schiff bases are also considered as one of the most biologically active compounds.  The aim of the present study was to synthesize new Schiff bases bearing triazole nucleus and to assess their antimicrobial activities. Four new Schiff base derivatives of 1,2,4-triazole-3-thione were synthesized by combining two different pharmacophores viz. triazole nucleus and Schiff base moiety and were characterized by spectral techniques (UV, FT-IR, and NMR). The Schiff bases were evaluated for antibacterial (Staphylococcus aureus, Escherichia coli, and Klebsiella pneumoniae) and antifungal (Candida albicans) activities. The synthesized compounds exhibited good to moderate activities against different strains of bacteria and fungi tested.

Syntheses, Spectroscopy And Crystal Structures Of (R)-N-(1-Aryl-Ethyl)Salicylaldimines And [Rh{(R)-N-(1-Aryl-Ethyl)Salicylaldiminato}(η4-Cod)] Complexes

2007 ◽  
Vol 62 (6) ◽  
pp. 807-817 ◽  
Author(s):  
Mohammed Enamullah ◽  
A.K.M. Royhan Uddin ◽  
Anne-Christine Chamayou ◽  
Christoph Janiak
Keyword(s):  
Mass Spectrometry ◽  
Schiff Base ◽  
Schiff Bases ◽  
Structure Determination ◽  
Chelate Ring ◽  
Optical Rotation ◽  
X Ray ◽  
Mononuclear Complexes ◽  
Chiral Schiff Base ◽  
C Nmr

Condensation of salicylaldehyde with enantiopure (R)-(1-aryl-ethyl)amines yields the enantiopure Schiff bases (R)-N-(1-aryl-ethyl)salicylaldimine (HSB*; aryl = phenyl, 2-methoxyphenyl, 3- methoxyphenyl, 4-methoxyphenyl (4), 4-bromophenyl (5), 2-naphthyl). These Schiff bases readily react with dinuclear (acetato)(η4-cycloocta-1,5-diene)rhodium(I), [Rh(μ-O2CMe)(η4-cod)]2, to afford the mononuclear complexes, cyclooctadiene-((R)-N-(1-aryl-ethyl)salicylaldiminato-κ2N,O)- rhodium(I), [Rh(SB∗)(η4-cod)] (SB* = deprotonated chiral Schiff base = salicylaldiminate; aryl = phenyl (7), 2-methoxyphenyl, 4-methoxyphenyl, 4-bromophenyl, 2-naphthyl). The complexes have been characterized by IR, UV/vis, 1H/13C NMR and mass spectrometry, optical rotation as well as by single-crystal X-ray structure determination for 4, 5 and 7. The structure of 5 shows C-Br· · ·π contacts. Compound 7 is only the second example of a Rh(η4-cod) complex with a six-membered Rh-N,O-chelate ring

Notizen: Magnetic Studies on Schiff Base Complexes of Al(III) and Si(IV)

1974 ◽  
Vol 29 (7-8) ◽  
pp. 565-566 ◽  
Author(s):  
R. N. Prasad ◽  
J. P. Tandon
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Schiff Base Complexes ◽  
Magnetic Studies ◽  
Magnetic Susceptibilities

The magnetic susceptibilities of some newly syntesized Al(III) and Si(IV) complexes of Schiff bases derived from the condensation of o-hydroxyacetophenone or 2-dydroxy-1-naphthaldehyde with hydroxyalkylamines or diamines have been measured and the data indicate their diamagnetic character.

scholarly journals Potentiometric performance of a dioxime-type Schiff base as a silver-ion recognizable material.

2001 ◽  
Vol 50 (9) ◽  
pp. 619-625 ◽  
Author(s):  
Masato UEDA ◽  
Naoko SAKAKI ◽  
Takayo MORIUCHI-KAWAKAMI ◽  
Yasuhiko SHIBUTANI
Keyword(s):  
Schiff Base ◽  
Silver Ion

Schiff Bases and Related Substances. III. Acetylation of a Schiff Base-Thiol Adduct1

1958 ◽  
Vol 80 (13) ◽  
pp. 3475-3478 ◽  
Author(s):  
Gardner W. Stacy ◽  
Richard I. Day ◽  
Richard J. Morath
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Related Substances

Electronic Structure of Pseudotetrahedral Copper(II) Schiff Base Complexes

1977 ◽  
Vol 32 (5) ◽  
pp. 551-561 ◽  
Author(s):  
John R. Wasson ◽  
H. Wayne Richardson ◽  
William E. Hatfield
Keyword(s):  
Electronic Structure ◽  
Schiff Base ◽  
Schiff Bases ◽  
Opposite Direction ◽  
Hyperfine Coupling ◽  
Coupling Constants ◽  
Schiff Base Complexes ◽  
Hyperfine Coupling Constants ◽  
Structure Correlations

Copper(II) complexes with the Schiff bases formed by condensing t-butyl-, isopropyl-, cyclohexyl- and diphenylmethylamines with salicylaldehyde and 3-methoxy- and 5-nitrosalicyl-aldehyde have been prepared and characterized. The isotropic nuclear hyperfine coupling constants increase in the order t-butyl < isopropyl < cyclohexyl < diphenylmethyl for the N-substituents in the three series of complexes while isotropic g-values increased in the opposite direction. Spectra structure correlations were examined and discussed.

scholarly journals A novel approach toward the synthesis of some new tridentate Schiff bases from anil-like compounds

2016 ◽  
Vol 81 (10) ◽  
pp. 1111-1119 ◽  
Author(s):  
Fatemeh Bagheri ◽  
Abolfazl Olyaei
Keyword(s):  
Schiff Base ◽  
Formic Acid ◽  
Schiff Bases ◽  
Condensation Product ◽  
Reaction Times ◽  
Acid Catalyst ◽  
Schiff Base Ligands ◽  
Novel Approach ◽  
Solvent Free Conditions ◽  
Novel Method

A novel method was developed for synthesizing a series of new three dentate Schiff base ligands starting from hydroxynaphthalidene pyrimidinyl amines with o-phenylenediamines or o-aminophenol or 2-amino-3-hydroxy-pyri-dine in the presence of formic acid catalyst under solvent-free conditions. In these reactions [1+1] condensation product as half-unit ligand was obtained. Moreover, the reaction of hydroxynaphthalidene pyrimidinyl amines with 3,4-diamino-pyridine and 1,8-naphthalenediamine lead to the formation of C2-naphthylated imidazopyridine and dihydropyrimidine, respectively. The attractive features of this protocol are: use of inexpensive catalyst, operationally simple, short reaction times, easy handling, and good yields.

Phosphine-assisted C–H bond activation in Schiff bases and formation of novel organo cobalt complexes bearing Schiff base ligands

2018 ◽  
Vol 42 (6) ◽  
pp. 4646-4652 ◽  
Author(s):  
Hua Zhang ◽  
Junyang Xing ◽  
Yanhong Dong ◽  
Shangqing Xie ◽  
Shishuai Ren ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Bond Activation ◽  
Cobalt Complexes ◽  
Schiff Base Ligands

The sp2 C–H bond activation of the HCN moiety in diphenylphosphino benzalimines was realized using CoMe(PMe3)4 with the elimination of methane.

ChemInform Abstract: LANTHANID COMPOUNDS WITH SCHIFF BASES AND WITH COPPER(II) SCHIFF BASE COMPLEXES AS LIGANDS

1975 ◽  
Vol 6 (15) ◽  
pp. no-no
Author(s):  
G. CONDORELLI ◽  
I. FRAGALA ◽  
S. GIUFFRIDA ◽  
A. CASSOL
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Schiff Base Complexes
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