Measurement and Computation of Excess Heat Capacity of Nonassociation Binary Liquid Mixture

1997 ◽  
Vol 13 (03) ◽  
pp. 264-269
Author(s):  
Sun Hong-Wei ◽  
◽  
Gao Ming-Shu
1999 ◽  
Vol 64 (7) ◽  
pp. 1093-1099 ◽  
Author(s):  
Ivona Malijevská ◽  
Anatol Malijevský

Temperature dependence of GE is discussed for three widely used equations linear and nonlinear in parameters. It is shown that the Wilson equation predicts always positive excess heat capacity regardless of values of its parameters. Several temperature modifications of the Redlich-Kister, Wilson and NRTL equations are discussed with respect to the sign of the excess Gibbs energy, excess enthalpy and excess heat capacity.


Author(s):  
Ari David Brown ◽  
Regis Brekosky ◽  
Felipe Colazo-Petit ◽  
Matthew Greenhouse ◽  
James Hay-Wehle ◽  
...  

Author(s):  
Thomas Zemb ◽  
Rose Rosenberg ◽  
Stjepan Marčelja ◽  
Dirk Haffke ◽  
Jean-François Dufrêche ◽  
...  

We use the model system ethanol–dodecane to demonstrate that giant critical fluctuations induced by easily accessible weak centrifugal fields as low as 2000g can be observed above the miscibility gap even far from the critical point of a binary liquid mixture.


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